水性苯丙吸波涂层的制备与性能研究

冯佳勇1, 韩晓飞1, 张志毅1,2, 余雯雯1,2, 贾兰1,2, 何宏伟1,2*

化工新型材料 ›› 2024, Vol. 52 ›› Issue (3) : 139 -145.

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化工新型材料 ›› 2024, Vol. 52 ›› Issue (3) : 139-145. DOI: 10.19817/j.cnki.issn1006-3536.2024.03.036
新材料与新技术

水性苯丙吸波涂层的制备与性能研究

    冯佳勇1, 韩晓飞1, 张志毅1,2, 余雯雯1,2, 贾兰1,2, 何宏伟1,2*
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Preparation and performance study of waterborne styrene-acrylate wave-absorbing coating

  • Feng Jiayong1, Han Xiaofei1, Zhang Zhiyi1,2, Yu Wenwen1,2, Jia Lan1,2, He Hongwei1,2
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摘要

吸波涂料是一种能够吸收和衰减入射电磁波的功能涂料,而水性吸波涂料更具有环保健康的特点。选择炭黑和羰基铁粉作为复合吸波剂,加入水性苯丙乳液中制备成本较低的复合吸波涂层。首先测试了炭黑和羰基铁粉的电磁参数,并计算得出成分为12%炭黑和70%羰基铁粉,厚度为2mm时吸波性能最佳,反射损耗优于-5dB的有效吸收频宽达到9.9GHz,反射损耗峰值达到-28.6dB。然后制备了含12%炭黑和70%羰基铁粉,厚度为2mm的苯丙吸波涂层,测试分析了苯丙吸波涂层的吸波性能以及涂料相关性能。

Abstract

Wave-absorbing coating is a kind of functional coating that can absorb and attenuate incident electromagnetic waves,while waterborne wave-absorbing coating has more environmental protection and health characteristics.In this paper,carbon black and carbonyl iron powder were selected as composite absorbers,and a low-cost composite wave-absorbing coating was prepared by adding them to aqueous styrene acrylic emulsion.Firstly,the electromagnetic parameters of carbon black and carbonyl iron powder were tested.It was calculated that the optimal absorption performance was achieved with the composition of 12% carbon black and 70% carbonyl iron powder at a thickness of 2mm,the effective absorption bandwidth of reflection loss was better than -5dB and reached 9.9GHz,and the peak reflection loss reached -28.6dB.Then,a styrene-acrylate wave-absorbing coating containing 12% carbon black and 70% carbonyl iron powder with a thickness of 2mm was prepared,and the wave absorption performance of the composite coating and the related coating properties were investigated.

关键词

炭黑 / 羰基铁粉 / 苯丙乳液 / 电磁参数 / 吸波涂层 / 吸波性能

Key words

carbon black / carbonyl iron powder / styrene-acrylic emulsion / electromagnetic parameters / wave-absorbing coating / absorption performance

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水性苯丙吸波涂层的制备与性能研究[J]. 化工新型材料, 2024, 52(3): 139-145 DOI:10.19817/j.cnki.issn1006-3536.2024.03.036

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参考文献

[1] Duan Y,Liu Y,Cui Y,et al.Graphene to tune microwave absorption frequencies and enhance absorption properties of carbonyl iron/polyurethane coating[J].Progress in Organic Coatings,2018,125:89-98.
[2] Song W L,Wang J,Fan L Z,et al.Interfacial engineering of carbon nanofiber-graphene-carbon nanofiber heterojunctions in flexible lightweight electromagnetic shielding networks[J].ACS Applied Materials & Interfaces,2014,6(13):10516-10523.
[3] Zheng X,Feng J,Zong Y,et al.Hydrophobic graphene nanosheets decorated by monodispersed superparamagnetic Fe3O4 nanocrystals as synergistic electromagnetic wave absorbers[J].Journal of Materials Chemistry C,2015,3(17):4452-4463.
[4] 陶睿,刘朝辉,班国东,等.碳纤维粉-羰基铁粉复合材料的吸波性能及在涂层中的应用[J].电镀与涂饰,2017,36(22):1205-1210.
[5] 张明伟,曲冠达,庞梦瑶,等.电磁屏蔽机理及涂敷/结构型吸波复合材料研究进展[J].材料导报,2021,35(Z1):62-70.
[6] Cao M,Han C,Wang X,et al.Graphene nanohybrids:excellent electromagnetic properties for the absorbing and shielding of electromagnetic waves[J].Journal of Materials Chemistry C,2018,6(17):4586-4602.
[7] Oh J H,Oh K S,Kim C G,et al.Design of radar absorbing structures using glass/epoxy composite containing carbon black in X-band frequency ranges[J].Composites Part B:Engineering,2004,35(1):49-56.
[8] Schueler R,Petermann J,Schulte K,et al.Agglomeration and electrical percolation behavior ofcarbon black dispersed in epoxy resin[J].Journal of Applied Polymer Science,1997,63(13):1741-1746.
[9] Ling Q,Sun J,Zhao Q,et al.Microwave absorbing properties of linear low density polyethylene/ethylene-octene copolymer composites filled with short carbon fiber[J].Materials Science and Engineering:B,2009,162(3):162-166.
[10] 李晓光,吕华良,姬广斌,等.球磨钢珠配比对片状羰基铁粉吸波性能影响的研究[J].航空材料学报,2013,33(5):46-53.
[11] Cao X G,Ren H,Zhang H Y.Preparation and microwave shielding property of silver-coated carbonyl iron powder[J].Journal of Alloys and Compounds,2015,631:133-137.
[12] 王顺顺,张喆,王霏,等.环氧基复合吸波涂层的制备与性能研究[J].表面技术,2022,51(4):325-34.
[13] 刘立东,段玉平,陈利阳,等.羰基基铁粉/炭黑复合吸波涂层性能的研究[C].长沙:第七届中国功能材料及其应用学术会议,2010.
[14] 冯雪峰,李西营,陈蔚萍,等.苯丙乳液合成反应条件优化[J].化学研究,2014,25(2):181-186.
[15] Zheng D,Liu T,Zhou L,et al.Electromagnetic absorbing property of the flaky carbonyl iron particles by chemical corrosion process[J].Journal of Magnetism and Magnetic Materials,2016,419:119-124.
[16] Zhang X F,Dong X L,Huang H,et al.Microstructure and microwave absorption properties of carbon-coated iron nanocapsules[J].Journal of Physics D:Applied Physics,2007,40(17):5383-5387.
[17] 林媛.羰基铁粉的电磁波吸收性能[J].安全与电磁兼容,2019(3):55-58.
[18] Zeng J,Xu J,Tao P,et al.Ferromagnetic and microwave absorption properties of copper oxide-carbon fiber composites[J].Journal of Alloys and Compounds,2009,487(1-2):304-308.
[19] Cao L,Jiang J T,Wang Z Q,et al.Electromagnetic properties of flake-shaped Fe-Si alloy particles prepared by ball milling[J].Journal of Magnetism and Magnetic Materials,2014,368:295-299.
[20] Wu J,Ye Z,Ge H,et al.Modified carbon fiber/magnetic graphene/epoxy composites with synergistic effect for electromagnetic interference shielding over broad frequency band[J].J Colloid Interface Sci,2017,506:217-226.
[21] 周璐,付志强,吕幼军,等.聚酰亚胺/羰基铁粉吸波包装材料性能分析[J].包装工程,2021,42(11):81-86.

基金资助

山西浙大新材料与化工研究院研发项目(2022SX-TD022和2021SX-TD008);山西省“1331工程”资助(晋政发〔2021〕3号);山西省自然科学研究面上项目(202103021224102);山西省重点研发项目(202102040201011)

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