随着人们对三维材料的不断深入研究,三维孔洞材料的优势逐渐凸显,已经成为材料结构的研究热点。并且随着显微设备的不断发展,人们对三维孔洞结构的种类和特点认识逐渐全面。其中包含的反蛋白石结构由于比表面积高、独特的孔洞结构和光子间隙,更是引起了人们的广泛关注。人们开始将其应用于材料的改性和各类科学研究,尤其是在光催化和太阳能电池研究方面。综述了以反蛋白石结构为主的三维孔洞材料,在光催化降解污染和催化产氢、太阳能电池、传感器件、生物器件等方面的主要应用和研究现状,分析了现研究中存在的主要问题,并对未来的研究和应用进行了展望。
With the continuous deepening of the research on three-dimensional materials,the advantages of three-dimensional porous materials are gradually highlighted,and they have become a hot topic in material structure research.Furthermore,with the development of microscopic equipment,people have a more comprehensive understanding of the types and characteristics of three-dimensional porous structures.Among them,the inverse opal has attracted much attention due to its high specific surface area,unique porous structure and photon gap.It has been widely used in the modification of materials and various scientific research,especially in photocatalysis and solar cell research.This paper reviewed the main application and research status of three-dimensional porous materials,with emphasis on inverse opal structure,in photocatalytic degradation of pollution and catalytic hydrogen production,solar cells,sensor devices,and biological devices.Finally,it analyzed the main problems in current research and provided prospects for future research and applications.
[1] Aprile C,Corma A,Garcia H.Enhancement of the photocatalytic activity of TiO2 through spatial structuring and particle size control:from subnanometric to submillimetric length scale[J].Physical Chemistry Chemical Physics,2008,10(6):769-783.
[2] Liu X M,Zhong W L,Huang Y C,et al.Facile preparation of spherical TiO2 inverse opals with enhanced visible-light photodegradation of methylene blue[J].Journal of Materials Science:Materials in Electronics,2021,32(16):21742-21755.
[3] Li X F,Chen Z S,Quan H H,et al.Constructing photocatalyst from β-Bi2O3 photonic crystals for enhanced photocatalytic performance[J].Journal of Porous Materials,2018,25(3):677-685.
[4] Xie J,Lei K,Wang H,et al.Strontium titanate with inverse opal structure as the photocatalysts[J].Journal of Materials Science:Materials in Electronics,2020,31(3):2691-2698.
[5] Wu M,Liu J,Jin J,et al.Probing significant light absorption enhancement of titania inverse opal films for highly exalted photocatalytic degradation of dye pollutants[J].Applied Catalysis B:Environmental,2014,150:411-420.
[6] Le T H T,Bui T T,Bui H V,et al.TiO2 inverse opals modified by Ag nanoparticles:a synergic effect of enhanced visible-light absorption and efficient charge separation for visible-light photocatalysis[J].Catalysts,2021,11(7):761.
[7] Wu Y T,Li X,Liu C Q,et al.Studies on the active radicals in synthesized inverse opal photonic crystal and its effect on photocatalytic removal of organic pollutants[J].Journal of Molecular Liquids,2020,320(15):114414.
[8] Zheng X Z,Zhang Z,Meng S G,et al.Regulating charge transfer over 3D Au/ZnO hybrid inverse opal toward efficiently photocatalytic degradation of bisphenol A and photoelectrochemical water splitting[J].Chemical Engineering Journal,2020,393:124676.
[9] Yang Y,Jin Q,Mao D,et al.Dually ordered porous TiO2-rGO composites with controllable light absorption properties for efficient solar energy conversion[J].Advanced Materials,2017,29(4):1604795.
[10] Huo J W,Yuan C,Wang Y.Nanocomposites of three-dimensionally ordered porous TiO2 decorated with Pt and reduced graphene oxide for the visible-light photocatalytic degradation of waterborne pollutants[J].ACS Applied Nano Materials,2019,2(5):2713-2724.
[11] Ouyang K,Xie S,Wang P,et al.A novel visible-light responsive photocatalytic fuel cell with a highly efficient BiVO4/WO3 inverse opal photoanode and a MnO2/graphene oxide nanocomposite modified cathode[J].International Journal of Hydrogen Energy,2019,44(14):7288-7299.
[12] Apostolaki M A,Toumazatou A,Antoniadou M,et al.Graphene quantum dot-TiO2 photonic crystal films for photocatalytic applications[J].Nanomaterials,2020,10(2):2556.
[13] 孙翠锋.TiO2反蛋白石及其修饰结构的光催化CO2还原研究[D].北京:北京交通大学,2017.
[14] Tian Y H,Zhou L,Zhu Q H,et al.Hierarchical macro-mesoporous g-C3N4 with an inverse opal structure and vacancies for high-efficiency solar energy conversion and environmental remediation[J].Nanoscale,2019,11(43):20638-20647.
[15] Han G W,Xu F Y,Cheng B,et al.Enhanced photocatalytic H2O2 production over inverse opal ZnO@polydopamine S-scheme heterojunctions[J].Acta Physico-Chimica Sinica,2022,38(7):2112037.
[16] Wei Z S,Mogan T R,Wang K L,et al.Morphology-governed performance of Multi-Dimensional Photocatalysts for Hydrogen Generation[J].Energies,2021,14(21):7223.
[17] 刘雁军.ZnO复合微球的可控制备及光电性能与生物传感[D].南京:东南大学,2019.
[18] Oh Y J,Yang W,Tan J,et al.Photocathodes:boosting visible light harvesting in p-type ternary oxides for solar-to-hydrogen conversion using inverse opal structure[J].Advanced Functional Materials,2019,29(17):1970114.
[19] Liu Z C,Yuan X H,Zhang S S,et al.Three-dimensional ordered porous electrode materials for electrochemical energy storage[J].NPG Asia Materials,2019,11(1):1-21.
[20] Zhu H L,Zhang Y J,Zhu J Q,et al.Crack-free hematite inverse opal photo-anodes for enhancing photo-electrochemical water splitting[J].Journal of Materials Chemistry A,2020,8(43):22929-22937.
[21] Zhang S,Dong G Y,Lin B C,et al.Studies on fabrication of quasi-solid-state electrolytes with an inverse opal structure and their photoelectric properties[J].Journal of Jiangsu Polytechnic University,2015,27(3):24-28.
[22] Phillips K R,Shirman T,Aizenberg M,et al.Silica-titania hybrids for structurally robust inverse opals with controllable refractive index[J].Journal of Materials Chemistry C,2020,8(1):109-116.
[23] Hou P Q,Qu Y D,Li P W,et al.Controllable synthesis of polystyrene microspheres used as template and in-situ carbon source for Li2MnSiO4 cathode material to boost lithium-ion batteries performance[J].International Journal of Energy Research,2022,46(2):1711-1721.
[24] Ha S J,Heo J H,Im S.H,et al.Mesoscopic CH3NH3PbI3 perovskite solar cells using TiO2 inverse opal electron-conducting scaffolds[J].Journal of Materials Chemistry A,2017,5(5):1972-1977.
[25] Golabi P,Keshavarzi R,Mirkhani V,et al.Efficient colorful perovskite solar cells designed by 2D and 3D ordered titania inverse opals[J].Journal of Power Sources,2021,512,230488.
[26] 孙奇.具有周期性结构的孔洞电极的研究及其在钙钛矿太阳能电池中的应用[D].苏州:苏州大学.
[27] Dang X M,Jiang X,Zhang T T,et al.WO3 inversce opal photonic crystals:unique property,synthetic methods and extensive application[J].Chinese Journal of Chemistry,2021,39(6):1706-1715.
[28] 陈爱莲,钱程,李志娜.反蛋白石结构大孔碳材料的制备及其在染料敏化太阳能电池对电极中的应用[J].中国有色金属学报,2014,24(4):981-986.
[29] Qi K Z,Lv W X,Khan I,et al.Photocatalytic H2 generation via CoP quantum-dot-modified g-C3N4 synthesized by electroless plating[J].Chinese Journal of Catalysis,2020,41(1):114-121.
[30] Xu J,Huang J,Wang Z P,et al.Enhanced visible-light photocatalytic degradation and disinfection performance of oxidized nanoporous g-C3N4 via decoration with graphene oxide quantum dots[J].Chinese Journal of Catalysis,2020,41(3):474-484.
[31] 肖俊彦,罗艳红,李冬梅,等.基于反蛋白石结构SnO2的量子点敏化太阳电池[C].北京:第一届新型太阳能电池暨钙钛矿太阳能电池学术研讨会,2014.
[32] Liu Y Y,Wang Z,Li L J,et al.Highly efficient quantum-dot-sensitized solar cells with composite semiconductor of ZnO nanorod and oxide inverse opal in photoanode[J].Electrochimica Acta,2022,412:140145.
[33] Zhong Q F,Xu H,Ding H B,et al.Preparation of conducting polymer inverse opals and its application as ammonia sensor[J].Colloids and Surfaces A:Physicochemical and Engineering Aspects,2013,433(35):59-63.
[34] Sobhanimatin M B,Pourmahdian S,Tehranchi M M.Colorimetric monitoring of humidity by opal photonic hydrogel[J].Polymer Testing,2021,98:106999.
[35] Li G J,Cheng Z X,Xiang Q,et al.Bimetal PdAu decorated SnO2 nanosheets based gas sensor with temperature-dependent dual selectivity for detecting formaldehyde and acetone[J].Sensors & Actuators:B.Chemical,2019,283:590-601.
[36] Guo M,Yu X Q,Zhao J,et al.Versatile titanium dioxide inverse opal composite photonic hydrogel films towards multi-solvents chip sensors[J].Sensors and Actuators:B.Chemical,2021,347:130639.
[37] Xia L,Shang Y X,Chen X B,et al.Oriented neural spheroid formation and differentiation of neural stem cells guided by anisotropic inverse opals[J].Frontiers in Bioengineering and Biotechnology,2020,8:848.
[38] 许晓晨.反蛋白石微纳结构对神经干细胞自我更新及分化的调控[D].南京:东南大学,2018.
[39] 赵远锦,邵长敏,王月桐.一种分级结构反蛋白石多孔生物支架的制备方法:CN202010344111.X[P].2020-07-14.
[40] 张彬.反蛋白石结构水凝胶微载体的制备及其生物分析应用[D].南京:东南大学,2016.
[41] 李琳杰.复合结构色水凝胶制备及其细胞传感应用[D].南京:东南大学,2020.
[42] Weng W Q,Chi J J,Yu Y R,et al.Multifunctional composite inverse opal film with multiactives for wound healing[J].ACS Applied Materials & Interfaces,2021,13(3):4567-4573.
[43] Liu J H,Wang J X,Ikeda T,et al.Liquid-phase super photoactuator through the synergetic effects of a janus structure and solvent/thermal/photo responses[J].Advanced Functional Materials,2021,31(48):2105728.
[44] Wang Y P,Niu W B,Zhang S F,et al.Solvent responsive single-material inverse opal polymer actuator with structural color switching[J].Journal of Materials Science,2020,55(2):817-827.
[45] Shang L R,Zhang W X,Xu K,et al.Correction:bio-inspired intelligent structural color materials[J].Materials Horizons,2019,6(5):1080.
[46] Liu J C,Wang Y,Wang J X,et al.Inkless rewritable photonic crystals paper enabled by a light-driven azobenzene mesogen switch[J].ACS Applied Materials & Interfaces,2021,13(10):12383-12392.
[47] Huang F T,Weng Y H,Lin Y X,et al.Wetting-enhanced structural color for convenient and reversible encryption of optical information[J].ACS Applied Materials & Interfaces,2021,13(35):42276-42286.
[48] Yoo Y G,Lee S J,Ko M J,et al.Diphylleia grayi-inspired intelligent hydrochromic adhesive film[J].ACS Applied Materials & Interfaces,2020,12(44):49982-49991.
基金资助
湖北省高等学校优秀中青年科技创新团队计划项目(T2020008)
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