金属-有机骨架(MOF)材料是由金属离子或金属簇中心和有机配体组成的多孔材料,但是MOF存在化学稳定性较差、机械强度低、导电性能弱等缺点。用功能材料对MOF进行改性制备的复合材料,不仅具备MOF自身的优点,还能改善其他方面的性能,目前已广泛应用于气体吸附与分离、催化反应、药物传输、传感检测等领域。综述了近年来不同功能材料对MOF的改性研究进展,并对MOF复合材料的未来发展前景进行了展望。
Metal-organic framework (MOF) materials are porous materials composed of metal ions or metal cluster centers and organic ligands.However,MOF materials have the disadvantages of poor chemical stability,low mechanical strength and weak conductivity.The composite materials obtained by modifying MOF with functional materials not only have the advantages of MOF,but also can improve the performance of other aspects.At present,they have been widely used in the fields of gas adsorption and separation,catalytic reaction,drug delivery and sensing detection.The research progress on the modification of MOF by different functional materials in recent years was reviewed,and the development prospects of MOF composites were discussed.
[1] 李宏强.金属有机骨架及其复合材料在食品安全检测中的应用[J].理化检验-化学分册,2022,58(5):612-620.
[2] Guan H,Leblanc R J,Xie S,et al.Recent progress in the syntheses of mesoporous metal-organic framework materials[J].Coordination Chemistry Reviews,2018,369:76-90.
[3] Chen W,Wu C.Synthesis,functionalization,and applications of metal-organic frameworks in biomedicine[J].Dalton Transactions,2020,47:2114-2133.
[4] Marimuthu M,Arumugam S S,Jiao T H,et al.Metal organic framework based sensors for the detection of food contaminants[J].Trends in Analytical Chemistry,2022,154:116642-116666.
[5] 王世珍,刘凯泷,王世燕,等.新型材料固定化氧化还原酶研究进展[J].福州大学学报(自然科学版),2021,49(4):568-576.
[6] 饶强海,胡光煊,张春媚,等.碳基材料构建电化学传感器实现苯二酚异构体的超敏精准检测:综述[J].材料导报,2023,37(5):42-58.
[7] 王全璐,宋慧敏,张展鹏,等.金属有机骨架及其复合材料超电容性能研究进展[J].化学推进剂与高分子材料,2021,19(6):19-25.
[8] Yang S J,Choi J Y,Chae H K,et al.Preparation and enhanced hydrostability and hydrogen storage capacity of CNT@MOF-5 hybrid composite[J].Chemistry of Materials,2009,21:1893-1897.
[9] 史琳,叶倩玲,杨琦,等.UiO-66/氧化石墨烯的制备及对水中四氯化碳的吸附[J].环境工程学报,2019,13(5):1063-1072.
[10] Qian D,Lei C,Hao G,et al.Synthesis of hierarchical porous carbon monoliths with incorporated metal-organic frameworks for enhancing volumetric based CO2 capture capability[J].ACS Apply Mater Interfaces,2012,4(11):6125-6132.
[11] Seddon K R.Ionic liquids for clean technology[J].Journal of Chemical Technology and Biotechnology,1997,68(4):351-356.
[12] Ahmed I,Adhikary K K,Lee Y R,et al.Ionic liquid entrapped UiO-66:efficient adsorbent for Gd3+ capture from water[J].Chemical Engineering Journal,2019,370:792-799.
[13] Zeeshan M,Keskin S,Uzun A.Enhancing CO2/CH4 and CO2/N2 separation performances of ZIF-8 by post-synthesis modification with [BMIM][SCN][J].Polyhedron,2018,155:485-492.
[14] 费佳颖,梁艺萱,李寒冰,等.离子液体改性金属-有机骨架复合材料的构筑策略及在环境介质中的应用[J].复合材料学报,2022,39(6):2527-2542.
[15] 杨新月,高莉,孙亚明,等.离子液体修饰金属有机骨架复合材料的制备及其在分离分析中的应用[J].分析化学,2020,48(12):1607-1615.
[16] Kinik F P,Uzun A,Keskin S.Ionic liquid/metal-organic framework composites:from synthesis to applications[J].ChemSusChem,2017,10(14):2842-2863.
[17] Yang H M,Song X L,Yang T L,et al.Electrochemical synthesis of flower shaped morphology MOFs in an ionic liquid system and their electrocatalytic application to the hydrogen evolution reaction[J].RSC Advances,2014,4(30):15720-15726.
[18] Kavak S,Kulak H,Polat H M,et al.Fast and selective adsorption of methylene blue from water using [BMIM][PF6]-incorporated UiO-66 and NH2-UiO-66[J].Crystal Growth & Design,2020,20(6):3590-3595.
[19] 苏丹,吴天琪,杨雨,等.量子点标记免疫分析技术在食品安全检测中的应用现状[J].食品研究与开发,2022,43(10):210-216.
[20] Zhang N,Li J J,Li Y,et al.Visible-light driven boosting electron-hole separation in CsPbBr3 QDs@2D Cu-TCPP heterojunction and the efficient photoreduction of CO2[J].Journal of Colloid and Interface Science,2022,608:3192-3203.
[21] Ren J J,Li T R,Zhou X P,et al.Encapsulating all-inorganic perovskite quantum dots into mesoporous metal organic frameworks with significantly enhanced stability for optoelectronic applications[J].Chemical Engineering Journal,2019,358:30-39.
[22] 羌越,陈璐,张静.碳量子点/金属有机骨架材料修饰玻碳电极用于双酚A的电化学检测[J].理化检验-化学分册,2021,57(1):7-14.
[23] 李晓利,张国宏,张晶.嵌入量子点的MOFs制备及在GSH检测中的应用[J].山东化工,2022,51(8):63-65;74.
[24] Ngan Tran T K,Ho H L,Nguyen H V,et al.Photocatalytic degradation of Rhodamine B in aqueous phase by bimetallic metal-organic framework M/Fe-MOF (M=Co,Cu,and Mg)[J].Open Chemistry,2022,20(1):52-60.
[25] Lai H S,Dai H B,Li G K,et al.Rapid determination of pesticide residues in fruit and vegetable using Au@AgNPs decorated 2D Ni-MOF nanosheets as efficient surface-enhanced Raman scattering substrate[J].Sensors & Actuators:B Chemical,2022,369:132360-132368.
[26] Li M M,Yuan J W,Wang G,et al.One-step construction of Ti-In bimetallic MOFs to improve synergistic effect of adsorption and photocatalytic degradation of bisphenol A[J].Separation and Purification Technology,2022,298:121658-121669.
[27] 冯爱玲,王彦妮,徐榕,等.多功能MOFs复合材料研究进展[J].功能材料,2018,49(11):11061-11070.
[28] Li K,Zou S,Jin G,et al.Efficient removal of selenite in aqueous solution by MOF-801 and Fe3O4/MOF-801:adsorptive behavior and mechanism study[J].Separation and Purification Technology,2022,296:121384-121399.
[29] Shi Y,Wang L,Dong S,et al.Wool-ball-like BiOBr@ZnFe-MOF composites for degradation organic pollutant under visible-light:synthesis,performance,characterization and mechanism[J].Optical Materials,2022,131:112580-112592.
[30] Le Ouay B,Boudot M,Kitao T,et al.Nanostructuration of PEDOT in porous coordination polymers for tunable porosity and conductivity[J].Journal of the American Chemical Society,2016,138(32):10088-10091.
[31] Huang G,Yang Q,Xu Q,et al.Polydimethylsiloxane coating for a palladium/MOF composite:highly improved catalytic performance by surface hydrophobization[J].Angewandte Chemie,2016,128(26):7505-7509.
[32] 奚润晖.导电聚合物修饰MOFs及其气敏特性研究[D].成都:电子科技大学,2022.
[33] Salestan S K,Pirzadeh K,Rahimpour A,et al.Poly (ether-block amide) thin-film membranes containing functionalized MIL-101 MOFs for efficient separation of CO2/CH4[J].Journal of Environmental Chemical Engineering,2021,9(5):105820-105830.
[34] 龚文朋,柯晓芬,李志鹏,等.磷钼钨杂多酸修饰金属有机骨架MOF-5复合材料吸附亚甲基蓝[J].应用化学,2016,33(9):1047-1055.
[35] Xu Y,Zhao X,Chang R,et al.Designing heterogeneous MOF-on-MOF membrane with hierarchical pores for effective water treatment[J].Journal of Membrane Science,2022,658:120737-120743.
基金资助
江西省教育厅科学技术研究项目(GJJ212102)
PDF
