钢结构用膨胀型防火涂料的最新进展

谭春梅1, 陈雨聪2, 王晋磊1, 李佳兰1, 晏泓1*

化工新型材料 ›› 2023, Vol. 51 ›› Issue (12) : 231 -235.

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化工新型材料 ›› 2023, Vol. 51 ›› Issue (12) : 231-235. DOI: 10.19817/j.cnki.issn1006-3536.2023.12.016
开发与应用

钢结构用膨胀型防火涂料的最新进展

    谭春梅1, 陈雨聪2, 王晋磊1, 李佳兰1, 晏泓1*
作者信息 +

Recent advances in intumescent fireproof coatings for steel structures

  • Tan Chunmei1, Chen Yucong2, Wang Jinlei1, Li Jialan1, Yan Hong1
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文章历史 +
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摘要

膨胀型防火涂料在暴露于火焰时会膨胀形成保护炭层,有助于限制钢的温升以显著延长其失效时间,防止倒塌。近年来,基于可再生生物基材料、环保材料、一体化膨胀、纳米技术、协效剂和微纳米结构涂层等先进的防火体系被开发出来,为持久性长、释放热量低、烟雾少、有毒气体少、环保、多功能防火涂料的开发提供了潜在的解决方案。简要介绍了新的膨胀型阻燃剂基防火涂料,着重介绍了新膨胀防火涂料用协效剂,并进一步探讨了涂料的防火机理及发展方向。

Abstract

Intumescent fireproof coatings expand when exposed to flames to form a protective char layer that helps control temperature rise of steel to significantly prolong its failure time and prevent collapse.Some advanced fireproof systems have been developed in recent years based on renewable biobased materials,environmentally friendly materials,“all-in-one” intumescence,nanotechnology,synergistic agent,micro-nano structure coatings,etc.,which have provided potential solutions for the development of multifunctional fireproof coatings with great persistence,the low release of heat,smoke,and toxic gases,and environmental protection.This review outlined new intumescent flame retardants-based fireproof coatings,focusing on synergists used for these coatings.The fireproof mechanism and future development of intumescent fireproof coatings were further discussed.

关键词

钢结构 / 膨胀型防火涂料 / 膨胀型阻燃剂 / 协效剂 / 抑烟

Key words

steel structure / intumescent fireproof coating / intumescent flame retardant / synergist / smoke suppression

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钢结构用膨胀型防火涂料的最新进展[J]. 化工新型材料, 2023, 51(12): 231-235 DOI:10.19817/j.cnki.issn1006-3536.2023.12.016

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参考文献

[1] 李国强,王卫永.钢结构抗火安全研究现状与发展趋势[J].土木工程学报,2017,50(12):1-8.
[2] Alongi J,Han Z D,Bourbigot S.Intumescence:tradition versus novelty.a comprehensive review[J].Progress in Polymer Science,2015,51:28-73.
[3] 王清海,王秀娟,方健君,等.钢结构用水性膨胀型防火涂料的研究进展[J].涂层与防护,2021,42(12):52-58.
[4] Meng W H,Li P,Lan Y R,et al.Green fabrication of superhydrophilic and underwater superoleophobic coatings with applications in oil-water separation,photocatalysis and fire-retardance[J].Separation and Purification Technology,2020,233:115988.
[5] Price E J,Covello J,Tuchler A,et al.Intumescent,epoxy-based flame-retardant coatings based on poly(acrylic acid) compositions[J].ACS Applied Materials & Interfaces,2020,12(16):18997-19005.
[6] 刘婷婷,乔建江.复合氢氧化铝-季戊四醇的制备及其应用研究[J].现代化工,2018,38(9):155-159.
[7] Kazarinov R,Kowalczyk K,Ŀopiński J,et al.An intumescent coating system modified with waste poly(ethylene terephthalate) as a substitute for dipentaerythritol[J].Progress in Organic Coatings,2018,125:481-488.
[8] Ma Z,Zhang J,Maluk C,et al.A lava-inspired micro/nano-structured ceramifiable organic-inorganic hybrid fire-extinguishing coating[J].Matter,2022,5(3):911-932.
[9] De Souza M M,De Sá S C,Zmozinski A V,et al.Biomass as the carbon source in intumescent coatings for steel protection against fire[J].Industrial & Engineering Chemistry Research,2016,55(46):11961-11969.
[10] De Sá S C,De Souza M M,Peres R S,et al.Environmentally friendly intumescent coatings formulated with vegetable compounds[J].Progress in Organic Coatings,2017,113:47-59.
[11] 郭恩霞.钢结构用水性环氧基膨胀涂料防火和抑烟性能提升研究[D].北京:北京化工大学,2021.
[12] Long C T,Grunlan J C.Small molecule additives in multilayer polymer-clay thin films for improved heat shielding of steel[J].Npj Materials Degradation,2022,6(1):1-8.
[13] 王树伟.生物基膨胀型阻燃剂的制备及在钢结构防火涂料中的应用[D].沈阳:沈阳化工大学,2018.
[14] Beraldo C H M,Silveira M R S,Baldissera A F,et al.A new benzoxazine-based intumescent coating for passive protection against fire[J].Progress in Organic Coatings,2019,137:105321.
[15] Beheshti A,Heris S Z.Is MWCNT a good synergistic candidate in APP-PER-MEL intumescent coating for steel structure?[J].Progress in Organic Coatings,2016,90:252-257.
[16] Zhan W,Ni L,Gu Z,et al.The influences of graphene and carbon nanotubes on properties of waterborne intumescent fire resistive coating[J].Powder Technology,2021,385:572-579.
[17] Zhang D,Ma Z Y,Zhang Z H,et al.Graphene oxide nanosheets decorated with MgAlCr-layered double hydroxide nanosheets as flame retardant coatings for steel[J].ACS Applied Nano Materials,2021,4(8):8241-8250.
[18] Mohammadi S,Shariatpanahi H,Taromi F A.Influence of hybrid functionalized graphite nanoplatelets-tripolyphosphate on improvement in fire protection of intumescent fire resistive coating for steel structures[J].Polymer Degradation and Stability,2015,120:135-148.
[19] Lee Y X,Ahmad F,Kabir S,et al.Synergistic effects of tubular halloysite clay and zirconium phosphate on thermal behavior of intumescent coating for structural steel[J].Journal of Materials Research and Technology,2022,18:4456-4469.
[20] Yew M C,Sulong N H R,Yew M K,et al.Influences of flame-retardant fillers on fire protection and mechanical properties of intumescent coatings[J].Progress in Organic Coatings,2015,78:59-66.
[21] Feng W H,Wang Y F,Tang B,et al.Suppression on heat and smoke diffusion by zirconium nitride (ZrN) in intumescent flame retardant epoxy coatings[J].Progress in Organic Coatings,2020,146:105714.
[22] Hu X,Zhu X,Sun Z.Efficient flame-retardant and smoke-suppression properties of MgAlCO3-LDHs on the intumescent fire retardant coating for steel structures[J].Progress in Organic Coatings,2019,135:291-298.
[23] Gillani Q F,Ahmad F,Mutalib M I A,et al.Effects of halloysite nanotube reinforcement in expandable graphite based intumescent fire retardant coatings developed using hybrid epoxy binder system[J].Chinese Journal of Polymer Science,2018,36(11):1286-1296.
[24] Yang Z,Xiao G,Chen C,et al.Synergistic decoration of organic titanium and polydopamine on boron nitride to enhance fire resistance of intumescent waterborne epoxy coating[J].Colloids and Surfaces A:Physicochemical and Engineering Aspects,2021,621:126561.
[25] Samiee R,Montazeri S,Ramezanzadeh B,et al.Ce-MOF nanorods/aluminum hydroxide (AlTH) synergism effect on the fire-retardancy/smoke-release and thermo-mechanical properties of a novel thermoplastic acrylic intumescent composite coating[J].Chemical Engineering Journal,2022,428:132533.
[26] Dzulkafli H H,Ahmad F,Ullah S,et al.Effects of talc on fire retarding,thermal degradation and water resistance of intumescent coating[J].Applied Clay Science,2017,146:350-361.
[27] Ahmad F,Ullah S,Merican N,et al.An investigation on thermal performance of wollastonite and bentonite reinforced intumescent fire-retardant coating for steel structures[J].Construction and Building Materials,2019,228:15.
[28] Hu X C,Luo Y Q,Liu W,et al.Synergistic interaction between inorganic layered materials and intumescent fire retardants for advanced fire protection[J].Carbon,2022,187:290-301.
[29] Beheshti A,Heris S Z.Experimental investigation and characterization of an efficient nanopowder-based flame retardant coating for atmospheric-metallic substrates[J].Powder Technology,2015,269:22-29.
[30] Yew M C,Yew M K,Saw L H,et al.Influences of nano bio-filler on the fire-resistive and mechanical properties of water-based intumescent coatings[J].Progress in Organic Coatings,2018,124:33-40.
[31] Beh J H,Yew M K,Yew M C,et al.Characterization and fire protection properties of rubberwood biomass ash formulated intumescent coatings for steel[J].Journal of Materials Research and Technology,2021,14:2096-2106.
[32] Nasir K M,Sulong N H R,Johan M R,et al.Synergistic effect of industrial- and bio-fillers waterborne intumescent hybrid coatings on flame retardancy,physical and mechanical properties[J].Progress in Organic Coatings,2020,149:14.

基金资助

国家自然科学基金面上项目(22178242);山西省重点研发计划项目(202102040201009)

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