木质素基聚氨酯导电泡沫的制备及其传感性能研究

王凡1,2, 赵洪龙2, 马晓振2, 那海宁2, 朱锦2, 陈景2*

化工新型材料 ›› 2024, Vol. 52 ›› Issue (7) : 263 -266.

PDF
化工新型材料 ›› 2024, Vol. 52 ›› Issue (7) : 263-266. DOI: 10.19817/j.cnki.issn1006-3536.2024.07.021
开发与应用

木质素基聚氨酯导电泡沫的制备及其传感性能研究

    王凡1,2, 赵洪龙2, 马晓振2, 那海宁2, 朱锦2, 陈景2*
作者信息 +

Preparation of lignin-based polyurethane conductive foam and its sensing properties

  • Wang Fan1,2, Zhao Honglong2, Ma Xiaozhen2, Na Haining2, Zhu Jin2, Chen Jing2
Author information +
文章历史 +
PDF

摘要

三维多孔导电泡沫材料是制备柔性压力传感器的理想材料,采用成本低廉的木质素和氧化还原石墨烯与六亚甲基二异氰酸酯混合一步发泡法制备了导电的木质素基聚氨酯泡沫。该泡沫在电路中可以使得小灯泡发亮,在压缩形变达到90%后不改变其形状,可以检测到0.5Hz、0.2Hz、1Hz和2Hz的外界不同物理频率刺激,穿戴在人体上可以进行人体运动监测。这种成本低廉、制备方法简单的木质素基聚氨酯泡沫在医疗健康领域和可穿戴电子器件领域有着巨大的应用前景。

Abstract

Three-dimensional porous conductive foam materials are ideal for the preparation of flexible pressure sensors.Using low-cost lignin and redox graphene mixed with hexamethylene diisocyanate to prepare a conductive lignin-based polyurethane foam by one-step foaming method.The foam could make a small light bulb glow in the circuit,and its shape did not change after 90% compression deformation.It could detect the different physical frequency stimuli of 0.5Hz,0.2Hz,1Hz,and 2Hz,and could be worn on the human body for human motion monitoring.This lignin-based polyurethane foam,which is low-cost and simple-to-prepare,has great promise for applications in the fields of medical health and wearable electronic devices.

关键词

木质素 / 聚氨酯 / 氧化还原石墨烯 / 发泡 / 压力传感器

Key words

lignin / polyurethane / redox graphene / foaming / pressure sensors

引用本文

引用格式 ▾
木质素基聚氨酯导电泡沫的制备及其传感性能研究[J]. 化工新型材料, 2024, 52(7): 263-266 DOI:10.19817/j.cnki.issn1006-3536.2024.07.021

登录浏览全文

4963

注册一个新账户 忘记密码

参考文献

[1] Yuan H,Lei T,Qin Y,et al.Flexible electronic skins based on piezoelectric nanogenerators and piezotronics[J].Nano Energy,2019,59:84-90.
[2] Wang C,Pan C,Wang Z.Electronic skin for closed-loop systems[J].ACS Nano,2019,13(11):12287-12293.
[3] Rao J,Chen Z,Zhao D,et al.Recent progress in self-powered skin sensors[J].Sensors,2019,19(12):2763-2780.
[4] Lu Y,Lou Z,Jiang K,et al.Recent progress of self-powered wearable monitoring systems integrated with microsupercapacitors[J].Materials Today Nano,2019,8:100050.
[5] Chen H,Song Y,Cheng X,et al.Self-powered electronic skin based on the triboelectric generator[J].Nano Energy,2019,56:252-268.
[6] Zhang X S,Han M,Kim B,et al.All-in-one self-powered flexible microsystems based on triboelectric nanogenerators[J].Nano Energy,2018,47:410-426.
[7] Huynh T P,Haick H.Autonomous flexible sensors for health monitoring[J].Advanced Materials,2018,30(50):1802337.
[8] Kakria P,Tripathi N K,Kitipawang P.A real-time health monitoring system for remote cardiac patients using smartphone and wearable sensors[J].International Journal of Telemedicine and Applications,2015,2015:1-11.
[9] Yang Z,Pang Y,Han X,et al.Graphene textile strain sensor with negative resistance variation for human motion detection[J].ACS Nano,2018,12(9):9134-9141.
[10] Lee J,Shin S,Lee S,et al.Highly sensitive multifilament fiber strain sensors with ultrabroad sensing range for textile electronics[J].ACS Nano,2018,12(5):4259-4268.
[11] Cho D,Park J,Kim J,et al.Three-dimensional continuous conductive nanostructure for highly sensitive and stretchable strain sensor[J].ACS Applied Materials & Interfaces,2017,9(20):17369-17378.
[12] Pang Y,Tian H,Tao L,et al.Flexible,highly sensitive,and wearable pressure and strain sensors with graphene porous network structure[J].ACS Applied Materials & Interfaces,2016,8(40):26458-26462.
[13] Wang S,Liu W,Yang D,et al.Highly resilient lignin-containing polyurethane foam[J].Industrial & Engineering Chemistry Research,2018,58(1):496-504.
[14] 甘卫星,刘金明,张建辉,等.木质素液化改性酚醛树脂研究进展[J].林业工程学报,2002,7(3):11-19.
[15] Laurichesse S,Avérous L.Chemical modification of lignins:towards biobased polymers[J].Progress in Polymer Science,2014,39(7):1266-1290.

基金资助

国家重点研发计划项目(2017YFE0102300);国家自然科学基金(51503218);宁波市重点研发计划项目(2022Z139)

AI Summary AI Mindmap
PDF

468

访问

0

被引

导航
相关文章

AI思维导图

/