工业固废基地质聚合物是一种以工业固体废弃物为原料制备而成的新型绿色凝胶材料,具有原料来源广泛,成本低廉,绿色环保等特点,是工业固废资源化利用的重要途径之一,在环境保护领域具有十分广阔的应用前景。重点概述了不同工业固废制备地质聚合物的研究现状,并介绍了其在碳捕集、废水治理、固化重金属以及其他环境治理领域的应用研究进展,以期推动固废基地质聚合物的研究和促进工业固废的资源化利用。
Industrial solid waste-based geopolymer is a new type of green gel material with the advantages of wide source of raw materials,low cost and environmental protection.It is one of the important ways for the resource utilization of industrial solid waste,holding broad application prospects in the field of environmental protection.This paper mainly summarized the research status of geopolymers prepared from different solid wastes,and introduced their research progress of applications in CO2 capture,wastewater treatment,solidification of heavy metals and other environmental treatment field in order to promote the research of solid waste-based geopolymer and facilitate the resource utilization of industrial solid waste.
[1] 李洪兵,张吉军.中国能源消费结构及天然气需求预测[J].生态经济,2021,37(8):71-78.
[2] 再协.2020年全国大、中城市固体废物污染环境防治年报[J].中国资源综合利用,2021,39(1):4.
[3] 余春松,张玲玲,郑大伟,等.固废基地质聚合物的研究及其应用进展[J].中国科学:技术科学,2022,52(4):529-546.
[4] 孙道胜,王爱国,胡普华.地质聚合物的研究与应用发展前景[J].材料导报,2009,23(4):61-65.
[5] 马鸿文,杨静,任玉峰,等.矿物聚合材料:研究现状与发展前景[J].地学前沿,2002,9(4):398-407.
[6] Breck D W.Zeolite molecular sieves:structure,chemistry and use[M].New York:John Wiley & Sons,1974.
[7] Habert G,De Lacaillerie J B D E,Roussel N.An environmental evaluation of geopolymer based concrete production:reviewing current research trends[J].Journal of Cleaner Production,2011,19(11):1229-1238.
[8] McLellan B C,Williams R P,Lay J,et al.Costs and carbon emissions for geopolymer pastes in comparison to ordinary portland cement[J].Journal of Cleaner Production,2011,19(9-10):1080-1090.
[9] 吴小缓,张杨,袁鹏,等.地质聚合物的研究进展与应用[J].硅酸盐通报,2016,35(12):4032-4037.
[10] 朱国振.粉煤灰/偏高岭土地质聚合物材料的制备及其性能研究[D].景德镇:景德镇陶瓷学院,2014.
[11] Temuujin J,van Riessen A,MacKenzie K J D.Preparation and characterisation of fly ash based geopolymer mortars[J].Construction and Building Materials,2010,24(10):1906-1910.
[12] 贾屹海.Na-粉煤灰地质聚合物制备与性能研究[D].北京:中国矿业大学,2009.
[13] 王菲,刘泽,韩乐,等.活化煤矸石地质聚合物的制备与性能研究[J].硅酸盐通报,2021,40(3):914-920.
[14] 王建新,李晶,赵仕宝,等.中国粉煤灰的资源化利用研究进展与前景[J].硅酸盐通报,2018,37(12):3833-3841.
[15] 曲阳威,韩凤兰,邢质冰,等.粉煤灰地质聚合物多孔材料的制备及其性能研究[J].新型建筑材料,2020,47(11):144-147.
[16] 孟宪娴,韩敏芳,贾屹海,等.粉煤灰基地质聚合物材料性能研究[J].新型建筑材料,2011,38(12):67-70.
[17] Ahdaya M,Imqam A.Fly ash class C based geopolymer for oil well cementing[J].Journal of Petroleum Science and Engineering,2019,179:750-757.
[18] 王骏.碱激发矿渣地质聚合物的性能调控研究[D].西安:西安建筑科技大学,2017:2.
[19] 罗新春,汪长安.矿渣基地质聚合物多孔材料的制备与性能[J].硅酸盐学报,2016,44(3):450-456.
[20] 刘泽,周瑜,孔凡龙,等.碱激发矿渣基地质聚合物微观结构与性能研究[J].硅酸盐通报,2017,36(6):1830-1834.
[21] Wan H Y,He Y,Su Q Q,et al.Slag-based geopolymer microspheres as a support for CO2 methanation[J].Fuel,2022,319:123627.
[22] Davidovits J.Geopolymer chemistry and applications,5th Ed[M].Saint-Quentin:Institut Geopolymere,2020,1-22.
[23] 张卫清,柴军,冯秀娟,等.煤矸石基地质聚合物的制备及微观结构[J].中国矿业大学学报,2021,50(3):539-547.
[24] 周梅,徐秒,任光宇,等.自燃煤矸石-矿渣-粉煤灰地质聚合材料的制备及基本性能研究[J].硅酸盐通报,2013,32(9):1826-1831.
[25] 徐子芳,杨政,邹小童,等.煤系废物地聚合物稳定/固化重金属离子效果研究[J].环境科学学报,2015,35(3):812-818.
[26] 王超,宋卫锋,杨佐毅,等.工业固废基地聚合物的制备及其吸附Pb(Ⅱ)的性能[J].环境科学学报,2021,41(7):2700-2711.
[27] 王晨希,吴文瞳,郑蕾,等.地质聚合物应用于环境治理领域的研究进展[J].现代化工,2021,41(3):63-67.
[28] Freire A L,Moura-Nickel C D,Scaratti G,et al.Geopolymers produced with fly ash and rice husk ash applied to CO2 capture[J].Journal of Cleaner Production,2020,273:122917.
[29] Chen H,Zhang Y J,He P Y,et al.Novel activated carbon route to low-cost geopolymer based porous composite with high mechanical resistance and enhanced CO2 capacity[J].Microporous and Mesoporous Materials,2020,305:110282.
[30] Minelli M,Medri V,Papa E,et al.Geopolymers as solid adsorbent for CO2 capture[J].Chemical Engineering Science,2016,148:267-274.
[31] 孟范平,易怀昌.各种吸附材料在印染废水处理中的应用[J].材料导报,2009,23(13):69-73.
[32] Li L,Wang S B,Zhu Z H.Geopolymeric adsorbents from fly ash for dye removal from aqueous solution[J].Journal of Colloid and Interface Science,2006,300(1):52-59.
[33] Li C J,Zhang Y J,Chen H,et al.Development of porous and reusable geopolymer adsorbents for dye wastewater treatment[J].Journal of Cleaner Production,2022,348:131278.
[34] Siyal A A,Shamsuddin M R,Rabat N E,et al.Fly ash based geopolymer for the adsorption of anionic surfactant from aqueous solution[J].Journal of Cleaner Production,2019,229:232-243.
[35] 邹照华,何素芳,韩彩芸,等.吸附法处理重金属废水研究进展[J].环境保护科学,2010,36(3):22-24.
[36] Maleki A,Hajizadeh Z,Sharifi V,et al.A green,porous and eco-friendly magnetic geopolymer adsorbent for heavy metals removal from aqueous solutions[J].Journal of Cleaner Production,2019,215:1233-1245.
[37] Liu Y,Yan C J,Zhang Z Z,et al.A comparative study on fly ash,geopolymer and faujasite block for Pb removal from aqueous solution[J].Fuel,2016,185:181-189.
[38] Al-Harahsheh M S,Al Zboon K,Al-Makhadmeh L,et al.Fly ash based geopolymer for heavy metal removal:a case study on copper removal[J].Journal of Environmental Chemical Engineering,2015,3(3):1669-1677.
[39] Luukkonen T,Runtti H,Niskanen M,et al.Simultaneous removal of Ni(Ⅲ),As(Ⅲ),and Sb(Ⅲ) from spiked mine effluent with metakaolin and blast-furnace-slag geopolymers[J].Journal of Environmental Management,2016,166:579-588.
[40] Huang J G,Wen Y,Ding N,et al.Effect of sulfate on anaerobic reduction of nitrobenzene with acetate or propionate as an electron donor[J].Water Research,2012,46(14):4361-4370.
[41] Runtti H,Luukkonen T,Niskanen M,et al.Sulphate removal over barium-modified blast-furnace-slag geopolymer[J].Journal of Hazardous Materials,2016,317:373-384.
[42] Sanguanpak S,Wannagon A,Saengam C,et al.Porous metakaolin-based geopolymer granules for removal of ammonium in aqueous solution and anaerobically pretreated piggery wastewater[J].Journal of Cleaner Production,2021,297:126643.
[43] Hashemi S S G,Mahmud H B,Ghuan T C,et al.Safe disposal of coal bottom ash by solidification and stabilization techniques[J].Construction and Building Materials,2019,197:705-715.
[44] Xia M,Muhammad F,Zeng L H,et al.Solidification/stabilization of lead-zinc smelting slag in composite based geopolymer[J].Journal of Cleaner Production,2019,209:1206-1215.
[45] 蔡卓雨,刘清,毕嘉琪,等.高炉矿渣-粉煤灰基地质聚合物固化铅离子及防辐射性能研究[J].无机盐工业,2022,54(8):125-131.
[46] Guo X L,Shi H S,Xu M F.Static and dynamic leaching experiments of heavy metals from fly ash-based geopolymers[J].Journal of Wuhan University of Technology-Materials Science,2013,28(5):938-943.
[47] Leiva C,Luna-Galiano Y,Arenas C,et al.A porous geopolymer based on aluminum-waste with acoustic properties[J].Waste Management,2019,95:504-512.
[48] Arenas C,Luna-Galiano Y,Leiva C,et al.Development of a fly ash-based geopolymeric concrete with construction and demolition wastes as aggregates in acoustic barriers[J].Construction and Building Materials,2017,134:433-442.
[49] Luna-Galiano Y,Leiva C,Arenas C,et al.Fly ash based geopolymeric foams using silica fume as pore generation agent.Physical,mechanical and acoustic properties[J].Journal of Non-crystalline Solids,2018,500:196-204.
基金资助
陕西省重点研发计划项目资助(2022SF-216)