超疏水材料由于其独特的润湿性能,被广泛应用于日常生活和工业生产中。目前,单一功能化超疏水材料已经难以满足条件更为严苛的应用环境。近年来,超疏水表面在透明性、自修复、浸润性转换和耐久性等方面被广泛关注,并开展了一系列研究。这种材料的功能性应用于金属防护,能够极大地减少腐蚀介质与基底表面的接触,从而达到高效的防腐蚀效果,并满足表面的其他功能性需求。综述了功能性超疏水表面的构筑,及其在金属防护中的应用研究进展,并展望了超疏水材料在金属防护领域的研究热点和方向。
Due to their unique wetting properties,superhydrophobic materials are widely used in daily life and industrial production.Currently,single functionalized superhydrophobic materials are no longer able to meet the more demanding conditions of application environments.In recent years,superhydrophobic surfaces have been widely focused on transparency,self-healing,wettability conversion,and durability,and a series of studies have been conducted.The functional application of such materials in metal protection can significantly reduce the contact of corrosive media with the substrate surface,thus achieving efficient corrosion protection and meeting other functional requirements of the surface.This paper reviewed the construction of functionalized superhydrophobic surfaces and the research progress of their application in metal protection and looked forward to the research hotspots and directions of superhydrophobic materials in the field of metal protection.
[1] Sam E K,Sam D K,Lv X,et al.Recent development in the fabrication of self-healing superhydrophobic surfaces[J].Chemical Engineering Journal,2019,373:531-546.
[2] Quan Y Y,Chen Z,Lai Y,et al.Recent advances in fabricating durable superhydrophobic surfaces:a review in the aspects of structures and materials[J].Materials Chemistry Frontiers,2021,5(4):1655-1682.
[3] Wang Y,Liu Y,Li J,et al.Fast self-healing superhydrophobic surfaces enabled by biomimetic wax regeneration[J].Chemical Engineering Journal,2020,390:124311.
[4] Xue C H,Li H G,Guo X J,et al.Superhydrophobic anti-icing coatings with self-deicing property using melanin nanoparticles from cuttlefish juice[J].Chemical Engineering Journal,2021,424:130553.
[5] 郑龙珠,苏晓竞,李红强,等.功能性超疏水表面的构建及其应用进展[J].化工进展,2021,40(5):12.
[6] Li Z,Cao M,Li P,et al.Surface-embedding of functional micro-/nanoparticles for achieving versatile superhydrophobic interfaces[J].Matter,2019,1(3):661-673.
[7] Deng X,Mammen L,Zhao Y,et al.Transparent,thermally stable and mechanically robust superhydrophobic surfaces made from porous silica capsules[J].Advanced Materials,2011,23(26):2962-2965.
[8] Kim J G,Choi H J,Park K C,et al.Multifunctional inverted nanocone arrays for non-wetting,self-cleaning transparent surface with high mechanical robustness[J].Small,2014,10(12):2487-2494.
[9] Yu S,Guo Z,Liu W.Biomimetic transparent and superhydrophobic coatings:from nature and beyond nature[J].Chemical Communications,2015,51(10):1775-1794.
[10] Li X,Li B,Li Y,et al.Nonfluorinated,transparent,and spontaneous self-healing superhydrophobic coatings enabled by supramolecular polymers[J].Chemical Engineering Journal,2021,404:126504.
[11] Han G,Nguyen T B,Park S,et al.Moth-eye mimicking solid slippery glass surface with icephobicity,transparency,and self-healing[J].ACS Nano,2020,14(8):10198-10209.
[12] Verho T,Bower C,Andrew P,et al.Mechanically durable superhydrophobic surfaces[J].Advanced Materials,2011,23(5):673-678.
[13] Cheng L C,Simonaitis J W,Gadelrab K R,et al.Imparting superhydrophobicity with a hierarchical block copolymer coating[J].Small,2020,16(1):1905509.
[14] Zhu T,Cheng Y,Huang J,et al.A transparent superhydrophobic coating with mechanochemical robustness for anti-icing,photocatalysis and self-cleaning[J].Chemical Engineering Journal,2020,399:125746.
[15] Sam E K,Sam D K,Lv X,et al.Recent development in the fabrication of self-healing superhydrophobic surfaces[J].Chemical Engineering Journal,2019,373:531-546.
[16] Li Y,Li Q,Zhang C,et al.Intelligent self-healing superhydrophobic modification of cotton fabrics via surface-initiated ARGET ATRP of styrene[J].Chemical Engineering Journal,2017,323:134-142.
[17] Xue C H,Bai X,Jia S T.Robust,self-healing superhydrophobic fabrics prepared by one-step coating of PDMS and octadecylamine[J].Scientific Reports,2016,6(1):1-11.
[18] Ge M,Cao C,Liang F,et al.A “PDMS-in-water” emulsion enables mechanochemically robust superhydrophobic surfaces with self-healing nature[J].Nanoscale Horizons,2020,5(1):65-73.
[19] Zhang K,Xu F,Gao Y.Superhydrophobic and oleophobic dual-function coating with durablity and self-healing property based on a waterborne solution[J].Applied Materials Today,2021,22:100970.
[20] Lu C,Gao Y,Yu S,et al.Non-fluorinated flexible superhydrophobic surface with excellent mechanical durability and self-cleaning performance[J].ACS Applied Materials & Interfaces,2022,14(3):4750-4758.
[21] Ludwicki J M,Robinson F L,Steen P H.Switchable wettability for condensation heat transfer[J].ACS Applied Materials & Interfaces,2020,12(19):22115-22119.
[22] Liu Y,Gao H,Li S,et al.Bioinspired platform with reversibly switchable wettability for transfer and storage of droplets[J].Chemical Engineering Journal,2018,337:697-708.
[23] Gao H,Liu Y,Wang G,et al.A multifunctional graphene composite coating with switchable wettability[J].Chemical Engineering Journal,2021,415:128862.
[24] 陈逢军,向望,胡天.静电气喷磁响应复合微结构功能表面制备研究[J].机械工程学报,2022,58(9):9.
[25] Wang Q,Wang W,Ji X,et al.Self-healing coatings containing core-shell nanofibers with pH-responsive performance[J].ACS Applied Materials & Interfaces,2021,13(2):3139-3152.
[26] Yin X,Yu S,Wang K,et al.Fluorine-free preparation of self-healing and anti-fouling superhydrophobic Ni3S2 coating on 304 stainless steel[J].Chemical Engineering Journal,2020,394:124925.
[27] Wang J,Wang X,Zhao S,et al.Robust superhydrophobic mesh coated by PANI/TiO2 nanoclusters for oil/water separation with high flux,self-cleaning,photodegradation and anti-corrosion[J].Separation and Purification Technology,2020,235:116166.
[28] Xia Y,He Y,Chen C,et al.MoS2 nanosheets modified SiO2 to enhance the anticorrosive and mechanical performance of epoxy coating[J].Progress in Organic Coatings,2019,132:316-327.
[29] Zhao Z,Wang H,Liu Z,et al.Durable fluorine-free superhydrophobicpolyethersulfone (PES) composite coating with uniquely weathering stability,anti-corrosion and wear-resistance[J].Progress in Organic Coatings,2019,127:16-26.
[30] Zhou H,Wang H,Lin T,et al.Super-robust self-healing superhydrophobic coating with triboelectrification induced liquid self-repellency[J].Materials & Design,2021,211:110145.
[31] Zhang D,Wu G,Li H,et al.Superamphiphobic surfaces with robust self-cleaning,abrasion resistance and anti-corrosion[J].Chemical Engineering Journal,2021,406:126753.
[32] Peng F,Zhang D,Liu X,et al.Recent progress in superhydrophobic coating on Mg alloys:a general review[J].Journal of Magnesium and Alloys,2021,9(5):1471-1486.
[33] Li Z,Yang W,Yu Q,et al.New method for the corrosion resistance of AZ31 Mg alloy with a porous micro-arc oxidation membrane as an ionic corrosion inhibitor container[J].Langmuir,2018,35(5):1134-1145.
[34] Guo L,Gu C,Feng J,et al.Hydrophobic epoxy resin coating with ionic liquid conversion pretreatment on magnesium alloy for promoting corrosion resistance[J].Journal of Materials Science & Technology,2020,37:9-18.
[35] Jiang S,Zhang Z,Wang D,et al.Zif-8-based micro-arc oxidation composite coatings enhanced the corrosion resistance and superhydrophobicity of a Mg alloy[J].Journal of Magnesium and Alloys,2021,1-14.
[36] Zhang Y,Li N,Ling N,et al.Enhanced long-term corrosion resistance of Mg alloys by superhydrophobic and self-healing composite coating[J].Chemical Engineering Journal,2022,449:137778.
[37] Yin X,Mu P,Wang Q,et al.Superhydrophobic ZIF-8-based dual-layer coating for enhanced corrosion protection of Mg alloy[J].ACS Applied Materials & Interfaces,2020,12(31):35453-35463.
[38] Jiang Y,Zhang G,Xing J,et al.In situ growth and protectiveness mechanism of layered double hydroxide/oxide hierarchical structure on copper alloy in 3.5 wt% NaCl solution[J].Surface and Coatings Technology,2020,397:126042.
[39] Ji D,Wen X,Foller T,et al.Chemical vapour deposition of graphene for durable anticorrosive coating on copper[J].Nanomaterials,2020,10(12):2511.
[40] Li Y,Yang H,Wang F,et al.Fabrication and anti-corrosion properties of melamine-treated graphene oxide adsorbed on copper[J].Progress in Organic Coatings,2020,141:105564.
[41] Chen Y,Liu Y W,Xie Y,et al.Preparation and anti-corrosion performance of superhydrophobic silane/graphene oxide composite coating on copper[J].Surface and Coatings Technology,2021,423:127622.
[42] Khodakarami S,Zhao H,Rabbi K F,et al.Scalable corrosion-resistant coatings for thermal applications[J].ACS Applied Materials & Interfaces,2021,13(3):4519-4534.
[43] Xu W,Rajan K,Chen X G,et al.Facile electrodeposition of superhydrophobic aluminum stearate thin films on copper substrates for active corrosion protection[J].Surface and Coatings Technology,2019,364:406-415.
[44] Wang C X,Zhang X F.A non-particle and fluorine-free superhydrophobic surface based on one-step electrodeposition of dodecyltrimethoxysilane on mild steel for corrosion protection[J].Corrosion Science,2020,163:108284.
[45] Chen H,Fan H,Su N,et al.Highly hydrophobic polyaniline nanoparticles for anti-corrosion epoxy coatings[J].Chemical Engineering Journal,2021,420:130540.
[46] Wu H,Zhang L,Liu C,et al.Deposition of Zn-G/Al composite coating with excellent cathodic protection on low-carbon steel by low-pressure cold spraying[J].Journal of Alloys and Compounds,2020,821:153483.
[47] 赵亚梅,曹婷婷,丁思奇,等.SMEP/PDMS@ZnO@SiO2自修复超疏水涂层及其防腐性能[J].复合材料学报,2022,40:1-12.
基金资助
国家西部地区自然科学基金项目(51063003);国家西部地区自然科学基金项目(21664009);国家科技部2020年重点研发计划创新方法工作专项(SQ2020IMG100001)
PDF
