碳微球/多孔VO2(B)复合材料的水热合成及其电化学性能研究

杨子1, 娄有信2, 曹晓润1, 尹蕊1, 娄广辉1, 张伟1

化工新型材料 ›› 2024, Vol. 52 ›› Issue (5) : 146 -149.

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化工新型材料 ›› 2024, Vol. 52 ›› Issue (5) : 146-149. DOI: 10.19817/j.cnki.issn1006-3536.2024.05.038
科学研究

碳微球/多孔VO2(B)复合材料的水热合成及其电化学性能研究

    杨子1, 娄有信2, 曹晓润1, 尹蕊1, 娄广辉1, 张伟1
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Hydrothermal synthesis and electrochemical properties of carbon microspheres/porous VO2(B) composite materials

  • Yang Zi1, Lou Youxin2, Cao Xiaorun1, Yin Rui1, Lou Guanghui1, Zhang Wei1
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摘要

钒氧化物及其复合材料是一种理想的锂离子电池电极材料。使用一步水热法合成了碳微球/多孔VO2(B)复合材料,采用X射线衍射仪、扫描电子显微镜和电池测试系统对该复合材料的结构、形貌和电化学性能进行了表征测试。结果表明:碳微球/多孔VO2(B)复合材料由无定型碳微球和由柔性弯曲的VO2(B)纳米条自构筑的多孔VO2(B)复合而成,当电流密度分别为0.5A/g、1A/g、2A/g和5A/g时,其放电比容量可分别达到748.4mAh/g、612.2mAh/g、457.5mAh/g和359.6mAh/g,经250次循环,其容量保持率可达90.7%(在5A/g时)。

Abstract

Vanadium oxide and its composite materials are ideal electrode materials for lithium-ion batteries.A carbon microspheres/porous VO2(B) composite material was synthesized using one-step hydrothermal method.The structure,morphology,and electrochemical properties of the composite material were characterized and tested using X-ray diffraction,scanning electron microscopy,and battery testing systems.The results showed that carbon microspheres/porous VO2(B) composite material was composed of amorphous carbon microspheres and porous VO2(B) self-constructed from flexible bent VO2(B) nanobelts.When the current densities were 0.5A/g,1A/g,2A/g,and 5A/g,the discharge specific capacities could reach 748.4mAh/g,612.2mAh/g,457.5mAh/g,and 359.6mAh/g,respectively.After 250 cycles,the capacity retention rate could reach 90.7% (at 5A/g).

关键词

碳微球 / 多孔VO2(B) / 水热法 / 电化学

Key words

carbon microspheres / porous VO2(B) / hydrothermal method / electrochemistry

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碳微球/多孔VO2(B)复合材料的水热合成及其电化学性能研究[J]. 化工新型材料, 2024, 52(5): 146-149 DOI:10.19817/j.cnki.issn1006-3536.2024.05.038

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基金资助

河南省科学院科研开发专项项目(220609099)

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