近年来,由于锂资源的短缺和快速消耗,锂离子电池的成本急剧增加,因此寻找新型储能系统显得日益重要。钠离子电池具有和锂离子电池相似的工作原理,可以作为锂离子电池的一种经济高效的替代品。锰基普鲁士蓝材料因其原材料分布广泛、成本低、结构稳定、环境友好且制备工艺简单等优点,是一种极具潜力的钠离子电池正极材料。综述了有关锰基普鲁士蓝材料的储钠机理、合成方法、修饰路线及材料应用的最新进展,从迁移离子、过渡金属、结合水与空位分析了普鲁士蓝材料对钠离子电池电化学性能的影响,并对可能的发展方向进行了展望。
In recent years,due to the shortage and rapid consumption of lithium resources,the cost of lithium-ion batteries has increased sharply,making it increasingly important to find new energy storage systems.Sodium-ion batteries have similar working principle to lithium-ion batteries and can be used as a cost-effective alternative to lithium-ion batteries.Manganese-based Prussian blue material is a potential cathode material for sodium-ion batteries due to its advantages of wide distribution of raw materials,low cost,stable structure,environmental friendliness and simple preparation process.In this paper,the latest progress in sodium storage mechanism,synthesis methods,modification routes and material applications of manganese-based Prussian blue materials was reviewed.The effects of Prussian blue materials on the electrochemical performance of sodium-ion batteries were analyzed in terms of migration ions,transition metals,bonded water and vacancies,and the possible development directions were discussed.
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基金资助
河南省重点研发专项(221111240600);河南省重点研发与推广专项(科技攻关)(222102240030);河南省自然科学基金项目(222300420581)
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