聚丁二酸-共-对苯二甲酸丁二醇酯/氧化镁复合薄膜的制备及性能

张佳宁1,2, 郭睿劼1,2, 张杰1,2

化工新型材料 ›› 2024, Vol. 52 ›› Issue (3) : 253 -256.

PDF
化工新型材料 ›› 2024, Vol. 52 ›› Issue (3) : 253-256. DOI: 10.19817/j.cnki.issn1006-3536.2024.03.033
开发与应用

聚丁二酸-共-对苯二甲酸丁二醇酯/氧化镁复合薄膜的制备及性能

    张佳宁1,2, 郭睿劼1,2, 张杰1,2
作者信息 +

Preparation and properties of poly (butylene succinate-co-terephthalate)/ magnesium oxide composite film

  • Zhang Jianing1,2, Guo Ruijie1,2, Zhang Jie1,2
Author information +
文章历史 +
PDF

摘要

以聚丁二酸-共-对苯二甲酸丁二醇酯(PBST)为基体,纳米氧化镁(MgO NPs)为抗菌剂,通过溶剂挥发法制备了PBST/MgO纳米复合薄膜,并探讨了复合薄膜在食品包装中的应用。研究了MgO NPs对纳米复合薄膜的机械性能、水蒸汽透过率(WVP)、氧气透过率(OTR)和紫外阻隔性能的影响。结果表明:MgO NPs的加入改善了PBST基体的力学性能和阻隔性能。与PBST薄膜相比,复合膜的拉伸强度和断裂伸长率分别提高了43.7%和32.2%,水蒸汽透过率和氧气透过率分别降低了28.1%和23.6%,并具有良好的紫外阻隔性能。当MgO NPs质量含量为5%时,复合膜的性能最佳。

Abstract

Poly(butylene succinate-co-terephthalate) (PBST)/magnesium oxide (MgO) nanocomposite films were prepared via a solvent evaporation method using PBST as a matrix and MgO NPs as an antibacterial agent.The application of PBST/MgO nanocomposite films in food packaging was explored.The effects of MgO NPs on the mechanical properties,water vapor transmittance (WVP),oxygen transmittance (OTR) and UV barrier properties of nanocomposite films were investigated.The results showed that the addition of MgO NPs improved the mechanical and barrier properties of PBST matrix.Compared with PBST film,the tensile strength and elongation at break of the composite film were increased by 43.7% and 32.2%,respectively,and the WVP and OTR were reduced by 28.1% and 23.6%,respectively.When the content of MgO NPs was 5wt%,the composite film had the best performance.

关键词

聚丁二酸-共-对苯二甲酸丁二醇酯 / 纳米氧化镁 / 溶剂挥发法 / 食品包装

Key words

poly(butylene succinate-co-terephthalate) / nano magnesium oxide / solvent evaporation method / food packaging

引用本文

引用格式 ▾
聚丁二酸-共-对苯二甲酸丁二醇酯/氧化镁复合薄膜的制备及性能[J]. 化工新型材料, 2024, 52(3): 253-256 DOI:10.19817/j.cnki.issn1006-3536.2024.03.033

登录浏览全文

4963

注册一个新账户 忘记密码

参考文献

[1] Hufendiek A,Lingier S,Du Prez F E.Thermoplastic polyacetals:chemistry from the past for a sustainable future?[J].Polymer Chemistry,2019,10(1):9-33.
[2] Zhang J,Li F X,Yu J Y.Non-isothermal crystallization behavior of biodegradable poly(butylene succinate-co-terephthalate)(PBST) copolyesters[J].Thermal Science,2012,16(5):1480-1483.
[3] Wang X,Cui L,Fan S,et al.Biodegradable poly(butylene adipate-co-terephthalate) antibacterial nanocomposites reinforced with MgO nanoparticles[J].Polymers (Basel),2021,13(4):507.
[4] Jia J,Yang J,Zhao Y,et al.The crystallization behaviors and mechanical properties of poly(l-lactic acid)/magnesium oxide nanoparticle composites[J].RSC Advances,2016,6(50):43855-43863.
[5] Hoseinnejad M,Jafari S M,Katouzian I.Inorganic and metal nanoparticles and their antimicrobial activity in food packaging applications[J].Critical Reviews in Microbiology,2018,44(2):161-181.
[6] Zhang J,Wang X,Li F,et al.Mechanical properties and crystal structure transition of biodegradable poly(butylene succinate-co-terephthalate)(PBST) fibers[J].Fibers and Polymers,2012,13(10):1233-1238.
[7] Yu H K,Lee J L.Growth mechanism of MgO film on Si(100):domain matching epitaxy,strain relaxation,preferred orientation ormation[J].Crystal Growth & Design,2010,10(12):5200-5204.
[8] Lan W,Wang S,Zhang Z,et al.Development of red apple pomace extract/chitosan-based films reinforced by TiO2 nanoparticles as a multifunctional packaging material[J].International Journal of Biological Macromolecules,2021,168:105-115.
[9] Cao C,Wang Y,Zheng S,et al.Poly (butylene adipate-co-terephthalate)/titanium dioxide/silver composite biofilms for food packaging application[J].LWT,2020,132:109874.
[10] Lu J,Wu L B,Li B G.Long chain branched poly(butylene succinate-co-terephthalate) copolyesters using pentaerythritol as branching agent:synthesis,thermo-mechanical,and rheological properties[J].Journal of Applied Polymer Science,2017,134(9):44544.
[11] Liu J,Shen J,Zheng Z,et al.Revealing the toughening mechanism of graphene-polymer nanocomposite through molecular dynamics simulation[J].Nanotechnology,2015,26(29):291003.
[12] Swaroop C,Shukla M.Nano-magnesium oxide reinforced polylactic acid biofilms for food packaging applications[J].International Journal of Biological Macromolecules,2018,113:729-736.[13] Etemadi H,Yegani R,Babaeipour V.Study on the reinforcing effect of nanodiamond particles on the mechanical,thermal and antibacterial properties of cellulose acetate membranes[J].Diamond and Related Materials,2016,69:166-176.
[14] Li Y,Tang C,He Q.Effect of orange (Citrus sinensis L.) peel essential oil on characteristics of blend films based on chitosan and fish skin gelatin[J].Food Bioscience,2021,41:100927.
[15] Swaroop C,Shukla M.Nano-magnesium oxide reinforced polylactic acid biofilms for food packaging applications[J].International Journal of Biological Macromolecules,2018,113:729-736.
[16] Mihindukulasuriya S D F,Lim L T.Nanotechnology development in food packaging:a review[J].Trends in Food Science & Technology,2014,40(2):149-167.
[17] Zinck P,Mäder E,Gerard J F.Role of silane coupling agent and polymeric film former for tailoring glass fiber sizings from tensile strength measurements[J].Journal of Materials Science,2001,36(21):5245-5252.
[18] Wu Y,Ying Y,Liu Y,et al.Preparation of chitosan/poly vinyl alcohol films and their inhibition of biofilm formation against Pseudomonas aeruginosa PAO1[J].International Journal of Biological Macromolecules,2018,118:2131-2137.
[19] Koutchma T.Advances in ultraviolet light technology for non-thermal processing of liquid foods[J].Food and Bioprocess Technology,2009,2(2):138-155.
[20] Decol M,Pachekoski W M,Becker D.Compatibilization and ultraviolet blocking of PLA/PCL blends via interfacial localization of titanium dioxide nanoparticles[J].Journal of Applied Polymer Science,2018,135(6):44849.
[21] De Silva R T,Mantilaka M M M G P G,Ratnayake S P,et al.Nano-MgO reinforced chitosan nanocomposites for high performance packaging applications with improved mechanical,thermal and barrier properties[J].Carbohydrate Polymers,2017,157:739-747.

基金资助

江苏省高校丝绸工程重点实验室(KJS2058);山西省“1331工程”(晋政发〔2021〕3号)

AI Summary AI Mindmap
PDF

461

访问

0

被引

导航
相关文章

AI思维导图

/