共价有机框架材料(COFs)是一类新型的结晶多孔聚合物,具有孔隙高、活性位点丰富、框架结构可调等特点,广泛应用于催化、储能、气体吸附及光电子等领域。其中卟啉基COFs因具有独特的共轭π电子结构,可促进激发态电子的传输,因此在电催化领域有重要的应用。主要介绍了卟啉基COFs的合成策略及其在析氢反应(HER)、析氧反应(OER)、氧还原反应(ORR)和超级电容器的应用,并结合目前研究中存在的问题,提出了卟啉基COFs今后在电催化及储能领域的挑战和发展方向。
Covalent organic frameworks materials (COFs) are a class of emerging crystalline porous polymers with high porosity,rich active sites and adjustable structure,and have been widely used in catalysis,energy storage,gas adsorption and optoelectronics.Among them,porphyrin-based COFs possess unique conjugate π-electronic structure,which can promote the transmission of excited state electrons,thus making them have important applications in the field of electrocatalysis.This paper mainly introduced the synthesis strategies of porphyrin-based COFs and their applications in hydrogen evolution reaction (HER),oxygen evolution reaction (OER),oxygen reduction reaction (ORR) and supercapacitors.Combined with the problems existing in the current research,it proposed the challenges and future development directions of porphyrin-based COFs in the field of electrocatalysis.
[1] Liu H,Zhao D,Liu Y,et al.NiMoCo layered double hydroxides for electrocatalyst and supercapacitor electrode[J].Science China Materials,2021,64(3):581-591.
[2] Tang W,Li B,Teng K,et al.Advanced noble-metal-free bifunctional electrocatalysts for metal-air batteries[J].Journal of Materiomics,2021,8:454-474.
[3] Cote A P,Benin A I,Ockwig N W,et al.Porous,crystalline,covalent organic frameworks[J].Science,2005,310(5751):1166-1170.
[4] Rodríguez-San-Miguel D,Montoro C,Zamora F.Covalent organic framework nanosheets:preparation,properties and applications[J].Chemical Society Reviews,2020,49(8):2291-2302.
[5] Yang H,Zhang S,Han L,et al.High conductive two-dimensional covalent organic framework for lithium storage with large capacity[J].ACS Applied Materials & Interfaces,2016,8(8):5366-5375.
[6] Kong X,Zhou S,Strømme M,et al.Redox active covalent organic framework-based conductive nanofibers for flexible energy storage device[J].Carbon,2021,171:248-256.
[7] Yao M Y,Guo C F,Geng Q H,et al.Construction of anthraquinone-containing covalent organic frameworks/graphene hybrid films for a flexible high-performance microsupercapacitor[J].Industrial & Engineering Chemistry Research,2022,61:7480-7488.
[8] 邹文午,蒋国星,杜丽.共价有机框架材料(COFs)在氧电极电催化中的研究进展[J].储能科学与技术,2021,10(6):1891.
[9] Ren L,Zhou J,Xiong S,et al.N-doping carbon-nanotube membrane electrodes derived from covalent organic frameworks for efficient capacitive deionization[J].Langmuir,2020,36(40):12030-12037.
[10] Chen M,Li H,Liu C,et al.Porphyrin-and porphyrinoid-based covalent organic frameworks (COFs):from design,synthesis to applications[J].Coordination Chemistry Reviews,2021,435:213778.
[11] Liang Z,Wang H Y,Zheng H,et al.Porphyrin-based frameworks for oxygen electrocatalysis and catalytic reduction of carbon dioxide[J].Chemical Society Reviews,2021,50(4):2540-2581.
[12] Yusran Y,Fang Q,Valtchev V.Electroactive covalent organic frameworks:design,synthesis,and applications[J].Advanced Materials,2020,32(44):2002038.
[13] Liu Q Y,Li J F,Wang J W.Research of covalent organic frame materials based on porphyrin units[J].Journal of Inclusion Phenomena and Macrocyclic Chemistry,2019,95(1):1-15.
[14] Wan S,Gándara F,Asano A,et al.Covalent organic frameworks with high charge carrier mobility[J].Chemistry of Materials,2011,23(18):4094-4097.
[15] Shinde D B,Kandambeth S,Pachfule P,et al.Bifunctional covalent organic frameworks with two dimensional organocatalytic micropores[J].Chemical Communications,2015,51(2):310-313.
[16] Feng X,Chen L,Dong Y,et al.Porphyrin-based two-dimensional covalent organic frameworks:synchronized synthetic control of macroscopic structures and pore parameters[J].Chemical Communications,2011,47(7):1979-1981.
[17] Yi J D,Xu R,Chai G L,et al.Cobalt single-atoms anchored on porphyrinic triazine-based frameworks as bifunctional electrocatalysts for oxygen reduction and hydrogen evolution reactions[J].Journal of Materials Chemistry A,2019,7(3):1252-1259.
[18] 陈梦回.三嗪环基卟啉共价有机骨架的构建及性质研究[D].北京:北京交通大学,2021.
[19] Wu Y,Veleta J M,Tang D,et al.Efficient electrocatalytic hydrogen gas evolution by a cobalt-porphyrin-based crystalline polymer[J].Dalton Transactions,2018,47(26):8801-8806.
[20] Patra B C,Khilari S,Manna R N,et al.A metal-free covalent organic polymer for electrocatalytic hydrogen evolution[J].ACS Catalysis,2017,7(9):6120-6127.
[21] Bhunia S,Das S K,Jana R,et al.Electrochemical stimuli-driven facile metal-free hydrogen evolution from pyrene-porphyrin-based crystalline covalent organic framework[J].ACS Applied Materials & Interfaces,2017,9(28):23843-23851.
[22] Wang A,Cheng L,Zhao W,et al.Electrochemical hydrogen and oxygen evolution reactions from a cobalt-porphyrin-based covalent organic polymer[J].Journal of Colloid and Interface Science,2020,579:598-606.
[23] Park E,Jack J,Hu Y,et al.Covalent organic framework-supported platinum nanoparticles as efficient electrocatalysts for water reduction[J].Nanoscale,2020,12(4):2596-2602.
[24] Bhunia S,Bhunia K,Patra B C,et al.Efficacious electrochemical oxygen evolution from a novel Co(Ⅱ) porphyrin/pyrene-based conjugated microporous polymer[J].ACS Applied Materials & Interfaces,2018,11(1):1520-1528.
[25] Huang H,Li F,Zhang Y,et al.Two-dimensional graphdiyne analogue Co-coordinated porphyrin covalent organic framework nanosheets as a stable electrocatalyst for the oxygen evolution reaction[J].Journal of Materials Chemistry A,2019,7(10):5575-5582.
[26] Jia H,Sun Z,Jiang D,et al.Covalent cobalt porphyrin framework on multiwalled carbon nanotubes for efficient water oxidation at low overpotential[J].Chemistry of Materials,2015,27(13):4586-4593.
[27] Gan Z,Lu S,Qiu L,et al.Fine tuning of supported covalent organic framework with molecular active sites loaded as efficient electrocatalyst for water oxidation[J].Chemical Engineering Journal,2021,415:127850.
[28] Zhao X,Pachfule P,Li S,et al.Macro/microporous covalent organic frameworks for efficient electrocatalysis[J].Journal of the American Chemical Society,2019,141(16):6623-6630.
[29] Ma W,Yu P,Ohsaka T,et al.An efficient electrocatalyst for oxygen reduction reaction derived from a Co-porphyrin-based covalent organic framework[J].Electrochemistry Communications,2015,52:53-57.
[30] Zuo Q,Cheng G,Luo W.A reduced graphene oxide/covalent cobalt porphyrin framework for efficient oxygen reduction reaction[J].Dalton Transactions,2017,46(29):9344-9348.
[31] Guo J,Lin C Y,Xia Z,et al.A pyrolysis-free covalent organic polymer for oxygen reduction[J].Angewandte Chemie International Edition,2018,57(38):12567-12572.
[32] Lei H,Zhang Q,Wang Y,et al.Significantly boosted oxygen electrocatalysis with cooperation between cobalt and iron porphyrins[J].Dalton Transactions,2021,50(15):5120-5123.
[33] Li B Q,Zhang S Y,Chen X,et al.One-pot synthesis of framework porphyrin materials and their applications in bifunctional oxygen electrocatalysis[J].Advanced Functional Materials,2019,29(29):1901301.
[34] Li B Q,Zhang S Y,Wang B,et al.A porphyrin covalent organic framework cathode for flexible Zn-air batteries[J].Energy & Environmental Science,2018,11(7):1723-1729.
[35] Zhang B,Wang W,Liang L,et al.Prevailing conjugated porous polymers for electrochemical energy storage and conversion:lithium-ion batteries,supercapacitors and water-splitting[J].Coordination Chemistry Reviews,2021,436:213782.
[36] Zhao-Karger Z,Gao P,Ebert T,et al.New organic electrode materials for ultrafast electrochemical energy storage[J].Advanced Materials,2019,31(26):1806599.
[37] Yusran.用于高性能催化剂和电化学储能的结晶多孔聚合物[D].吉林:吉林大学,2020.
[38] Li R,Xing L,Chen A,et al.Covalent organic polymer-derived carbon nanotube-twined carbon nanospheres for efficient oxygen electroreduction and capacitance storage[J].Ionics,2020,26(2):927-937.
[39] Patra B C,Bhattacharya S.New covalent organic square lattice based on porphyrin and tetraphenyl ethylene building blocks toward high-performance supercapacitive energy storage[J].Chemistry of Materials,2021,33(21):8512-8523.
基金资助
山东省重点研发计划(公益类专项)项目(2019GGX103017)
PDF
