近年来,碳基纳米复合材料的制备与应用备受关注,尤其是碳基纳米复合材料作为吸附剂的研究取得了一系列重要进展。综述了碳基纳米复合材料在制备中起到的关键影响因素。重点介绍了碳基纳米复合材料所具备的高比表面积、强机械性能、热稳定性等独特性能,及其在重金属废水、大气污染物吸附领域中的功能化应用。最后阐述了碳基纳米复合材料研究的不足和未来的发展方向,提出了对碳基纳米复合材料进行更进一步多功能化的研究,深度挖掘其在吸附领域的发展潜力等建议。
In recent years,the preparation and application of carbon-based nanocomposites have attracted much attention,especially the research on carbon-based nanocomposites as adsorbents has made a series of important progress.This paper reviewed the key influencing factors in the preparation of carbon-based nanocomposites.The unique properties of carbon-based nanocomposites,such as high specific surface area,strong mechanical properties,thermal stability,etc.,as well as their functional applications in the field of heavy metal wastewater and atmospheric pollutant adsorption were mainly introduced.Finally,the deficiencies and future development directions of carbon-based nanocomposites were expounded,and recommendations were put forward for further research on carbon-based nanocomposites and their development potential in the field of adsorption.
[1] 张静壳.聚糖/氧化石墨烯氟吸附剂的组分调变与结构调控的研究[D].北京:中国地质大学(北京),2019.
[2] 吴腾宴,成茵,吴钟晴,等.铥离子浓度对碲酸盐玻璃热稳定性及光谱性能的影响[J].硅酸盐通报,2013,32(4):583-588.
[3] Mullick A,Neogi S.Acoustic cavitation induced synthesis of zirconium impregnated activated carbon for effective fluoride scavenging from water by adsorption[J].Ultrasonics Sonochemistry,2018,45:65-77.
[4] Wu L,Liao L,Lv G,et al.Micro-electrolysis of Cr(Ⅵ) in the nanoscale zero-valent iron loaded activated carbon[J].Journal of Hazardous Materials,2013,254-255:277-283.
[5] Yao S,Wang L,Lv B,et al.Removal of trace Cr(Ⅵ) from aqueous solution by porous activated carbon balls supported by nanoscale zero-valent iron composites[J].Environmental Science and Pollution Research International,2020,27(7):7015-7024.
[6] 陆海楠,胡学玉,刘红伟.不同裂解条件对生物炭稳定性的影响[J].环境科学与技术,2013,36(8):11-14.
[7] Wang J,Chen N,Feng C,et al.Performance and mechanism of fluoride adsorption from groundwater by lanthanum-modified pomelo peel biochar[J].Environmental Science and Pollution Research International,2018,25(16):15326-15335.
[8] Yu Y,Wang C,Guo X,et al.Modification of carbon derived from Sargassum sp.by lanthanum for enhanced adsorption of fluoride[J].Journal of Colloid And Interface Science,2015,441:113-120.
[9] Vilakati B,Sivasankar V,Nxumalo E,et al.Fluoride removal studies using virgin and Ti(Ⅳ)-modified Musa paradisiaca (plantain pseudo-stem) carbons[J].Environmental Science and Pollution Research International,2018,26(12):11565-11578.
[10] Wan S,Lin J,Tao W,et al.Enhanced fluoride removal from water by nanoporous biochar-supported magnesium oxide[J].Industrial & Engineering Chemistry Research,2019,58(23):9988-9996.
[11] Hoa V,Prabhakaran S,Le K,et al.A single atom Ir doped heterophase of a NiMoP-NiMoPxOy ultrathin layer assembled on CNTs-graphene for high-performance water splitting[J].Journal of Materials Chemistry A,2022,10:14604-14612.
[12] Zhang X,Gao B,Cao C,et al.Adsorption of VOCs onto engineered carbon materials:a review[J].Journal of Hazardous Materials,2017,338:102-123.
[13] Liu W,Li Z,Zhang S,et al.Adsorption performance of multi-walled carbon nanotube-SiO2 adsorbent for toluene[J].Journal of Fuel Chemistry and Technology,2021,49(6):861-872.
[14] Dou B,Li J,Wang Y F,et al.Adsorption and desorption performance of benzene over hierarchically structured carbon-silica aerogel composites[J].Journal of Hazardous Materials,2011,196:194-200.
[15] 靳君,张聪璐.多壁碳纳米管/壳聚糖复合材料对水中染料的吸附[J].工业水处理,2022,42(4):100-105.
[16] 张漩卓一,张晓龙,孙雨琼,等.聚噻吩/碳纳米管复合材料的制备及其对重金属离子的吸附[J].当代化工,2021,50(3):562-566.
[17] Ji M,Ji H,Chang Y,et al.Toluene and acetaldehyde removal from air on to graphene-based adsorbents with microsized pores[J].Journal of Hazardous Materials,2018,344.
[18] Sumita R,Mukesh K,Sumit S,et al.Role of graphene in structural transformation of zirconium oxide[J].Journal of Sol-Gel Science and Technology,2014,71(3):470-476.
[19] Sun D,Ye L,Li Z.Visible-light-assisted aerobic photocatalytic oxidation of amines to imines over NH2-MIL-125(Ti)[J].Applied Catalysis B:Environmental,2015,164:428-432.
[20] Dai X,Wang Y,Wang X,et al.Polarity on adsorption and photocatalytic performances of N-GR/TiO2 towards gaseous acetaldehyde and ethylene[J].Applied Surface Science,2019,485:255-265.
[21] Li X,Yu J,Xie J,et al.Graphene in photocatalysis:a review[J].Small (Weinheim an der Bergstrasse,Germany),2016,12(48):6640-6696.
[22] Wang Z H,Shen D K,Wu C F,et al.State-of-the-art on the production and application of carbon nanomaterials from biomass[J].Green Chemistry,2018,20(22).
[23] Liang Q W,Luo H J,Geng J J,et al.Facile one-pot preparation of nitrogen-doped ultra-light graphene oxide aerogel and its prominent adsorption performance of Cr(Ⅵ)[J].Chemical Engineering Journal,2018,338:62-71.
[24] Bagher H,Afshin M,Farhood N,et al.Super high removal capacities of heavy metals (Pb2+ and Cu2+) using CNT dendrimer[J].Journal of Hazardous Materials,2017,336:146-157.
[25] Ding C C,Cheng W C,Wang X X,et al.Competitive sorption of Pb(Ⅱ),Cu(Ⅱ) and Ni(Ⅱ) on carbonaceous nanofibers:a spectroscopic and modeling approach[J].Journal of Hazardous Materials,2016,313:253-261.
[26] Zhu K R,Chen C L,Xu M,et al.Wakeel,Njud S.Alharbi.In situ carbothermal reduction synthesis of Fe nanocrystals embedded into N-doped carbon nanospheres for highly efficient U(Ⅵ) adsorption and reduction[J].Chemical Engineering Journal,2018,331:395-405.
[27] Yang C T,Miao G,Pi Y H,et al.Abatement of various types of VOCs by adsorption/catalytic oxidation:a review[J].Chemical Engineering Journal,2019,370:1128-1153.
[28] Li Z,Sun Z Y,Chen Y B,et al.Corrigendum to “The net GHG emissions of the Three Gorges Reservoir in China:Ⅱ.post-impoundment GHG inventories and full-scale synthesis”[J.Cleaner Prod.277,123961][J].Journal of Cleaner Production,2021,282.
[29] 李琳,辛智慧,秦君,等.氧化硅-石墨烯气凝胶介孔复合材料的合成及其对苯的吸附性能[J].化学通报,2021,84(10):1054-1059.
[30] Joung H J,Kim J H,Oh J S,et al.Catalytic oxidation of VOCs over CNT-supported platinum nanoparticles[J].Applied Surface Science,2014,290:267-273.
基金资助
广西民族大学校级引进人才科研启动项目(2020KJQD17);广西自然科学基金面上资助项目(2021GXNSFAA220075)
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