电子设备的迅速发展和广泛使用产生了大量电磁波,不仅影响其他电子设备的正常运行,还对人类健康造成危害。高性能电磁干扰屏蔽(EMI)和电磁波吸收(EMA)材料对控制电磁污染、保护人体和其他系统在民用或军事应用中至关重要。作为一种新型的二维材料,MXenes因具有特殊的层状结构、高比表面积、丰富的天然缺陷和特殊的金属特征,近年来在电磁屏蔽和微波吸收领域引起了广泛关注。主要介绍了Ti3C2Tx MXene的合成方法和特点,并总结了近年来它在电磁屏蔽和微波吸收性能方面的最新研究和应用。主要创新点在于重点介绍Ti3C2Tx MXene的合成工艺、结构设计以及引入不同材料形成不同复合材料对其电磁性能的影响。
The rapid development and wide use of electronic equipment have produced a large number of electromagnetic waves,which not only affect the normal operation of other electronic equipment,but also do harm to human health.High-performance electromagnetic interference shielding (EMI) and electromagnetic absorption (EMA) materials are critical for controlling electromagnetic contamination and protecting the human body and other systems in civil or military applications.As a new two-dimensional material,MXene has attracted extensive attention in the fields of EMI and EMA in recent years because of its special layered structure,high specific surface area,abundant natural defects and special metallic characteristics.In this paper,the synthesis methods and characteristics of Ti3C2Tx MXene were introduced,and the latest research and applications of Ti3C2Tx MXene in electromagnetic shielding and microwave absorption properties were summarized.The main innovation points were the introduction of the synthesis process,structure design of Ti3C2Tx Mxene and the influence of the introduction of different materials to form different composites on its electromagnetic properties.
[1] Liu X L,Wu J S,He J,et al.Electromagnetic interference shielding effectiveness of titanium carbide sheets[J].Materials Letters,2017,205:261-263.
[2] Feng D,Liu P,Wang Q.Exploiting the piezoresistivity and EMI shielding of polyetherimide/carbon nanotube foams by tailoring their porous morphology and segregated CNT networks[J].Composites Part A:Applied Science and Manufacturing,2019,124:105463.
[3] Joseph J,Mund A P R,John D A,et al.Graphene and CNT filled hybrid thermoplastic composites for enhanced EMI shielding effectiveness[J].Materials Research Express,2019,6(8):085617.
[4] Ren F,Li Z,Xu L,et al.Large-scale preparation of segregated PLA/carbon nanotube composite with high efficient electromagnetic interference shielding and favourable mechanical properties[J].Composites Part B:Engineering,2018,155:405-413.
[5] Dai M,Zhai Y,Wu L,et al.Magnetic aligned Fe3O4-reduced graphene oxide/waterborne polyurethane composites with controllable structure for high microwave absorption capacity[J].Carbon,2019,152:661-670.
[6] Kashani H,Giroux M,Johnson I,et al.Unprecedented electromagnetic interference shielding from Three-Dimensional Bi-continuous nanoporous graphene[J].Matter,2019,1(4):1077-1087.
[7] Faisal M,Khasim S.Broadband electromagnetic shielding and dielectric properties of polyaniline-stannous oxide composites[J].Journal of Materials Science:Materials in Electronics,2013,24(7):2202-2210.
[8] Gai L,Guo L,An Q,et al.Facile fabrication of SBA-15/polypyrrole composites with long-rod shape for enhanced electromagnetic wave absorption[J].Microporous and Mesoporous Materials,2019,288:109584.
[9] Ghosh S,Ganguly S,Remanan S,et al.Fabrication and investigation of 3D tuned PEG/PEDOT∶PSS treated conductive and durable cotton fabric for superior electrical conductivity and flexible electromagnetic interference shielding[J].Composites Science and Technology,2019,181:107682.1-107682.9.
[10] Yan S,Cao C,He J,et al.Investigation on the electromagnetic and broadband microwave absorption properties of Ti3C2 MXene/flaky carbonyl iron composites[J].Journal of Materials Science:Materials in Electronics,2019,30(7):6537-6543.
[11] Deng R,Chen B,Li H,et al.MXene/Co3O4 composite material:stable synthesis and its enhanced broadband microwave absorption[J].Applied Surface Science,2019,488:921-930.
[12] Liu P,Yao Z,Ng V M H,et al.Novel multilayer-like structure of Ti3C2Tx/CNZF composites for low-frequency electromagnetic absorption[J].Materials Letters,2019,248:214-217.
[13] Gargama H,Thakur A K,Chaturvedi S K.Polyvinylidene fluoride/nickel composite materials for charge storing,electromagnetic interference absorption,and shielding applications[J].Journal of Applied Physics,2015,117(22):224903.
[14] Gupta S,Sharma S K,Pradhan D,et al.Ultra-light 3D reduced graphene oxide aerogels decorated with cobalt ferrite and zinc oxide perform excellent electromagnetic interference shielding effectiveness[J].Composites Part A:Applied Science and Manufacturing,2019,123:232-241.
[15] Tan Y,Luo H,Zhou X,et al.Dependences of microstructure on electromagnetic interference shielding properties of nano-layered Ti3AlC2 ceramics[J].Scientific Reports,2018,8(1):7935.
[16] Tohidifar M R.Highly-efficient electromagnetic interference shielding and microwave dielectric behavior of a (Bi2O3+B2O3)-doped MWCNT/BaTiO3 ceramic nanocomposite[J].Ceramics International,2018,44(12):13613-13622.
[17] Mei H,Zhao X,Gui X,et al.SiC encapsulated Fe@CNT ultra-high absorptive shielding material for high temperature resistant EMI shielding[J].Ceramics International,2019,45(14):17144-17151.
[18] Li X,Yin X,Xu H,et al.Ultralight MXene-coated,interconnected SiCnws three-dimensional lamellar foams for efficient microwave absorption in the X-Band[J].ACS Applied Materials & Interfaces,2018,10(40):34524-34533.
[19] Wang H,Ma H.The electromagnetic and microwave absorbing properties of MoS2 modified Ti3C2Tx nanocomposites[J].Journal of Materials Science:Materials in Electronics,2019,30(16):15250-15256.
[20] Liu Y,Wu Y,Li K,et al.Amorphous SnS nanosheets/graphene oxide hybrid with efficient dielectric loss to improve the high-frequency electromagnetic wave absorption properties[J].Applied Surface Science,2019,486:344-353.
[21] Verger L,Natu V,Carey M,et al.MXenes:an introduction of their synthesis,select properties,and applications[J].Trends in Chemical Science,2019,1(7):656-669.
[22] Feng W L,Luo H,Wang Y,et al.Ti3C2 MXene:a promising microwave absorbing material[J].RSC Advances,2018,8(5):2398-2403.
[23] Li X L,Yin X W,Liang S,et al.2D carbide MXene Ti2CTx as a novel high-performance electromagnetic interference shielding material[J].Carbon,2019,146:210-217.
[24] Xu H L,Yin X W,Li X L,et al.Lightweight Ti2CTx MXene/Poly(vinyl alcohol) composite foams for electromagnetic wave shielding with absorption-dominated feature[J].ACS Applied Materials & Interfaces,2019,11(10):10198-10207.
[25] Shahzad F,Alhabeb M,Hatter C B,et al.Electromagnetic interference shielding with 2D transition metal carbides (MXenes)[J].Science,2016,353(6304):1137-1140.
[26] Vural M,Pena-francesch A,Bars-pomes J,et al.Inkjet printing of self-assembled 2D titanium carbide and protein electrodes for stimuli-responsive electromagnetic shielding[J].Advanced Functional Materials,2018,28(32):1801972.1-1801972.10.
[27] Liu P J,Chen S X,Yao M,et al.Double-layer absorbers based on hierarchical MXene composites for microwave absorption through optimal combination[J].Journal of Materials Research,2020,35(11):1481-1491.
[28] He P,Wang X X,Cai Y Z,et al.Tailoring Ti3C2Tx nanosheets to tune local conductive network as an environmentally friendly material for highly efficient electromagnetic interference shielding[J].Nanoscale,2019,11(13):6080-6088.
[29] Iqbal A,SAmbyal P,Koo C M.2D MXenes for electromagnetic shielding:a review[J].Advanced Functional Materials,2020,30(47):2000883.
[30] Cao M S,Cai Y Z,He P,et al.2D MXenes:electromagnetic property for microwave absorption and electromagnetic interference shielding[J].Chemical Engineering Journal,2019,359:1265-1302.
[31] Wang Z,Cheng Z,Fang C Q,et al.Recent advances in MXenes composites for electromagnetic interference shielding and microwave absorption[J].Composites Part A:Applied Science and Manufacturing,2020,136:105956.
[32] Alhabeb M,Maleski K,Anasori B,et al.Guidelines for synthesis and processing of two-dimensional titanium carbide (Ti3C2Tx MXene)[J].Chemistry of Materials,2017,29(18):7633-7644.
[33] Barsoum M W.MAX phases:properties of machinable ternary carbides and nitrides[M].US:Wiley-VCH,2013,436.
[34] Naguib M,Kurtoglu M,Presser V,et al.Two-dimensional nanocrystals produced by exfoliation of Ti3AlC2[J].Advanced Materials,2011,23(37):4248-4253.
[35] Naguib M,Mochalin V N,Barsoum M W,et al.25th anniversary article:MXenes:a new family of two-dimensional materials[J].Advanced Materials,2014,26(7):992-1005.
[36] Anasori B,Lukatskaya M R,Gogotsi Y.2D metal carbides and nitrides (MXenes) for energy storage[J].Nature Reviews Materials,2017,2:16098.
[37] Guo J,Legum B,Anasori B,et al.Cold sintered ceramic nanocomposites of 2D MXene and zinc oxide[J].Advanced Materials,2018,30(32):1801846.
[38] Kurtoglu M,Naguib M,Gogotsi Y,et al.First principles study of two-dimensional early transition metal carbides[J].MRS Communications,2012,2(4):133-137.
[39] Ghidiu M,Lukatskaya M R,Zhao M Q,et al.Conductive two-dimensional titanium carbide ‘clay’ with high volumetric capacitance[J].Nature,2014,516(7529):78-81.
[40] Zhang T,Pan L M,Tang H,et al.Synthesis of two-dimensional Ti3C2Tx MXene using HCl+LiF etchant:enhanced exfoliation and delamination[J].Journal of Alloys and Compounds,2017,695:818-826.
[41] Yang S,Zhang P P,Wang F X,et al.Fluoride-free synthesis of two-dimensional titanium carbide (MXene) using a binary aqueous system[J].Angewandte Chemie International Edition,2018,57(47):15491-15495.
[42] Cui G Z,Sun X D,Zhang G Y,et al.Electromagnetic absorption performance of two-dimensional MXene Ti3C2Tx exfoliated by HCl+LiF etchant with diverse etching times[J].Materials Letters,2019,252:8-10.
[43] Tong Y,He M,Zhou Y M,et al.Electromagnetic wave absorption properties in the centimetre-band of Ti3C2Tx MXenes with diverse etching time[J].Journal of Materials Science:Materials in Electronics,2018,29(10):8078-8088.
[44] Hu S J,Li S B,Xu W M,et al.Rapid preparation,thermal stability and electromagnetic interference shielding properties of two-dimensional Ti3C2 MXene[J].Ceramics International,2019,45(16):19902-19909.
[45] Xu G F,Wang X X,Gong S D,et al.Solvent-regulated preparation of well-intercalated Ti3C2Tx MXene nanosheets and application for highly effective electromagnetic wave absorption[J].Nanotechnology,2018,29(35):355201.
[46] Han M K,Yin X W,Wu H,et al.Ti3C2 MXenes with modified surface for high-performance electromagnetic absorption and shielding in the X-Band[J].ACS Applied Materials & Interfaces,2016,8(32):21011-21019.
[47] Han M K,Yin X W,Li X L,et al.Laminated and two-dimensional carbon-supported microwave absorbers derived from MXenes[J].ACS Applied Materials & Interfaces,2017,9(23):20038-20045.
[48] Yuan W J,Yang J Z,Yin F X,et al.Flexible and stretchable MXene/Polyurethane fabrics with delicate wrinkle structure design for effective electromagnetic interference shielding at a dynamic stretching process[J].Composites Communications,2020,19:90-98.
[49] Cao W T,Chen F F,Zhu Y J,et al.Binary strengthening and toughening of MXene/cellulose nanofiber composite paper with nacre-inspired structure and superior electromagnetic interference shielding properties[J].ACS Nano,2018,12(5):4583-4593.
[50] Liu J,Zhang H B,Sun R H,et al.Hydrophobic,flexible,and lightweight MXene foams for high-performance electromagnetic-interference shielding[J].Advanced Materials,2017,29(38):1702367.
[51] Jia X C,Shen B,Zhang L H,et al.Construction of compressible polymer/MXene composite foams for high-performance absorption-dominated electromagnetic shielding with ultra-low reflectivity[J].Carbon,2021,173:932-940.
[52] Sun R H,Zhang H B,Liu J,et al.Highly conductive transition metal carbide/carbonitride(MXene)@polystyrene nanocomposites fabricated by electrostatic assembly for highly rfficient electromagnetic interference shielding[J].Advanced Functional Materials,2017,27(45):1702807.
[53] Zhang X S,Wang X F,Lei Z W,et al.Flexible MXene-decorated fabric with interwoven conductive networks for integrated joule heating,electromagnetic interference shielding,and strain sensing performances[J].ACS Applied Materials & Interfaces,2020,12(12):14459-14467.
[54] Liang L Y,Han G J,Li Y,et al.A promising Ti3C2Tx MXene/Ni chain hybrid with excellent electromagnetic wave absorption and shielding capacity[J].ACS Applied Materials & Interfaces,2021,11(28):25399-25409.
[55] Pan F,Yu L Z,Xiang Z,et al.Improved synergistic effect for achieving ultrathin microwave absorber of 1D Co nanochains/2D carbide MXene nanocomposite[J].Carbon,2021,172:506-515.
[56] Deng B W,Wang L H,Xiang Z,et al.Rational construction of MXene/ferrite@C hybrids with improved impedance matching for high-performance electromagnetic absorption applications[J].Materials Letters,2021,284:129029.
[57] Liu P J,Yao Z J,Ng V M H,et al.Facile synthesis of ultrasmall Fe3O4 nanoparticles on MXenes for high microwave absorption performance[J].Composites Part A:Applied Science and Manufacturing,2018,115:371-382.
[58] Li X L,Yin X W,Song C Q,et al.Self-assembly core-shell graphene-bridged hollow MXenes spheres 3D foam with ultrahigh specific EM absorption performance[J].Advanced Functional Materials,2018,28(42):1803938.
[59] Qian Y,Wei H W,Dong J D,et al.Fabrication of urchin-like ZnO-MXene nanocomposites for high-performance electromagnetic absorption[J].Ceramics International,2017,43(14):10757-10762.
基金资助
吉林省科技厅青年成长科技计划项目(20220508026RC);吉林省发展和改革委员会项目(2022C040)