一种稳固的SiO2/PDMS超疏水涂层的制备与稳定性研究

宁浩良, 尚佳佳, 苏诗超, 彭淑鸽*

化工新型材料 ›› 2024, Vol. 52 ›› Issue (5) : 258 -263.

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化工新型材料 ›› 2024, Vol. 52 ›› Issue (5) : 258-263. DOI: 10.19817/j.cnki.issn1006-3536.2024.05.012
开发与应用

一种稳固的SiO2/PDMS超疏水涂层的制备与稳定性研究

    宁浩良, 尚佳佳, 苏诗超, 彭淑鸽*
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Preparation of a robust SiO2/PDMS superhydrophobic coating and stability performance study

  • Ning Haoliang, Shang Jiajia, Su Shichao, Peng Shuge
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摘要

为了提高超疏水涂层的稳定性,构筑良好的界面是关键。本研究选取并制备了一种硅烷偶联剂改性的SiO2纳米粒子(KH570-SiO2),不仅能在聚二甲基硅氧烷(PDMS)分散液中良好分散,还能与PDMS链之间通过共价键链接;通过一步喷涂并完全固化后在玻璃表面构筑了一个改性SiO2/PDMS超疏水涂层。利用扫描电镜、红外光谱、接触角等多种方式对改性SiO2/PDMS涂层的形貌、结构及表面性质进行分析;并通过划格法、砂纸摩擦及胶带剥离实验对SiO2/PDMS涂层的机械稳定性进行评价,最后探讨了涂层的稳定性机制。结果表明,改性SiO2/PDMS涂层具有优异的超疏水性及机械稳定性。本研究为在材料表面构筑稳定的超疏水涂层提供了一种新方法,有望扩展材料在自清洁、防腐涂层、管道运输、油水分离等领域的应用。

Abstract

To improve the stability of superhydrophobic coatings,the construction of excellent interfaces is the key.This work adopted the strategy of optimizing the interface structure and prepared a silane coupling agent-modified SiO2 nanoparticles (KH570-SiO2),which could not only disperse well in PDMS dispersion solution,but also form covalently bonds with PDMS chain.Then,a modified SiO2/PDMS superhydrophobic coating was constructed on the glass surface by spraying method and fully cured.The morphology,microstructure,and surface characteristics of the modified SiO2/PDMS coating were investigated by scanning electron microscope (SEM),Fourier transform infrared spectroscopy (FT-IR),contact angle measuring instrument (CA) and so on.The mechanical stability of the SiO2/PDMS coating was evaluated by the experiments of marking,sandpaper wear and tape stripping.Finally,the stability mechanism of the coating was discussed.The results indicated that the modified SiO2/PDMS coating exhibited excellent superhydrophobicity and mechanical stability.This study provided a new method for constructing stable superhydrophobic coatings on the surface of materials,which was expected to expand the application of materials in self-cleaning,anticorrosive coating,pipeline transportation,oil-water separation and other fields.

关键词

超疏水涂层 / 聚二甲基硅氧烷 / KH570改性二氧化硅 / R972 / DNS-1

Key words

superhydrophobic coating / PDMS / KH570-SiO2 / R972 / DNS-1

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引用格式 ▾
一种稳固的SiO2/PDMS超疏水涂层的制备与稳定性研究[J]. 化工新型材料, 2024, 52(5): 258-263 DOI:10.19817/j.cnki.issn1006-3536.2024.05.012

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基金资助

国家自然科学基金(22175057);河南科技大学SRTP项目(2022195)

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