纤维素纳米晶(CNC)具有高强度、高模量、生物可降解和优良的机械性能,常被用作生物可降解纤维的增强材料。介绍了CNC的来源、制备方法以及表面改性方法,根据近年来国内外对CNC增强生物可降解复合纤维的研究,总结了CNC对生物可降解复合纤维热性能、力学性能、吸水性和抗菌性的影响。
Cellulose nanocrystals(CNCs)are often used as reinforcement materials for biodegradable fibers due to their high strength,high modulus,biodegradability and excellent mechanical properties.The sources,preparation methods and surface modification methods of CNC were introduced,and the effects of CNC on the thermal,mechanical,water absorption and antimicrobial properties of biodegradable composite fibers were summarized based on the research on CNC-reinforced biodegradable composite fibers at home and abroad in recent years.
[1] Han J Q,Yue Y Y,Wu Q L,et al.Effects of nanocellulose on the structure and properties of poly(vinyl alcohol)-borax hybrid foams[J].Cellulose,2017,24(10):4433-4448.
[2] Dhar P,Bhardwaj U,Kumar A,et al.Investigations on rheological and mechanical behavior of poly(3-hydroxybutyrate)/cellulose nanocrystal based nanobiocomposites[J].Polymer Composites,2017,38:392-401.
[3] Mariano M,El Kissi N,Dufresne A.Cellulose nanocrystals and related nanocomposites:review of some properties and challenges[J].Journal of Polymer Science,2014,52(12):791-806.
[4] Chen M J,Wan C Y,Zhang Y,et al.Fibre orientation and mechanical properties of short glass fibre reinforced PP compo-sites[J].Polymers & Polymer Composites,2005,13(3):253-262.
[5] Xiao M,Yu J,Zhu J,et al.Effect of UHMWPE concentration on the extracting,drawing,and crystallizing properties of gel fibers[J].Journal of Materials Science,2011,46(17):5690-5697.
[6] Yang Q B.Research on the tensile and surface frictional pro-perty of PLA fibers[C].International Conference on Material Science,Environmental Science and Computer Science (MSESCS 2011).2011:287-290.
[7] Tang J,Song Y,Tanvir S,et al.Polyrhodanine cated cellulose nanocrystals:a sustainable antimicrobial agent[J].ACS Sustainable Chemistry & Engineering,2015,3(8):1801-1809.
[8] 刘亚芝,宗雪,蔡以兵,等.碳纳米管(CNTs)的改性及其熔纺PLA复合纤维的结构与力学性能研究[J].化工新型材料,2015,43(4):107-110.
[9] Zhang Z,Wang S C,Zhang J,et al.Self-formation of elastomer network assisted by nano-silicon dioxide particles:a simple and efficient route toward polymer nanocomposites with simultaneous improved toughness and stiffness[J].Chemical Engineering Journal,2016,285:439-448.
[10] 曹嘉欣,陈进,邵水源.静电纺丝法制备石墨烯/聚乙烯吡咯烷酮复合纤维及其导电性能研究[J].化工新型材料,2020,48(6):171-174.
[11] Oguzlu H,Danumah C,Boluk Y.Colloidal behavior of aqueous cellulose nanocrystal suspensions[J].Current Opinion in Colloid & Interface Science,2017,29:46-56.
[12] 周孟娇,杨思彤,贾清秀.纤维素纳米晶材料研究进展[J].化工新型材料,2019,47(9):40-44.
[13] Khalil H,Bhat A H,Yusra A F I.Green composites from sustainable cellulose nanofibrils:a review[J].Carbohydrate Polymers,2012,87(2):963-979.
[14] Espinosa S C,Kuhnt T,Foster E J,et al.Isolation of thermally stable cellulose nanocrystals by phosphoric acid hydrolysis[J].Biomacromolecules,2013,14(4):1223-1230.
[15] Tang J T,Berry R M,Tam K C.Stimuli-responsive cellulose nanocrystals for surfactant-free oil harvesting[J].Biomacromolecules,2016,17(5):1748-1756.
[16] 梁真真,白绘宇,张胜文,等.载银聚乙烯醇/纳米晶纤维素/氧化石墨烯复合膜的制备及性能研究[J].化工新型材料,2019,47(1):87-91.
[17] Henriksson M,Henriksson G,Berglund L A,et al.An environmentally friendly method for enzyme-assisted preparation of microfibrillated cellulose (MFC) nanofibers[J].European Polymer Journal,2007,43(8):3434-3441.
[18] Wang H,Pudukudy M,Ni Y H,et al.Synthesis of nanocrystalline cellulose via ammonium persulfate-assisted swelling followed by oxidation and their chiral self-assembly[J].Cellulose,2020,27(2):657-676.
[19] Gao A,Chen H,Hou A,et al.Preparation of high-aspect-ratio cellulose nanocrystals by solvothermal synthesis followed by mechanical exfoliation[J].Cellulose,2019,26(10):5937-5945.
[20] Zaman M,Xiao H N,Chibante F,et al.Synthesis and characterization of cationically modified nanocrystalline cellulose[J].Carbohydrate Polymers,2012,89(1):163-170.
[21] Li J H,Wei X Y,Wang Q H,et al.Homogeneous isolation of nanocellulose from sugarcane bagasse by high pressure homogenization[J].Carbohydrate Polymers,2012,90(4):1609-1613.
[22] Teodoro K B R,Teixeira E D M,Correa A C,et al.Whiskers from sisal fibers obtained under different acid hydrolysis conditions:effect of time and temperature of extraction[J].Polimeros,2011,21(4):280-285.
[23] Le Normand M,Moriana R,Ek M.Isolation and characterization of cellulose nanocrystals from spruce bark in a biorefinery perspective[J].Carbohydrate Polymers,2014,111:979-987.
[24] Beck-Candanedo S,Roman M,Gray D G.Effect of reaction conditions on the properties and behavior of wood cellulose nanocrystal suspensions[J].Biomacromolecules,2005,6(2):1048-1054.
[25] Araki J,Kuga S.Effect of trace electrolyte on liquid crystal type of cellulose microcrystals[J].Langmuir,2001,17(15):4493-4496.
[26] 李娜,丁姜鑫,褚特野,等.纤维素纳米晶的性能及应用研究进展[J].棉纺织技术,2021,49(12):75-79.
[27] 李金召,李政,庄旭品,等.纤维素纳米晶体的制备及其在复合材料中的应用[J].化学进展,2021,33(8):1293-1310.
[28] Reid M S,Stimpson T C,Niinivaara E,et al.Comparing soft semicrystalline polymer nanocomposites reinforced with cellulose nanocrystals and fumed silica[J].Industrial & Engineering Chemistry Research,2018,57(1):220-230.
[29] Bledzki A K,Gassan J.Composites reinforced with cellulose based fibres[J].Progress in Polymer Science,1999,24(2):221-274.
[30] Rol F,Belgacem M N,Gandini A,et al.Recent advances in surface-modified cellulose nanofibrils[J].Progress in Polymer Science,2019,88:241-264.
[31] Mulyadi A,Deng Y.Surface modification of cellulose nanofibrils by maleated styrene block copolymer and their compo-site reinforcement application[J].Cellulose,2016,23(1):519-528.
[32] Ifuku S,Yano H.Effect of a silane coupling agent on the mechanical properties of a microfibrillated cellulose composite[J].International Journal of Biological Macromolecules,2015,74:428-432.
[33] Taipina M D O,Favaro Ferrarezi M M,Pagotto Yoshida I V,et al.Surface modification of cotton nanocrystals with a silane agent[J].Cellulose,2013,20(1):217-226.
[34] Xu P,Cao Y,Wu B,et al.Effects of modified nanocrystalline cellulose on the hydrophilicity,crystallization and mechanical behaviors of poly(3-hydroxybutyrate-co-3-hydroxyhexanoate)[J].New Journal of Chemistry,2018,42(14):11972-11978.
[35] Abraham E,Kam D,Nevo Y,et al.Highly modified cellulose nanocrystals and formation of epoxy-nanocrystalline cellulose (CNC) nanocomposites[J].ACS Appl Mater Interfaces,2016,8(41):28086-28095.
[36] Miao C W,Hamad W Y.Alkenylation of cellulose nanocrystals (CNC) and their applications[J].Polymer,2016,101:338-346.
[37] De Oliveira Santos R P,Ramos L A,Frollini E.Bio-based electrospun mats composed of aligned and nonaligned fibers from cellulose nanocrystals,castor oil,and recycled PET[J].Int J Biol Macromol,2020,163:878-887.
[38] Bellani C F,Pollet E,Hebraud A,et al.Morphological,thermal,and mechanical properties of poly(ε-caprolactone)/poly(ε-caprolactone)-grafted-cellulose nanocrystals mats produced by electrospinning[J].Journal of Applied Polymer Science,2016,133(21):43445.
[39] Leones A,Mujica-Garcia A,Arrieta M P,et al.Organic and inorganic PCL-based electrospun fibers[J].Polymers,2020,12(6):1325.
[40] Ci M Y,Liu J,Shang S L,et al.The effect of HPMC and CNC on the structure and properties of alginate fibers[J].Fibers and Polymers,2020,21(10):2179-2185.
[41] Chen S,Schueneman G,Pipes R B,et al.Effects of crystal orientation on cellulose nanocrystals-cellulose acetate nanocomposite fibers prepared by dry spinning[J].Biomacromolecules,2014,15(10):3827-3835.
[42] Arrieta M P,López J,López D,et al.Biodegradable electrospun bionanocomposite fibers based on plasticized PLA-PHB blends reinforced with cellulose nanocrystals[J].Industrial Crops and Products,2016,93:290-301.
[43] Wang D,Cheng W L,Wang Q X,et al.Preparation of electrospun chitosan/poly(ethylene oxide) composite nanofibers reinforced with cellulose nanocrystals:structure,morphology,and mechanical behavior[J].Composites Science and Techno-logy,2019,182:107774-107782.
[44] Ma X,Li R,Zhao X,et al.Biopolymer composite fibres composed of calcium alginate reinforced with nanocrystalline cellulose[J].Composites Part A:Applied Science and Manufacturing,2017,96:155-163.
[45] Rashtchian M,Hivechi A,Bahrami S H,et al.Fabricating alginate/poly(caprolactone) nanofibers with enhanced bio-mechanical properties via cellulose nanocrystal incorporation[J].Carbohydr Polym,2020,233:115873.
[46] Angela F J,Julia R S,Gabriela R S,et al.Libidibia ferrea loaded in bacterial nanocellulose:evaluation of antimicrobial acti-vity and wound care[J].Brazilian Journal of Development,2020,6(2):5996-6013.
[47] Homaeigohar S,Boccaccini A R.Antibacterial biohybrid nanofibers for wound dressings[J].Acta Biomaterialia,2020,107:25-49.
[48] Ribeiro A S,Costa S M,Ferreira D P,et al.Chitosan/nanocellulose electrospun fibers with enhanced antibacterial and antifungal activity for wound dressing applications[J].Reactive and Functional Polymers,2021,159:104808-104818.
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