浓度及溶剂配比对PVDF静电纺纳米纤维膜的影响

布热比耶·玉苏普, 李新梅*, 王晓辉, 杨睿

化工新型材料 ›› 2023, Vol. 51 ›› Issue (10) : 116 -120.

PDF
化工新型材料 ›› 2023, Vol. 51 ›› Issue (10) : 116-120. DOI: 10.19817/j.cnki.issn1006-3536.2023.10.039
新材料与新技术

浓度及溶剂配比对PVDF静电纺纳米纤维膜的影响

    布热比耶·玉苏普, 李新梅*, 王晓辉, 杨睿
作者信息 +

Effect of concentration and solvent ratio on PVDF electrospun nanofiber membranes

  • Burebiye Yusupu, Li Xinmei, Wang Xiaohui, Yang Rui
Author information +
文章历史 +
PDF

摘要

以聚偏氟乙烯(PVDF)为纺丝溶质,N,N-二甲基甲酰胺(DMF)与四氢呋喃(THF)为混合溶剂,配制不同浓度和不同溶剂配比的纺丝溶液,利用静电纺丝技术制备了PVDF纳米纤维膜。通过扫描电子显微镜(SEM)、光学接触角测量仪、ImageJ软件对所制纳米纤维膜的微观形貌、疏水性能、纤维直径等进行分析,研究了不同浓度和不同溶剂配比对纳米纤维膜的影响。结果表明:当溶液浓度为10%(PVDF质量分数),DMF/THF溶剂配比为3/2时静电纺丝制备的纳米纤维膜纤维形貌良好,直径分布均匀,具有良好的疏水效果。

Abstract

Polyvinylidene fluoride (PVDF) was used as the spinning solute,and N,N-dimethyl formamide (DMF) and tetrahydrofuran (THF) were used as the mixed solvent to prepare spinning solutions with different concentrations and solvent ratios,and then PVDF nanofiber membranes were obtained by electrostatic spinning technique.By scanning electron microscope (SEM),optical contact angle measuring instrument and ImageJ software,the microscopic topography,hydrophobic properties and fiber diameter of the manufactured nanofiber membranes were analyzed,and the effects of different concentrations and different solvent ratios on the nanofiber membranes were studied.The results showed that when the solution concentration was 10% (PVDF mass fraction) and the DMF/THF solvent ratio was 3/2,the nanofiber membrane fibers prepared by electrostatic spinning exhibited good morphology,uniform diameter distribution,and excellent hydrophobicity.

关键词

静电纺丝 / 聚偏氟乙烯 / 纺丝液浓度 / 溶剂配比

Key words

electrostatic spinning / polyvinylidene fluoride / spinning solution concentration / solvent ratio

引用本文

引用格式 ▾
浓度及溶剂配比对PVDF静电纺纳米纤维膜的影响[J]. 化工新型材料, 2023, 51(10): 116-120 DOI:10.19817/j.cnki.issn1006-3536.2023.10.039

登录浏览全文

4963

注册一个新账户 忘记密码

参考文献

[1] 郝明磊,郭建生.国内外静电纺丝技术的研究进展[J].纺织导报,2013(1):58-60.
[2] 林丹丹,赵伟,马然,等.从专利的角度梳理静电纺丝技术发展的脉络[J].中国发明与专利,2015(1):120-124.
[3] 魏娜,仇久安,孙诚.JDFSS-1型多功能静电纺丝机的研制[J].包装工程,2015,36(21):70-74.
[4] 王艳芝.静电纺丝技术发展简史及应用[J].合成纤维工业,2018,41(4):52-57.
[5] 孙娟,姚琛,李新松.抗菌聚合物纳米纤维的研究进展[J].高分子通报,2010(8):27-33.
[6] Xiang Shang,Guo Zhenghua,Wang Yuelin,et al.The microstructure regulation,strengthening,toughening and hydrophilicity ofpolyamide6 in fabricating poly (vinylidene fluoride)-based flat membrane via thethermally induced phase separation technique[J].European Polymer Journal,2020,126:109568.
[7] Zhang Guiyuan,ZhanYingqing,He Shuangjiang,et al.Construction of super hydrophilic/underwater superoleophobic polydopamine-modified h-BN/poly(aryleneethernitrile) composite membrane for stable oil-water emulsions separation[J].Polymers for Advanced Technologies,2020,31(5):1007-1018.
[8] 贠延滨,刘丽英,马润宇.聚偏氟乙烯膜的研究进展[J].膜科学与技术,2003(2):57-61.
[9] Wang Andong,Shao Mingwei,Yang Fan,et al.Preparation and properties of antibacterial PVDF composite thin films[J].European PolymerJournal,2021,160:110803.
[10] Tarasova E,Tamberg K G,Viirsalu M,et al.Formation of uniform PVDF fibers under ultrasound exposure in presence of anionic surfactant[J].Journal of Electrostatics,2015,76:39-47.
[11] 张庆华,李晨曦,许琪.静电纺丝法制备PVDF纳米纤维[J].合成技术及应用,2021,36(2):6-9.
[12] Wang Y R,Zheng J M,Ren G Y,et al.A flexible piezo electric for cesensor based on PVDF fabrics[J].Smart Materials and Structures,2011,20(4):45009.
[13] 朱丹华,王文利,李志平,等.静电纺丝法制备聚偏氟乙烯(PVDF)及其复合纳米纤维的应用与发展前景[J].功能材料,2016,47(8):8058-8063.
[14] Bottino A,Camera-Roda G,Capannelli G,et al.The formation of microporous polyvinylidene difluoride membranes by phase separation[J].Journal of Membrane Science,1991,57(1):1-20.
[15] Maria Lígia,Costa Ligia Maria Manzine,Elida Rosário,et al.Effect of solution concentration on the electrospray/electrospinning transition and on the crystalline phase of PVDF[J].Materials Sciences and Applications,2010,1(4):247-252.
[16] Song Yoseung,Yun Yonghyeon,Lee Deukyong,et al.Effect of PVDF concentration and number of fiber lines on piezoelectric properties of polymeric PVDF biosensors[J].Fibers and Polymers,2021,22:1200-1207.
[17] 周菊,赵建茹,李玲.添加剂和温度对PVDF微孔膜性能的影响[J].新疆大学学报:自然科学版,2008,25(2):198-203.
[18] 张杰琳,吕斯濠,范洪波,等.溶剂对PVDF空气滤膜结构性能的影响[J].东莞理工学院学报,2011,18(5):94-98.
[19] 张国辉.新型聚己内酯基超疏水膜的制备及其油水分离性能的研究[D].长春:吉林大学,2019.
[20] 姜钦亮.PVDF静电纺丝纳米纤维疏水膜的制备及其膜蒸馏特性研究[D].南昌:南昌大学,2015.
[21] Faturechi Rahim,Hashemi Ata,Abolfathi Nabiollah,et al.Fabrications of small diameter compliance by pass conduitusing electrospinning of clinical grade polyurethane[J].Vascular,2019,27(6):636-647.
[22] Deitzel J M,Kleinmeyer J,Harris D,et al.The effect of processing variables on the morphology of electrospun nanofibers and textiles[J].Polymer,2001,42(1):261-272.
[23] Fong Hao,Reneker Darrell H.Elastomeric nanofibers of styrene-butadiene-styrene triblock copolymer[J].Journal of Polymer Science Part B:Polymer Physics,1999,37(24):3488-3493.

基金资助

国家自然科学基金(51865055和52161017)

AI Summary AI Mindmap
PDF

878

访问

0

被引

导航
相关文章

AI思维导图

/