化工新型材料

化工新型材料 ›› 2023, Vol. 51 ›› Issue (12) : 60-66. DOI: 10.19817/j.cnki.issn1006-3536.2023.12.048

综述与专论

四氧化三钴及掺杂材料电催化性能的研究进展

作者信息 +

Research progress in the electrocatalytic performance of cobalt tetroxide and doped materials

Zhang Man¹, Fan Min²

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文章历史 +

Received		Published
2022-07-21		2023-12-20
Issue Date	Revised Date
2023-12-27	2022-07-21

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摘要

综述了Co₃O₄及掺杂材料的性质、结构和电催化性能。Co₃O₄中的钴离子是Co²⁺和Co³⁺的混合价。由于Co₃O₄具有独特的尖晶石晶体结构,有利于Co²⁺和Co³⁺离子之间的电子传导,具有空电子轨道且易实现晶格氧化可作为氧还原反应(ORR)催化剂。综述了Co₃O₄的电催化性能的影响因素主要由其表面积和电子态决定,表面积通过调整纳米结构的大小和形貌来调节,电子态可以通过掺入第三种元素或氧空位来调控。综述了Co₃O₄掺杂不同材料后均表现出优异的催化性能与良好甲醇耐受性。Co₃O₄与Pd掺杂可以提高金属Pd在载体表面的分散性,降低金属颗粒团聚;Co₃O₄与P的组合使催化剂的内在活性增强;Co₃O₄与Ni掺杂,在ORR方面表现比Pt/C更好的稳定性和甲醇耐受性;Co₃O₄掺杂氮原子,这种复合催化剂表现出良好的抗甲醇中毒能力与稳定性。

Abstract

The properties,structure and electrocatalytic performance of Co₃O₄ and doped materials were summarized.The cobalt ions in Co₃O₄ were the mixed valence of Co²⁺ and Co³⁺.Co₃O₄ had a unique spinel crystal structure,which was conducive to the electron conduction between Co²⁺ and Co³⁺ ions.Co₃O₄ had empty electron orbits and was easy to realize lattice oxidation,which could be used as ORR catalyst.The influencing factors of the electrocatalytic performance of Co₃O₄ were mainly determined by its surface area and electronic states.The surface area was adjusted by adjusting the size and morphology of the nanostructure.Electronic states could be regulated by the incorporation of a third element or oxygen vacancy.The excellent catalytic performance and methanol tolerance of Co₃O₄ doped with different materials were reviewed.Co₃O₄ doping with Pd could improve the dispersion of metal Pd on the surface of the carrier and reduce the agglomeration of metal particles.The combination of Co₃O₄ and P enhanced the intrinsic activity of the catalyst.Co₃O₄ doped with Ni exhibited better ORR stability and methanol tolerance than Pt/C.Co₃O₄ doped with nitrogen atom demonstrated good stability and resistance to methanol poisoning.

关键词

四氧化三钴 / 电催化性能 / 氧还原反应 / 燃料电池 / 掺杂材料

Key words

cobalt tetroxide / electrocatalytic performance / oxygen reduction reaction / fuel cell / doped material

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四氧化三钴及掺杂材料电催化性能的研究进展[J]. 化工新型材料, 2023, 51(12): 60-66 DOI:10.19817/j.cnki.issn1006-3536.2023.12.048

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