以聚酯纤维为研究对象,对其进行了表面电气石负载改性整理,以增加聚酯纤维的远红外辐射率和负离子释放等功能。采用单因素分析法分别探讨了时间、硅烷偶联剂用量及温度对聚酯纤维改性整理效果的影响。结果表明:聚酯纤维最佳改性整理工艺条件为1g聚酯短纤维浸泡在含有电气石的硅烷偶联剂酸性溶液中,于50℃烘箱中静置反应6h时,电气石负载率可达1.71%。对所得改性整理纤维进行表征及性能测试,电气石粉体成功引入到了聚酯纤维表面,其远红外辐射率达0.7,负离子释放量为950ions/cm3。
Polyester fiber was taken as the research object,and tourmaline was loaded on its surface to increase the far-infrared radiation rate and enhance the release of negative ions.The influence of reaction time,the amount of silane coupling agent and reaction temperature on the modification and treatment effect of polyester fiber was investigated by single factor analysis method.The results indicated that the optimum modification conditions for polyester fibers were as follows:1 gram of polyester staple fibers were immersed in an acidic solution containing tourmaline and silane coupling agent,reacted in an oven at 50℃ for 6h,and the tourmaline loading rate reached 1.71%.The obtained modified fibers were characterized and tested.The results showed that tourmaline powder was successfully introduced into the surface of polyester fibers,with a far-infrared radiation rate of 0.7 and a negative ion release amount of 950 ions/cm3.
[1] 崔奎,胡应模.电气石功能复合材料研究进展[J].化工新型材料,2021,49(S1):30-34.
[2] 文圆,黄惠宁,张国涛,等.电气石性能与应用研究发展[J].陶瓷,2019(2):17-24.
[3] Gao Z,Liang J,Zhang H,et al.Strengthening mechanism of far-infrared radiation of tourmaline in iron-tailing ceramics[J].Ceramics International,2021,47(18):25214-25220.
[4] Zhang H,Xu Y,Lei Y,et al.Tourmaline nanoparticles modifying hemostatic property of chitosan/polyvinyl alcohol hydrogels[J].Materials Letters,2022,324:132718.
[5] Fan M,Chen X,Zhou Y,et al.Improved bioactivity on substrate degradation in microbial fuel cells using tourmaline-modified anodes[J].Journal of Environmental Engineering,2019,145(5):06019003.
[6] Xue G,Luo X,Srinivasakannan C,et al.Effective removal of organic dye and heavy metal from wastewater by tourmaline/graphene oxide composite nano material[J].Materials Research Express,2019,6(11):115618-115618.
[7] Qi S Y,Zhao Y D,Ma N L,et al.Photocatalytic mechanism of tourmaline/BiVO4 composites with different ratios[J].Inorganic and Nano-Metal Chemistry,2020,50(1):28-34.
[8] Bi Y,Li R,Guo F,et al.Photocatalytic purification of vehicle exhaust using CeO2-Bi2O3 loaded on white carbon and tourmaline[J].Environmental Science and Pollution Research,2021,28(14):17724-17738.
[9] Yao Y,Li M,Lackner M,et al.A continuous fiber-reinforced additive manufacturing processing based on PET fiber and PLA[J].Materials,2020,13(14):3044.
[10] Addis S,Ejegu H,Dubale M,et al.Development of sustainable and functional fabrics from recycled and nanocomposite polyester fibers[J].Advances in Materials Science and Engineering,2021,2021:1-12.
[11] Zhao C,Jin X,Ruan F,et al.Recycled high performance polyester fibers for cement designed from micromechanics theory[J].Journal of Polymer Research,2021,28(12):1-8.
[12] Vachirapanyakun S,Lim M K,Choi D U.Seismic performance of circular RC columns retrofitted using ductile PET fibers[J].Journal of the Korea Concrete Institute,2016,28(3):289-298.
[13] Niraj S P,Rajesh P S,Ashok K G.Shear strength of medium plastic expansive soil reinforced with polyester fibers[J].Slovak Journal of Civil Engineering,2018,26(2):1-8.
[14] Mohammed Q I,Hiba M Al-Taher.Reinforcement of asphalt concrete by polyester fibers to improve flexural bending fatigue resistance[J].Engineering Journal,2015,21(1):115-130.
[15] Qian Y,Wei P,Jiang P K,et al.Preparation of hybrid phosphamide containing polysilsesquioxane and its effect on flame retardancy and mechanical properties of polypropylene composites[J].Composites Part B,2013,45(1):1541-1547.
[16] 窦午红,刘东月,王文涛,等.新型P-N-Si无卤阻燃剂的合成及其在棉纤维中的应用[J].合成化学,2016,24(2):107-111.
[17] 顾伟,吴亚容,周翔,等.含磷氮硅阻燃剂的合成及涤纶织物阻燃抗熔滴整理[J].印染,2019,45(2):1-6.
[18] 赵江惠,王勇,刘志.涤纶织物表面改性方法研究进展[J].棉纺织技术,2021,49(1):81-84.
[19] 宋路明,李淳,牟效泉.石油工业用抗静电过滤布的开发[J].纺织学报,2005,26(2):130-132.
[20] 章梦洁,伍仲,方园.涤棉混纺织物阻燃性能的实验分析[J].浙江理工大学学报,2013,30(1):36-39.
基金资助
国家自然科学基金(52272094)