钛基锂电池负极材料具备安全性高、倍率性能好、寿命长以及循环稳定性优异等特点,是一类极具潜力的负极材料。综述了钛酸锂、钛铌氧化物、TiO2等钛基负极材料的结构、电化学特性、储锂机理以及常用改性方法,并对未来发展方向做出展望。
Titanium-based anode materials for lithium-ion batteries are a promising class of anode materials with high safety,good rate performance,long life and excellent cycling stability.This paper reviewed the structure,electrochemical properties,lithium storage mechanism,and common modification methods of titanium-based anode materials such as lithium titanate,titanium niobium oxide and TiO2.Additionally,the future developing direction was prospected.
[1] Aurbach D,Markovsky B,Weissman I,et al.On the correlation between surface chemistry and performance of graphite negative electrodes for Li ion batteries[J].Electrochimica Acta,1999,45(1-2):67-86.
[2] Yao X Y,Xie S,Chen C H,et al.Comparisons of graphite and spinel Li1.33Ti1.67O4 as anode materials for rechargeable lithium-ion batteries[J].Electrochimica Acta,2005,50(20):4076-4081.
[3] 路密,尹鸽平,史鹏飞.锂离子电池负极石墨材料的修饰与改性[J].电池,2001,31(4):195-197.
[4] Ferg E,Gummow R J,De Kock A,et al.Spinel anodes for lithium-ion batteries[J].Journal of the Electrochemical Society,1994,141(11):147-150.
[5] Cava R,Murphy D,Zahurak S,et al.The crystal structures of the lithium-inserted metal oxides Li0.5TiO2 anatase,LiTi2O4 spinel,and Li2Ti2O4[J].Journal of Solid State Chemistry,1984,53(1):64-75.
[6] Wilkening M,Amade R,Iwaniak W,et al.Ultraslow Li diffusion in spinel-type structured Li4Ti5O12—A comparison of results from solid state NMR and impedance spectroscopy[J].Physical Chemistry Chemical Physics,2007,9(10):1239-1246.
[7] Wagemaker M,Simon D R,Kelder E M,et al.A kinetic two-phase and equilibrium solid solution in spinel Li4+xTi5O12[J].Advanced Materials,2006,18(23):3169-3173.
[8] Colin J F,Godbole V,Novák P.In situ neutron diffraction study of Li insertion in Li4Ti5O12[J].Electrochemistry Communications,2010,12(6):804-807.
[9] Wang W,Jiang B,Xiong W,et al.A nanoparticle Mg-doped Li4Ti5O12 for high rate lithium-ion batteries[J].Electrochimica Acta,2013,114:198-204.
[10] Zhang Y X,Luo Y,Chen Y,et al.Enhanced rate capability and low-temperature performance of Li4Ti5O12 anode material by facile surface fluorination[J].ACS Applied Materials & Interfaces,2017,9(20):17145-17154.
[11] Jiang C,Ichihara M,Honma I,et al.Effect of particle dispersion on high rate performance of nano-sized Li4Ti5O12 anode[J].Electrochimica Acta,2007,52(23):6470-6475.
[12] Yuan T,Yu X,Cai R,et al.Synthesis of pristine and carbon-coated Li4Ti5O12 and their low-temperature electrochemical performance[J].Journal of Power Sources,2010,195(15):4997-5004.
[13] Huang C,Zhao S X,Peng H,et al.Hierarchical porous Li4Ti5O12-TiO2 composite anode materials with pseudocapacitive effect for high-rate and low-temperature applications[J].Journal of Materials Chemistry A,2018,6(29):14339-14351.
[14] Yuan T,Soule L K,Zhao B,et al.Recent advances in titanium niobium oxide anodes for high-power lithium-ion Batteries[J].Energy & Fuels,2020,34(11):13321-13334.
[15] Han J T,Goodenough J B.3-V full cell performance of anode framework TiNb2O7/spinel LiNi0.5Mn1.5O4[J].Chemistry of Materials,2011,23(15):3404-3407.
[16] Hu L,Luo L J,Tang L F,et al.Ti2Nb2xO4+5x anode materials for lithium-ion batteries:a comprehensive review[J].Journal of Materials Chemistry A,2018,6(21):9799-9815.
[17] Yang C,Yu S,Ma Y,et al.Cr3+ and Nb5+ co-doped Ti2Nb10O29 materials for high-performance lithium-ion storage[J].Journal of Power Sources,2017,360:470-479.
[18] Park H,Wu H B,Song T,et al.Porosity-controlled TiNb2O7 microspheres with partial nitridation as s practical negative electrode for high-power lithium-ion batteries[J].Advanced Energy Materials,2015,5(8):1401945.
[19] Guo B K,Yu X Q,Sun X G,et al.A long-life lithium-ion battery with a highly porous TiNb2O7 anode for large-scale electrical energy storage[J].Energy & Environmental Science,2014,7(7):2220-2226.
[20] Liu X D,Chen H,Liu R Y,et al.Ionic liquid-assisted synthesis of hierarchical Ti2Nb10O29 porous microspheres coated by ultrathin N-doped carbon layers for high-performance lithium-ion battery[J].Ceramics International,2021,47(12):17606-17614.
[21] Sudant G,Baudrin E,Larcher D,et al.Electrochemical lithium reactivity with nanotextured anatase-type TiO2[J].Journal of Materials Chemistry,2005,15(12):1263-1269.
[22] Koudriachova M V,Harrison N M,de Leeuw S W.Diffusion of Li-ions in rutile.An ab initio study[J].Solid State Ionics,2003,157(1-4):35-38.
[23] Borghols W J H,Wagemaker M,Lafont U,et al.Impact of nanosizing on lithiated rutile TiO2[J].Chemistry of Materials,2008,20(9):2949-2955.
[24] Zhang W F,Shen D L,Liu Z W,et al.Brookite TiO2 mesocrystals with enhanced lithium-ion intercalation properties[J].Chemical Communications,2018,54(81):11491-11494.
[25] Zukalová M,Kalbáč M,Kavan L,et al.Pseudocapacitive lithium storage in TiO2(B)[J].Chemistry of Materials,2005,17(5):1248-1255.
[26] Brohan L,Marchand R.Properties physiques des bronzes MxTiO2(B)[J].Solid State Ionics,1983,9-10:419-424.
[27] Opra D P,Gnedenkov S V,Sinebryukhov S L.Recent efforts in design of TiO2(B) anodes for high-rate lithium-ion batteries:a review[J].Journal of Power Sources,2019,442:227225.
[28] Ho C K,Li C Y V,Chan K Y,et al.Interfacing TiO2(B) nanofibers with Li4Ti5O12 towards highly reversible and durable TiO2-based anode for Li-ion batteries[J].Energy Technology,2019,7(1):107-112.
[29] Lu S Y,Shang Y F,Zheng W,et al.TiO2(B) nanosheets modified Li4Ti5O12 microsphere anode for high-rate lithium-ion batteries[J].Nanotechnology,2022,33(24):245404.
基金资助
国家自然基金联合基金项目(U20A2072)