尖晶石型镍锰酸锂具有高工作电压、高安全性以及低成本等优点成为近年来锂离子电池正极材料研究的热点之一,但其自身存在Mn溶解导致结构破坏和循环性能衰减较快的缺点。重点阐述了通过晶型结构控制、离子掺杂和表面包覆等改性方法提高镍锰酸锂材料结构稳定性和循环性能的研究进展。最后,展望了镍锰酸锂材料未来研究的重点和发展趋势。
Spinel-type lithium nickel manganese oxide has become one of the hot spots in the research of lithium-ion battery cathode materials in recent years due to its advantages of high working voltage,high safety,and low cost.However,it has the disadvantages of structural failure and fast decay of cycling performance caused by Mn dissolution.This paper focused on the research progress on improving the structural stability and cycling performance of lithium nickel manganese oxide materials by modification methods such as crystal structure control,ion doping and surface coating.Finally,the focus and development trend of lithium nickel manganese oxide materials in the future were prospected.
[1] Li J H,Jiang N Y,Liao J Y,et al.Nonstoichiometric Cu0.6Ni0.4Co2O4 nanowires as an anode material for high performance lithium storage[J].Nanomaterials,2020,10(2):191.
[2] Pirmin S,Valeriu M,Holger G,et al.On the composition of LiNi0.5Mn1.5O4 cathode active materials[J].Advanced Energy Materials,2023,13(10):2203778.
[3] Chen J X,Huang Z,Zeng W H,et al.Synthesis,modification,and lithium-storage properties of spinel LiNi0.5Mn1.5O4[J].ChemElectroChem,2021,8(4):608-624.
[4] Yang W,Chang L J,Luo S H.Study on annealing treatment of spinel LiNi0.5Mn1.5O4 as cathode materials for high-voltage lithium-ion batteries[J].International Journal of Energy Research,2022,46(13):608-624.
[5] Yu C Y,Dong L,Zhang Y X,et al.Promoting electrochemical performances of LiNi0.5Mn1.5O4 cathode via YF3 surface coating[J].Solid State Ionics,2020,357:115464.
[6] 罗英,丁赵波,刘雯,等.微米级单晶高电压LiNi0.5Mn1.5O4材料的制备及性能[J].无机化学学报,2022,38(4):611-619.
[7] Li X Y,Su B,Xue W L,et al.The effects of Ru4+ doping on LiNi0.5Mn1.5O4 with two crystal structures[J].Materials,2022,15(12):4273-4279.
[8] Ding H,Zhang N S,Wang P,et al.Role of carbon nanotube on preparation of spinel LiNi0.5Mn1.5O4 cathode[J].Journal of Materials Science,2022,57:14440-14449.
[9] Pirmin S,Holger G,Sylvio I,et al.On the electrochemical properties of the Fe-Ti doped LNMO material LiNi0.5Mn1.37Fe0.1Ti0.03O3.95[J].Journal of Materials Chemistry,2022,16(10):9010-9024.
[10] 温嘉玮,杨晨林,成建凤,等.尖晶石型三元高电压正极材料的合成及其性能[J].化工进展,2022,41(11):5968-5976.
[11] Ji Xiang,Dai Xinyi,Wu Fuzhong,et al.In situ Sr2+-doped spinel LiNi0.5Mn1.5O4 cathode material for Li-ion batteries with high electrochemical performance and its impact on morphology[J].Ceramics International,2021,47(22):32043-32052.
[12] Zeng F F,Zhang Y,Shao Z C.Synthesis and electrochemical performance of Mo-doped LiNi0.5Mn1.5O4 cathode material[J].Materials and Manufacturing Processes,2022,38(2):197-205.
[13] Shih C P,Maecin K,Panitat H,et al.Spray-drying synthesis of fluorine-doped LiNi0.5Mn1.5O4 as high-voltage cathodes for lithium-ion batteries[J].Journal of Alloys and Compounds,2022,932:167641.
[14] 陈孟,陈朝轶,李军旗,等.锂离子电池镍锰酸锂正极材料研究进展[J].电子元件与材料,2021,40(9):833-839,865.
[15] Lin F C,Wu H M,Chen T C,et al.The action of Y-F co-doping in LiNi0.5Mn1.5O4 positive electrode materials[J].Powder Technology,2022,409:117812.
[16] Mu J P,Wei A J,He R,et al.Exploring the synergistic effect of Li+ and Br- co-doping on improving the microstructural and electrochemical performances of LiNi0.5Mn1.5O4 cathode materials[J].Journal of the Taiwan Institute of Chemical Engineers,2022,138:104437.
[17] 刘卓钦,周晓崇,莫梁君.硼酸锂包覆改性尖晶石锰酸锂的研究[J].无机盐工业,2022,54(9):90-95.
[18] Chen T C,Wu H M,Zhou D F,et al.The CeF4-coated spinel LiNi0.5Mn1.5O4 with improved electrochemical performance for 5V lithium-ion batteries[J].Materials in Electronics,2022,33:11712-11724.
[19] Luo H,Chen H,Luo X,et al.Effects of in situ-converted Li3PO4 coating on electrochemical performance of MOF-assisted LiNi0.5Mn1.5O4 cathode materials for lithium-ion batteries[J].Materials in Electronics,2022,33:6872-6887.
[20] Wu Y D,Ben L B,Zhan Y J,et al.Binding Li3PO4 to spinel LiNi0.5Mn1.5O4 via a surface Co-containing bridging layer to improve the electrochemical performance[J].Energy Techenology,2021,9(8):2100147.
[21] Bi X L,Chang L J,Cao S Y,et al.Preparation and improvement of electrochemical performance of LiNi0.5Mn1.5O4 cathode materials in situ coated with AlPO4[J].Energy Fuels,2023,37(4):3236-3246.
[22] Ma C Z,Wen Y H,Qiao Q,et al.Improving electrochemical performance of high-voltage spinel LiNi0.5Mn1.5O4 cathodes by silicon oxide surface modification[J].Energy Materials,2021,4(11):1220-12210.
[23] Zawar A Q,Hanan A T,Hiba M H,et al.Influence of graphene wrapped-cerium oxide coating on spherical LiNi0.5Mn1.5O4 particles as cathode in high-voltage lithium-ion batteries[J].Journal of Alloys and Compounds,2022,920:165989.
[24] Sun L Z,Li H,Liu H,et al.Lattice matched coating on the surface of LiNi0.5Mn1.5O4[J].Ceramics International,2019,45(12):15745-15748.
[25] Shih-Chieh H,Chang J,Huang T Y,et al.Synergistic effect of doping and surface engineering on LiNi0.5Mn1.5O4 and its application as a high-performance cathode material for Li-ion batteries[J].Ceramics International,2022,48(19):27859-27869.
基金资助
广东省科技计划项目(2017B010119002);佛山市科技计划项目(1920001001421)
PDF
