化工新型材料

化工新型材料 ›› 2024, Vol. 52 ›› Issue (4) : 69-73. DOI: 10.19817/j.cnki.issn1006-3536.2024.04.021

综述与专论

钠离子电池硒化钴负极材料制备方法及改性研究进展

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作者信息 +

Research progress on preparation and modification of cobalt selenide anode materials for sodium-ion batteries

Kang Jianglong¹, Yuan Yongxiang¹, Xi Ruheng¹, Hou Xiaoyi²

Author information +

文章历史 +

Received		Published
2022-12-17		2024-04-20
Issue Date	Revised Date
2024-05-07	2022-12-17

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摘要

硒化钴(CoSe₂)因具有较高的理论容量,被认为是极具潜在价值的钠离子电池(SIBs)负极材料。但CoSe₂负极材料在充放电过程中体积膨胀严重且充放电性能差,影响了电池的实际应用。针对CoSe₂材料应用于钠离子电池负极中存在的问题,主要从材料晶体结构及储钠机理、制备工艺、改性研究(纳米结构调控、杂原子掺杂、材料复合化)等方面入手,概述了国内外研究学者将CoSe₂应用于钠离子电池负极材料的设计研究进展。最后,立足于当下CoSe₂负极材料研究现状,阐述了其在某些方面存在的问题,以及仍需努力的方向。

Abstract

Cobalt selenide (CoSe₂) is considered a potential anode material for sodium-ion batteries (SIBs) due to its high theoretical capacity.However,CoSe₂ anode material has serious volume expansion and poor charge-discharge performance during the charge-discharge process,which hinders its practical application in battery.In view of the existing problems in the application of CoSe₂ material in sodium-ion battery anodes,mainly from the perspectives of the crystal structure,sodium storage mechanism,preparation process,and modification research (nanostructure control,heteroatom doping and material compounding) of CoSe₂ material,the design and research progress of CoSe₂ used as an anode material for sodium-ion batteries by domestic and foreign researchers was reviewed.Finally,based on the current research status of CoSe₂ anode materials,the existing problems in some aspects and the research direction that still needed to be worked on were expounded.

关键词

钠离子电池 / 负极材料 / 硒化钴 / 制备方法 / 电化学性能

Key words

sodium-ion battery / anode material / CoSe₂ / preparation method / electrochemical performance

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钠离子电池硒化钴负极材料制备方法及改性研究进展[J]. 化工新型材料, 2024, 52(4): 69-73 DOI:10.19817/j.cnki.issn1006-3536.2024.04.021

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