相变材料(PCM)是一种可逆的储能材料,在实际使用中可以周期性的以相变潜热的形式储存能量以达到节能的效果。针对相变温度为中低温的有机基相变材料(OPCM)进行了探讨,其具有长期的化学稳定性,无污染且节能、高效、无毒无腐蚀性。归纳综述了国内外有机基相变材料的制备以及OPCM包封技术的最新研究成果,根据材料的特点介绍了降低可燃性的方法以及在各个领域的最新应用。
Phase change material (PCM) is a kind of reversible energy storage material and can cyclically store energy in the form of latent heat of phase change to achieve energy saving effect in practical use.The organic-based phase change materials (OPCMs) with medium and low phase change temperatures were discussed,and they exhibited long-term chemical stability,non-pollution,energy saving,high efficiency,non-toxic and non-corrosive properties.The latest research progress on the preparation methods and encapsulation technologies of OPCMS at home and abroad were reviewed.According to the characteristics of materials,the methods of reducing flammability and the latest applications in various fields were introduced.
[1] 曹恩惠,赵嘉璐.气候变化成全球性挑战[N].21世纪经济报道,2023-09-11(011).https://kns.cnki.net/kcms2/article/abstract?v=ipUboLYjcOVHK3WdD87rlml0blYqfPlpPJGXZk51wegXx3AeTa-US3ADklI0q0VmGNcHcdPUgYen6UGYdxm9QpQmmx-BnT95YigH1mF33yTtQkb2jkpv5UOd-aVyWW1HhGioMKuVxJo=&uniplatform=NZKPT&language=CHS.
[2] Zhao Y,Zhang X,Hua W.Review of preparation technologies of organic composite phase change materials in energy storage[J].Journal of Molecular Liquids,2021,336:115923.
[3] Giro-Paloma J,Martínez M,Cabeza L F,et al.Types,methods,techniques,and applications for microencapsulated phase change materials (MPCM):a review[J].Renewable and Sustainable Energy Reviews,2016,53:1059-1075.
[4] Yuan Y,Zhang N,Tao W,et al.Fatty acids as phase change materials:a review[J].Renewable and Sustainable Energy Reviews,2014,29:482-498.
[5] Liu Q,Zhang J,Liu J,et al.Self-healed inorganic phase change materials for thermal energy harvesting and management[J].Applied Thermal Engineering,2023,219:119423.
[6] Palacios A,De Gracia Á,Cabeza L F,et al.New formulation and characterization of enhanced bulk-organic phase change materials[J].Energy and Buildings,2018,167:38-48.
[7] Zuo P,Liu Z,Zhang H,et al.Formulation and phase change mechanism of Capric acid/Octadecanol binary composite phase change materials[J].Energy,2023,270:126943.
[8] Ma Z,Yue K,Yao Z,et al.Development of novel phase change materials based on methyl laurate and fatty acids for low-temperature applications[J].Energy Sources,Part A:Recovery,Utilization,and Environmental Effects,2023,45(2):5823-5835.
[9] Al-Maghalseh M,Mahkamov K.Methods of heat transfer intensification in PCM thermal storage systems[J].Renewable and Sustainable Energy Reviews,2018,92:62-94.
[10] He R,Fang M,Zhou J,et al.Multifunctional MIL-101 (Cr)-NH2/expanded graphite/multi-walled carbon nanotube/paraffin wax composite phase change materials with excellent thermal conductivity and highly efficient thermal management for electronic devices[J].Journal of Materials Chemistry C,2023,11(33):11341-11352.
[11] Sun K,Kou Y,Zhang Y,et al.Photo-triggered hierarchical porous carbon-based composite phase-change materials with superior thermal energy conversion capacity[J].ACS Sustainable Chemistry & Engineering,2020,8(8):3445-3453.
[12] Li S,Dong X,Lin X,et al.Flexible phase change materials obtained from a simple solvent-evaporation method for battery thermal management[J].Journal of Energy Storage,2021,44:103447.
[13] Jiang Z,Shu J,Ge Z,et al.Preparation and performance of magnetic phase change microcapsules with organic-inorganic double shell[J].Solar Energy Materials and Solar Cells,2022,240:111716.
[14] Methaapanon R,Kornbongkotmas S,Ataboonwongse C,et al.Microencapsulation of n-octadecane and methyl palmitate phase change materials in silica by spray drying process[J].Powder Technology,2020,361:910-916.
[15] Lin C,Ge H,Ying P,et al.Synthesis and properties of dynamic crosslinking polyurethane/PEG shape-stable phase change materials based on the Diels-Alder Reaction[J].ACS Applied Polymer Materials,2023,5(6):4190-4198.
[16] Xiao T,Liu Q,Lin Y,et al.In situ encapsulation of phase-change thermal-storage material using 3D polymer-aided cross-linked porous carbon[J].Advanced Energy and Sustainability Research,2023,4(3):2200164.
[17] Palacios A,De Gracia A,Haurie L,et al.Study of the thermal properties and the fire performance of flame retardant-organic PCM in bulk form[J].Materials,2018,11(1):117.
[18] Ma T,Li L,Wang Q,et al.High-performance flame retarded paraffin/epoxy resin form-stable phase change material[J].Journal of Materials Science,2019,54(1):875-885.
[19] Kazanci B,Cellat K,Paksoy H.Preparation,characterization,and thermal properties of novel fire-resistant microencapsulated phase change materials based on paraffin and a polystyrene shell[J].RSC Advances,2020,10(40):24134-24144.
[20] Hu Z T,Reinack V H,An J,et al.Ecofriendly microencapsulated phase-change materials with hybrid core materials for thermal energy storage and flame retardancy[J].Langmuir,2021,37(21):6380-6387.
[21] Yin L,Xie D,Gong K,et al.Phase change materials encapsulated in coral-inspired organic-inorganic aerogels for flame-retardant and thermal energy storage[J].ACS Applied Nano Materials,2023,6(10):8752-8762.
[22] Wang X,Yan M,Yu J,et al.Preparation of novel hollow metal organic framework for enhancing flame retardancy of paraffin/EP thermal energy storage materials[J].Polymer Composites,2023,DOI:10.1002/pc.27687.
[23] Yang R,Zheng N,Yu Z,et al.Nickel foam/covalent-organic frameworks for composite phase change materials with enhanced solar-thermal energy conversion and storage capacity[J].Applied Thermal Engineering,2023,230:120808.
[24] Chen X,Wang L,Gao Y,et al.Co/N co-doped flower-like carbon-based phase change materials toward solar energy harvesting[J].Aggregate,2023,DOI:10.1002/agt2.413.
[25] Liang C,Zhang W,Liu C,et al.Multifunctional phase change textiles with electromagnetic interference shielding and multiple thermal response characteristics[J].Chemical Engineering Journal,2023,471:144500.
[26] Zhou G,Zeng J,Tang S,et al.One-step bulk-suspension polymerization of polyethylene glycol-based copolymer microspheres for phase change textiles[J].Polymers,2023,15(9):2090.
[27] Zormati S,Mhiri H,Aloulou F,et al.Synthesis and characterization of organoclay and cellulose nanofibers modified with lauric acid eutectic as new phase change material (PCM) used in buildings for thermal energy storage[J].Journal of Thermal Analysis and Calorimetry,2023,148(10):3955-3964.
[28] Yin L,Zhao M,Yang R.Preparation and thermal properties of propyl palmitate-based phase change composites with enhanced thermal conductivity for thermal energy storage[J].Polymers,2023,15(15):3192.
[29] Goud V M,Satyanarayana G,Ramesh J,et al.An experimental investigation and hybrid neural network modelling of thermal management of lithium-ion batteries using a non-paraffinic organic phase change material,Myristyl alcohol[J].Journal of Energy Storage,2023,72:108395.
[30] Li S,Wu Y,Ma X,et al.Organic phase change composite separators to enhance the safety performance of lithium-ion batteries[J].Journal of Power Sources,2023,584:233620.
基金资助
“十三五”国家重点研发计划项目(2018YFD1101001);吉林省科技发展计划项目(YDZJ202302CXJD033)