化工新型材料

化工新型材料 ›› 2024, Vol. 52 ›› Issue (2) : 277-281. DOI: 10.19817/j.cnki.issn1006-3536.2024.02.024

开发与应用

金属有机框架材料用于光催化CO₂还原的研究进展

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Research progress of metal-organic frame materials for photocatalytic CO₂ reduction

Wang Zhengmin¹, Zhao Shengbin², Qian Qingyi³, Zhao Qiuping¹

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文章历史 +

Received		Published
2022-11-02		2024-02-20
Issue Date	Revised Date
2024-02-28	2022-11-02

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摘要

CO₂光催化还原转化为有价值的碳氢燃料和化工原料是达成“碳中和”目标的重要途径。金属有机框架材料(MOFs)是一种由有机配位体和金属离子或团簇通过配位键形成的有机-无机杂化材料,具有超高的比表面积、可调的孔结构,并易于功能化修饰,在CO₂光催化还原反应中展现出良好的应用前景。总结了基于MOFs的新型功能材料绿色光催化CO₂还原的最新研究进展,探讨了改性及功能化MOFs材料及MOFs衍生物的光催化CO₂还原反应机理,并从理化特性上分析了材料性能优势的成因。总结了提高光催化还原CO₂反应的活性和选择性的策略。在此基础上,对这类新型催化剂面临的主要问题和未来发展进行了总结与展望。

Abstract

Photocatalytic reduction of CO₂ into valuable hydrocarbon fuels and chemical raw materials is an important way to achieve the goal of “carbon neutrality”.Metal-organic framework (MOFs) is an organic-inorganic hybrid material formed by organic ligands and metal ions or clusters through coordination bonds.They have exceptionally high specific surface area,adjustable pore structure,and ease of functionalization,showing a good application prospect in CO₂ photocatalytic reduction reactions.This paper reviewed the latest research progress of green photocatalytic CO₂ reduction by novel MOFs-based functional materials,explored the mechanisms of photocatalytic CO₂ reductions involving modified and functionalized MOFs materials and MOFs derivatives,and analyzed the causes of material performance advantages from the perspective of physicochemical properties.The strategies to improve the activity and selectivity of photocatalytic reduction of CO₂ were summarized.The main problems and future development directions of these novel catalysts were discussed.

关键词

CO₂还原 / 金属有机框架材料 / 光催化

Key words

CO₂ reduction / metal-organic frame materials (MOFs) / photocatalytic

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金属有机框架材料用于光催化CO₂还原的研究进展[J]. 化工新型材料, 2024, 52(2): 277-281 DOI:10.19817/j.cnki.issn1006-3536.2024.02.024

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