二硫化钼高效电催化析氢的改性策略

杜娟, 蔡天风, 韩乔, 武宏大, 杨占旭*

化工新型材料 ›› 2024, Vol. 52 ›› Issue (7) : 35 -40.

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化工新型材料 ›› 2024, Vol. 52 ›› Issue (7) : 35-40. DOI: 10.19817/j.cnki.issn1006-3536.2024.07.022
综述与专论

二硫化钼高效电催化析氢的改性策略

    杜娟, 蔡天风, 韩乔, 武宏大, 杨占旭*
作者信息 +

Modification strategy of molybdenum disulfide for efficient electrocatalytic hydrogen evolution

  • Du Juan, Cai Tianfeng, Han Qiao, Wu Hongda, Yang Zhanxu
Author information +
文章历史 +
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摘要

电解水制氢技术是提供廉价清洁能源的一种非常有前途的方法。二硫化钼(MoS2)以其优异的电催化活性作为潜在的电催化析氢(HER)催化剂受到广泛关注。然而,MoS2的HER性能需要改进才能与传统的Pt基催化剂竞争。详细分析基于MoS2表面/界面工程提高HER性能的最新研究进展,总结了提高HER性能的有效策略,如相工程、缺陷工程和异质结构的构建等典型策略,以揭示通过调控表面电子结构、提高电导率、暴露活性位点促进HER动力学。

Abstract

Hydrogen production through electrocatalytic hydrolysis is a promising way to provide cheap clean energy.Due to its excellent electrocatalytic activity,molybdenum disulfide (MoS2) has received extensive attention as a potential HER catalyst.However,the HER performance of MoS2 needs to be improved to compete with traditional Pt-based catalysts.Recent advances in improving HER performance based on MoS2 surface/interface engineering were analyzed.Several effective strategies such as phase engineering,defect engineering,and heterostructure construction were summarized to reveal the promotion of HER kinetics by regulating surface electron structure,increasing electrical conductivity,and exposing active sites.

关键词

二硫化钼 / 表面工程 / 电催化剂 / 析氢反应

Key words

molybdenum disulfide / surface engineering / electrocatalyst / hydrogen evolution reaction

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二硫化钼高效电催化析氢的改性策略[J]. 化工新型材料, 2024, 52(7): 35-40 DOI:10.19817/j.cnki.issn1006-3536.2024.07.022

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基金资助

辽宁省应用基础研究计划项目(2023JH2/101300230);国家自然科学基金面上项目(21671092)

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