Lignocellulose nanofibrils (LCNFs) were prepared from wheat straw using p-TsOH combined with enzymatic-assisted ultrasonic treatment,and then LCNFs filter membrane (LCNF-FM) was prepared by vacuum filtration.The microstructure,pure water flux,wettability and filtration performance against micro-nano particles of the LCNF-FM were studied.The results showed that LCNF-FM was composed of cross-linked nanofiber networks with an average pore diameter of 30.2nm.The filter membrane had good retention effect on both bacteria and TiO2 nanoparticles.LCNF-FM was preliminarily used to filtrate red wine,and the retention rate of effective ingredients in red wine was above 84% without affecting the wine quality significantly.This paper provided a green and environmental method to prepare LCNFs and corresponding filter membrane,which had a great potential for applications in the utilization of agricultural waste resources,as well as in water treatment,food and beverage purification and so on.
[1] 孔金凤,朱玉长,靳健.磺化纤维素纳米纤维多孔膜支撑的高通量纳滤膜的制备及脱盐性能[J].高等学校化学学报,2020,41(4):690-696.
[2] Priyanka R S,Sunil K S,Lindström T,et al.Nanocellulose-enabled membranes for water purification:perspectives[J].Advanced Sustainable Systems,2020,4(5):1-28.
[3] Voisin H,Bergström L,Liu P,et al.Nanocellulose-based materials for water purification[J].Nanomaterials,2017,7(3):57.
[4] Carpenter A W,De Lannoy C F,Wiesner M R.Cellulose nanomaterials in water treatment technologies[J].Environmental Science and Technology,2015,49(9):5277-5287.
[5] Sharma P R,Sharma S K,Lindström T,et al.Nanocellulose-enabled membranes for water purification:perspectives[J].Advanced Sustainable Systems,2020,4(5):1-28.
[6] Amiralian N,Annamalai P K,Memmott P,et al.Isolation of cellulose nanofibrils from Triodiapungens via different mechanical methods[J].Cellulose,Springer Netherlands,2015,22(4):2483-2498.
[7] Liang Y,Ma H,Taha A,et al.High-flux anti-fouling nanofibrous composite ultrafiltration membranes containing negatively charged water channels[J].Journal of Membrane Science,2020,612(15):118382.
[8] Thakur V K,Voicu S I.Recent advances in cellulose and chitosan based membranes for water purification:a concise review[J].Carbohydrate Polymers,Elsevier Ltd,2016,146:148-165.
[9] Suman,Kardam A,Gera M,et al.A novel reusable nanocomposite for complete removal of dyes,heavy metals and microbial load from water based on nanocellulose and silver nano-embedded pebbles[J].Environmental Technology (United Kingdom),2015,36(6):706-714.
[10] Wang Y S,Wang J L,Lin S J,et al.Wood-derived nanofibrillated cellulose hydrogel filters for fast and efficient separation of nanoparticles[J].Advanced Sustainable Systems,2019,3(9):1900063.
[11] Wang R,Guan S,Sato A,et al.Nanofibrous microfiltration membranes capable of removing bacteria,viruses and heavy metal ions[J].Journal of Membrane Science,2013,446:376-382.
[12] Metreveli G,Wagberg L,Emmoth E,et al.A size-exclusion nanocellulose filter paper for virus removal[J].Advanced Healthcare Materials,2014,3(10):1546-1550.
[13] Sehaqui H,de Larraya U P,Liu P,et al.Enhancing adsorption of heavy metal ions onto biobased nanofibers from waste pulp residues for application in wastewater treatment[J].Cellulose,2014,21(4):2831-2844.
[14] Sehaqui H,Zimmermann T,Tingaut P.Hydrophobic cellulose nanopaper through a mild esterification procedure[J].Cellulose,2014,21(1):367-382.
[15] Mautner A,Lee K Y,Lahtinen P,et al.Nanopapers for organic solvent nanofiltration[J].Chemical Communications,2014,50(43):5778-5781.
[16] 杨明琰,陈欣玥,张笑,等.双醛纤维素/聚乙烯醇复合水凝胶的制备及其性能[J].复合材料学报,2022,39(10):4889-4897.
[17] Yang M Y,Zhang X,Guan S Y,et al.Preparation of lignin containing cellulose nanofibers and its application in PVA nanocomposite films[J].International Journal of Biological Macromolecules,2020,158(3):1259-1267.
[18] Chinomso M E,Liu X R,Wu M W,et al.Lignin-containing cellulose nanomaterials:a promising new nanomaterial fornumerous applications[J].Journal of Bioresources and Bioproducts,2019,4(1):3-10.
[19] 王栩林,张景.保健食品中总黄酮的测定[J].食品安全导刊,2016,3:121-122.
[20] 李诗.纤维素纳滤膜的制备与表征及其在饮用水深度处理方面的应用[D].福州:福建农林大学,2018.
[21] Gopakumar D A,Manna S,Pasquini D,et al.New polymer nanocomposites for environmental remediation[M].Amsterdam:Elsevier,2018:469-486.
[22] Simon G,Frank W,Tobias H,et al.Comparative analysis of dry and wet porometry methods for characterization of regular and cross-linked virus removal filter papers[J].Membranes,2019:9(1):1-13.
基金资助
陕西省重点研发计划(2021SF-443)