化工新型材料

化工新型材料 ›› 2024, Vol. 52 ›› Issue (5) : 34-39. DOI: 10.19817/j.cnki.issn1006-3536.2024.05.004

综述与专论

共价有机框架材料用于光催化产H₂O₂研究进展

作者信息 +

Research progress of covalent organic framework materials for photocatalytic production of H₂O₂

Xu Mingyang, Bian Heng, Zhang Shuai, Wang Minghua, He Linghao

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文章历史 +

Received		Published
2023-01-29		2024-05-20
Issue Date	Revised Date
2024-05-28	2023-01-29

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摘要

过氧化氢(H₂O₂)作为一种环境友好型材料近年来备受关注,光催化作为一种潜在的技术用于H₂O₂生产时,不仅可以方便地将太阳能转化为化学能节约能源,而且在环境治理方面具有重要作用。与传统催化剂相比,共价有机框架(COFs)材料作为一种有机光催化剂,在可见光捕获、多孔结构、光化学稳定性和疏水性等方面具有明显的优势,其多孔结构不仅为催化反应提供了丰富的活性位点,还可以在多次循环后保持原始结构。更重要的是COFs材料设计的灵活性和合成方法的多样性,不仅可以预先设计明确的功能化结构用于光催化反应,还可以修饰功能化基团用于提高性能。介绍了光催化产H₂O₂的反应机理及检测H₂O₂的常用方法,综述了COFs材料在光催化产H₂O₂方面的优势以及提高COFs材料催化性能的方法。

Abstract

Hydrogen peroxide (H₂O₂),as an environment-friendly material,has attracted much attention in recent years.As a potential technology for the production of H₂O₂,photocatalysis can not only easily convert solar energy into chemical energy to save energy,but also has important significance in environmental governance.Compared with traditional catalysts,covalent organic frameworks (COFs),as organic photocatalysts,have outstanding advantages in visible light capture,porous structure,photochemical stability and hydrophobicity.The porous structure of COFs not only provides rich activation sites for catalytic reactions,but also can maintain their original structure after multiple cycles.More importantly,the flexibility of COFs material design and the diversity of synthesis methods of COFs can not only pre-design specific functional structures for photocatalytic reactions,but also modify functional groups to improve performance.Therefore,this article introduced the reaction mechanism of photocatalytic production of H₂O₂ and common methods for detecting H₂O₂.It summarized the advantages of COFs materials in photocatalytic production of H₂O₂ and the methods to improve the catalytic performance of COFs materials.

关键词

共价有机框架材料 / 过氧化氢 / 光催化剂

Key words

covalent organic framework materials / hydrogen peroxide / photocatalyst

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共价有机框架材料用于光催化产H₂O₂研究进展[J]. 化工新型材料, 2024, 52(5): 34-39 DOI:10.19817/j.cnki.issn1006-3536.2024.05.004

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基金资助

河南省优秀青年基金(202300410494)

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