基于二氧化锰纳米材料的COD去除性能及动力学行为研究

马春蕾, 王千慧, 郭江锐, 徐妍, 贾瑞思, 王琦

化工新型材料 ›› 2024, Vol. 52 ›› Issue (4) : 166 -171.

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化工新型材料 ›› 2024, Vol. 52 ›› Issue (4) : 166-171. DOI: 10.19817/j.cnki.issn1006-3536.2024.04.038
科学研究

基于二氧化锰纳米材料的COD去除性能及动力学行为研究

    马春蕾, 王千慧, 郭江锐, 徐妍, 贾瑞思, 王琦
作者信息 +

The COD removal performance and kinetic behavior of MnO2 nanomaterials

  • Ma Chunlei, Wang Qianhui, Guo Jiangrui, Xu Yan, Jia Ruisi, Wang Qi
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摘要

采用脱脂棉(DC)作为模板和还原剂,通过原位氧化还原反应温和制备DC负载的MnO2纳米颗粒(MnO2 NPs/DC),并对其形貌、组成进行表征。以骨胶模拟废水提供化学需氧量(COD)。利用MnO2 NPs/DC优异的吸附及催化氧化活性和DC的操作便捷性,进一步探究MnO2 NPs/DC对COD的去除性能。结果表明:MnO2 NPs较为均匀地分散于DC纤维表面。室温条件下通过简单的浸泡搅拌,MnO2 NPs/DC对COD仅21min的去除率可达64.03%,并且可通过增加材料用量和材料浸泡时间来提高去除率。动力学模型拟合结果表明,MnO2 NPs/DC对COD的去除过程更符合拟二级动力学模型。

Abstract

Degreased cotton (DC) was used as template and reducing agent to gently prepare DC-supported MnO2 nanoparticles (MnO2 NPs/DC) by in-situ redox reaction.The morphology and composition of MnO2 NPs/DC were characterized.Chemical oxygen demand (COD) was provided by simulating wastewater with bone glue.Leveraging the excellent adsorption and catalytic oxidation activities of MnO2 NPs/DC and the convenient operation performance of DC,the removal performance of MnO2 NPs/DC for COD was further explored.The experimental results showed that MnO2 NPs was dispersed evenly on the surface of DC fibers.The removal rate of COD by MnO2 NPs/DC could reach 64.03% in only 21 min by simple soaking and stirring at room temperature,and the removal rate could be improved by increasing the amount of material and soaking time.The kinetic model fitting results indicated that the removal process of COD by MnO2 NPs/DC was more consistent with the pseudo-second-order kinetic model.

关键词

脱脂棉 / 二氧化锰纳米颗粒 / 化学需氧量 / 去除

Key words

degreased cotton / MnO2 nanomaterials / COD / removal

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基于二氧化锰纳米材料的COD去除性能及动力学行为研究[J]. 化工新型材料, 2024, 52(4): 166-171 DOI:10.19817/j.cnki.issn1006-3536.2024.04.038

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基金资助

2023年山西省高等学校科技创新项目(2023L337);太原工业学院国家级大学生创新创业训练计划(20231138)

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