Anode material is one of the key factors to improve the electrochemical performance of lithium/sodium ion batteries.FeS2 has attracted wide attention due to its theoretical capacity of 890mAh·g-1 and low cost,but its high volume expansion rate and poor conductivity during the charge-discharge cycle hinder its use as an anode material.Recombination and nanostructure design are the effective ways to solve the above problems.This paper reviewed the research progress of FeS2-based composite materials used as anode materials of lithium/sodium ion battery,and discussed its development trend.
[1] Kim K H,Hong S H.Manganese tetraphosphide (MnP4) as a high capacity anode for lithium-ion and sodium-ion batteries[J].Advanced Energy Materials,2021,11(9):2003609.
[2] Wang B P,Lv R,Lan D S.Preparation and electrochemical properties of Sn/C composites[J].Rare Metals,2019,38(10):996-1002.
[3] Chi S S,Qi X G,Hu Y S,et al.3D flexible carbon felt host for highly stable sodium metal anodes[J].Advanced Energy Materials,2018,8(15):1702764.
[4] Li J,Han L,Li Y,et al.MXene-decorated SnS2/Sn3S4 hybrid as anode material for high-rate lithium-ion batteries[J].Chemical Engineering Journal,2020,380:122590.
[5] Park C,Kim Y H,Lee H,et al.Conductor-free anode of transition metal dichalcogenide nanosheets self-assembled with graft polymer Li-Ion channels[J].Advanced Energy Materials,2020,11(6):2003243.
[6] Hu Z,Zhang K,Zhu Z,et al.FeS2 microspheres with an ether-based electrolyte for high-performance rechargeable lithium batteries[J].Journal of Materials Chemistry A,2015,3(24):12898-12904.
[7] Zhang Y,Xu H,Li P,et al.Enhanced electrochemical performances of FeS/PC composites as anode materials for lithium-ion batteries[J].Inorganic Chemistry Communications,2022,137:109211.
[8] Liu Y,Wang W,Chen Q,et al.Resorcinol-formaldehyde resin-coated prussian blue core-shell spheres and their derived unique Yolk-Shell FeS2@C spheres for lithium-ion batteries[J].Inorganic Chemistry,2019,58(2):1330-1338.
[9] Zhou Y,Zhang M,Wang Q,et al.Pseudocapacitance boosted N-doped carbon coated Fe7S8 nanoaggregates as promising anode materials for lithium and sodium storage[J].Nano Research,2020,13(3):691-700.
[10] Wang H,Deng C,Li X,et al.Designing dual-defending system based on catalytic and kinetic iron Pyrite@C hybrid fibers for long-life room-temperature sodium-sulfur batteries[J].Chemical Engineering Journal,2021,420:129681.
[11] Wang Z,Wang Y,Chen Y,et al.Reticulate dual-nanowire aerogel for multifunctional applications:a high-performance strain sensor and a high areal capacity rechargeable anode[J].Advanced Functional Materials,2019,29(11):1807467.
[12] Wang J,Fang J,Zhao H,et al.Raspberry-like hierarchical structure FeS2 decorated by dual-carbon framework as high-performance cathode for rechargeable lithium batteries[J].Carbon,2021,171:171-178.
[13] Jing P,Wang Q,Wang B,et al.Encapsulating yolk-shell FeS2@carbon microboxes into interconnected graphene framework for ultrafast lithium/sodium storage[J].Carbon,2020,159:366-377.
[14] Du Y,Wu S,Huang M,et al.Reduced graphene oxide-wrapped pyrite as anode materials for Li-ion batteries with enhanced long-term performance under harsh operational environments[J].Chemical Engineering Journal,2017,326:257-264.
[15] He C,Li X,Zheng J,et al.A variety of carbon-coated FeS2 anodes:FeS2@CNT with excellent lithium-ion storage performance[J].Colloids and Surfaces A:Physicochemical and Engineering Aspects,2022,637:128226.
[16] Shao M,Cheng Y,Zhang T,et al.Designing MOFs-Derived FeS2@Carbon composites for high-rate sodium ion storage with capacitive contributions[J].ACS Applied Materials & Interfaces,2018,10(39):33097-33104.
[17] Yin W,Li W,Wang K,et al.FeS2@Porous octahedral carbon derived from metal-organic framework as a stable and high capacity anode for lithium-ion batteries[J].Electrochimica Acta,2019,318:673-682.
[18] Pang H,Sun W,Lv L P,et al.MOF-templated nanorice-nanosheet core-satellite iron dichalcogenides by heterogeneous sulfuration for high-performance lithium ion batteries[J].Journal of Materials Chemistry A,2016,4(48):19179-19188.
[19] Lu Z,Wang N,Zhang Y,et al.Metal-organic framework-derived sea-cucumber-like FeS2@C nanorods with outstanding pseudocapacitive Na-ion storage properties[J].ACS Applied Energy Materials,2018,1(11):6234-6241.
[20] Xie Z,Zhang L,Li L,et al.A ternary FeS2/Fe7S8@nitrogen-sulfur co-doping reduced graphene oxide hybrid towards superior-performance lithium storage[J].Progress in Natural Science:Materials International,2021,31(2):207-214.
[21] Je J,Lim H,Jung H W,et al.Ultrafast and ultrastable heteroarchitectured porous nanocube anode composed of CuS/FeS2 embedded in nitrogen-doped carbon for use in sodium-ion batteries[J].Small,2022,18(6):e2105310.
[22] Xu X X,Li L J,Chen H Q,et al.Constructing heterostructured FeS2/CuS nanospheres as high rate performance lithium ion battery anodes[J].Inorg Chem Front,2020,7(9):1900-1908.
[23] Liu Q,Zhang S J,Xiang C C,et al.Cubic MnS-FeS2 composites derived from a prussian blue analogue as anode materials for sodium-ion batteries with long-term cycle stability[J].ACS Applied Materials & Interfaces,2020,12(39):43624-43633.
[24] Yue L,Wu D,Wu Z,et al.A MnS/FeS2 heterostructure with a high degree of lattice matching anchored into carbon skeleton for ultra-stable sodium-ion storage[J].Journal of Materials Chemistry A,2021,9(42):24024-24035.
[25] Yuvaraj S,Veerasubramani G K,Park M S,et al.Facile synthesis of FeS2/MoS2 composite intertwined on rGO nanosheets as a high-performance anode material for sodium-ion battery[J].Journal of Alloys and Compounds,2020,821:153222.
[26] Li G,Cao S,Fu L,et al.A two-step hydrothermal synthesis of TiO2/C/FeS2 composite as high performance anode for lithium ion batteries[J].Electrochimica Acta,2021,386:138470.
[27] Song X,Li X,Chen Z,et al.A simple synthesized N-doped FeS2/Fe3O4@C nanocomposite as anode for sodium ion batteries[J].Materials Letters,2020,275:128109.
[28] Du C F,Liang Q,Zheng Y,et al.Porous MXene frameworks support pyrite nanodots toward high-rate pseudocapacitive Li/Na-ion storage[J].ACS Applied Materials & Interfaces,2018,10(40):33779-33784.
基金资助
国家自然科学基金(52102289);山西省重点研发计划项目(201803D421089);山西浙大新材料与化工研究院研发项目(2021SX-FR001)
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