近年来,树枝状介孔二氧化硅纳米颗粒(DMSNs)成为催化界的研究热点,因其具有大的开孔结构、高比表面积、优异的溶剂分散性、良好的生物相容性等,上述优点使得DMSNs在实现CO2的捕获和催化转化中取得了良好的发展。结合国内外研究进展,总结了近年树枝状介孔二氧化硅基纳米功能材料在CO2催化转化方面的应用和反应机制,并与传统二氧化硅介孔材料(如SBA-15或MCM-41)的催化转化性能进行比较。最后对该材料在CO2催化转化方面的应用进行了展望。
In recent years,dendritic mesoporous silica nanoparticles (DMSNs) have become a research hotspot in the catalytic field due to their large opening structure,high specific surface area,excellent solvent dispersion and good biocompatibility,etc.,and these advantages enable the significant development of DMSNs in the capture of CO2 as well as catalytic conversion.Combined with the research progress at home and abroad,the applications and reaction mechanisms of dendritic mesoporous silica-based nano-functional materials in the conversion of CO2 were summarized.Their catalytic properties were compared with those of traditional silica mesoporous materials (such as SBA-15 or MCM-41).Finally,the application of this material in the conversion of CO2 was prospected.
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基金资助
国家自然科学基金(52063029);陕西省自然科学基础研究计划资助项目(2022JM-200);延安大学大学生创新创业训练计划项目(D2021025)
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