SrTiO3及其复合材料的制备与性能改进研究进展

张晨阳1, 祁浩杰2, 张玉萍3, 李超1, 张琴琴1, 陈晓飞2, 胡广志1,4, 李再兴1*

化工新型材料 ›› 2023, Vol. 51 ›› Issue (10) : 65 -72.

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化工新型材料 ›› 2023, Vol. 51 ›› Issue (10) : 65-72. DOI: 10.19817/j.cnki.issn1006-3536.2023.10.031
综述与专论

SrTiO3及其复合材料的制备与性能改进研究进展

    张晨阳1, 祁浩杰2, 张玉萍3, 李超1, 张琴琴1, 陈晓飞2, 胡广志1,4, 李再兴1*
作者信息 +

Review on preparation and performance improvement of SrTiO3 and its composites

  • Zhang Chenyang1, Qi Haojie2, Zhang Yuping3, Li Chao1, Zhang Qinqin1, Chen Xiaofei2, Hu Guangzhi1,4, Li Zaixing1
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摘要

具有众多优良性能的SrTiO3已经受到人们的广泛关注。钛酸锶光催化剂能够在光子的激发下生成强氧化性的羟基自由基和超氧离子自由基等,进而有效地降解废水中有机物。然而,SrTiO3作为光催化剂,具有对可见光利用率小、难回收等问题。针对此问题,分析了相关文献中关于制备和改善SrTiO3性能的方法,总结了复合高吸附性材料、复合半导体、掺杂元素、改善结构、建立特定制备方法和复合可回收材料对SrTiO3光催化剂的性能影响和改性方法,并对今后的研究发展方向提出展望。

Abstract

Strontium titanate (SrTiO3) has attracted extensive attention due to their numerous excellent properties.SrTiO3 photocatalyst can generate strong oxidizing hydroxyl radical and superoxide ion radicals under the excitation of photons,and then degrade organic matter in wastewater effectively.However,as a photocatalyst,SrTiO3 has low utilization rate of visible light and is difficult to recycle.Aiming at this problem,this paper analyzed the methods for the preparation and performance improvement of SrTiO3 performance in the related literature,summarized the effects of composite high adsorption materials,compound semiconductor,doping elements,structure improvement,establishment of specific preparation methods and composite recyclable materials on the properties of SrTiO3 light catalyst and the modification methods,and put forward prospects for the research directions in the future.

关键词

复合材料 / SrTiO3 / 改性 / 光催化剂

Key words

composite materials / SrTiO3 / modification / photocatalyst

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SrTiO3及其复合材料的制备与性能改进研究进展[J]. 化工新型材料, 2023, 51(10): 65-72 DOI:10.19817/j.cnki.issn1006-3536.2023.10.031

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参考文献

[1] Azough F,Gholinia A,Alvarez-Ruiz D T,et al.Self-nanostructuring in SrTiO3:a novel strategy for enhancement of thermoelectric response in oxides[J].ACS Applied Materials & Interfaces,2019,11(36):32833-32843.
[2] Christensen D V,Trier F,Niu W,et al.Stimulating oxide heterostructures:a review on controlling SrTiO3-based heterointerfaces with external stimuli[J].Advanced Materials Interfaces,2019,6(21):1900772.
[3] Wang S,Teramura K,Hisatomi T,et al.Effective driving of Ag-loaded and Al-doped SrTiO3 under irradiation at λ>300nm for the photocatalytic conversion of CO2 by H2O[J].ACS Applied Energy Materials,2020,3(2):1468-1475.
[4] Chiang T H,Lyu H,Hisatomi T,et al.Efficient photocatalytic water splitting using Al-doped SrTiO3 coloaded with molybdenum oxide and rhodium-chromium oxide[J].ACS Catalysis,2018,8(4):2782-2788.
[5] Matuszewska C,Elzbieciak-Piecka K,Marciniak L.Transition metal ion-based nanocrystalline luminescent thermometry in SrTiO3∶Ni2+,Er3+ nanocrystals operating in the second optical window of biological tissues[J].The Journal of Physical Chemistry C,2019,123(30):18646-18653.
[6] Yang X,Liu S,Li J,et al.Promotion effect of strong metal-support interaction to thermocatalytic,photocatalytic,and photothermocatalytic oxidation of toluene on Pt/SrTiO3[J].Chemosphere,2020,249:126096.
[7] Wardhana A C,Yamaguchi A,Shoji S,et al.Visible-light-driven photocatalysis via reductant-to-band charge transfer in Cr(Ⅲ) nanocluster-loaded SrTiO3 system[J].Applied Catalysis B:Environmental,2020,270:118883.
[8] Lim P F,Leong K H,Sim L C,et al.Mechanism insight of dual synergistic effects of plasmonic Pd-SrTiO3 for enhanced solar energy photocatalysis[J].Applied Physics A,2020,126(7):1-10.
[9] Gao H,Yang H,Wang S.Hydrothermal synthesis,growth mechanism,optical properties and photocatalytic activity of cubic SrTiO3 particles for the degradation of cationic and anionic dyes[J].Optik,2018,175:237-249.
[10] Sternlicht H,Rheinheimer W,Mehlmann A,et al.The mechanism of grain growth at general grain boundaries in SrTiO3[J].Scripta Materialia,2020,188:206-211.
[11] Saadetnejad D,Yıldırım R.Photocatalytic hydrogen production by water splitting over Au/Al-SrTiO3[J].International Journal of Hydrogen Energy,2018,43(2):1116-1122.
[12] Mehra S,Bishnoi S,Goswami L,et al.Detailed chemical mechanism of the phase transition in nano-SrTiO3 perovskite with visible luminescence[J].Inorganic Chemistry Communications,2020,120:108125.
[13] Zhang Y,Li Y,Yuan Y,et al.C-dots decorated SrTiO3/NH4V4O10 Z-scheme heterojunction for sustainable antibiotics removal:reaction kinetics,DFT calculation and mechanism insight[J].Separation and Purification Technology,2022:121268.
[14] Wang T X,Chen W W.Solid phase preparation of submicron-sized SrTiO3 crystallites from SrO2 nanoparticles and TiO2 powders[J].Materials Letters,2008,62(17-18):2865-2867.
[15] 饶雨晨,李靖,陈艳,等.SrTiO3纳米粉的低温固相合成和光催化性质[J].中国陶瓷,2015,51(1):32-35.
[16] Nunocha P,Kaewpanha M,Bongkarn T,et al.A new route to synthesizing La-doped SrTiO3 nanoparticles using the sol-gel auto combustion method and their characterization and photocatalytic application[J].Materials Science in Semiconductor Processing,2021,134:106001.
[17] Li J,Tang X G,Liu Q X,et al.Interfacial resistive switching properties of Sr2TiO4/SrTiO3 heterojunction thin films prepared via sol-gel process[J].Ceramics International,2021,47(13):18808-18813.
[18] 谭冲,左丹烨,李俊生,等.W-Ag共掺杂SrTiO3的制备及其光催化性能[J].环境化学,2021,40(10):3217-3225.
[19] Wang L,Wang Z,Wang D,et al.The photocatalysis and mechanism of new SrTiO3/TiO2[J].Solid State Sciences,2014,31:85-90.
[20] Jiang D,Sun X,Wu X,et al.Hydrothermal synthesis of single-crystal Cr-doped SrTiO3 for efficient visible-light responsive photocatalytic hydrogen evolution[J].Materials Research Express,2020,7(1):015047.
[21] Wu Y,Dong B,Zhang J,et al.The synthesis of ZnO/SrTiO3 composite for high-efficiency photocatalytic hydrogen and electricity conversion[J].international Journal of Hydrogen Energy,2018,43(28):12627-12636.
[22] Chen X,Qi H,Zhang C,et al.Synthesis and characterization of recyclable PVA/SrTiO3/Ag2O composite with photocatalytic degradation performance of methylene blue[J].Applied Physics A,2022,128(5):1-9.
[23] 路红霞,景慧,张玲玲,等.钛酸锶粉体的共沉淀法制备研究[J].湖南有色金属,2017,33(6):49-51,80.
[24] Ren H,Ge L,Guo Q,et al.The enhancement of photocatalytic performance of SrTiO3 nanoparticles via combining with carbon quantum dots[J].RSC Advances,2018,8(36):20157-20165.
[25] Wei X,Xu G,Ren Z,et al.PVA-assisted hydrothermal synthesis of SrTiO3 nanoparticles with enhanced photocatalytic activity for degradation of RhB[J].Journal of the American Ceramic Society,2008,91(11):3795-3799.
[26] Sultanov F,Daulbayev C,Azat S,et al.Influence of metal oxide particles on bandgap of 1D photocatalysts based on SrTiO3/PAN fibers[J].Nanomaterials,2020,10(9):1734.
[27] Piao C,Lin Y,Liu Z,et al.Fabrication of Z-scheme CuPd/SrTiO3-CuPd-Bi2O3 photocatalyst for converting organic dye containing N and S elements into (NH4)2SO4[J].Journal of Environmental Chemical Engineering,2021,9(4):105537.
[28] 李立石,郭洁,王博,等.TiO2/SrTiO3微球的制备及其光催化性能[J].山东化工,2021,50(19):17-18,20.
[29] Cui Y,Sun H,Guo P.Highly efficient SrTiO3/Ag2O np heterojunction photocatalysts:improved charge carrier separation and enhanced visible-light harvesting[J].Nanotechnology,2020,31(24):245702.
[30] Atkinson I,Parvulescu V,Cusu J P,et al.Influence of preparation method and nitrogen(N) doping on properties and photo-catalytic activity of mesoporous SrTiO3[J].Journal of Photochemistry and Photobiology A:Chemistry,2019,368:41-51.
[31] Ren L,Yi X,Tong L,et al.Nitrogen-doped ultrathin graphene encapsulated Cu nanoparticles decorated on SrTiO3 as an efficient water oxidation photocatalyst with activity comparable to BiVO4 under visible-light irradiation[J].Applied Catalysis B:Environmental,2020,279:119352.
[32] Hong S S.Synthesis of lead-doped SrTiO3 perovskite type oxides and their photocatalytic activity under visible light irradiation[J].Journal of Nanoscience and Nanotechnology,2019,19(2):1204-1207.
[33] Vento-Lujano E,González L A.Defect-induced modification of band structure by the insertion of Ce3+ and Ce4+ in SrTiO3:a high-performance sunlight-driven photocatalyst[J].Applied Surface Science,2021,569:151044.
[34] 廖锡龙,毛田田,杨云龙,等.La掺杂对SrTiO3纳米颗粒光催化性能的影响[J].武汉科技大学学报(自然科学版),2018,41(5):365-369.
[35] Lee J T,Wey M Y.PVA/Pt/N-TiO2/SrTiO3 porous films with adjustable pore size for hydrogen production under simulated sunlight[J].Journal of Colloid and Interface Science,2020,573:158-164.
[36] Guo M,Liu Q,Wu M,et al.Novel reduced graphene oxide wrapped-SrTiO3 flower-like nanostructure with Ti-C bond for free noble metal decomposition of formic acid to hydrogen[J].Chemical Engineering Journal,2018,334:1886-1896.
[37] 李雨遥,李治,王云芸,等.氮掺杂SrTiO3/TiO2纳米棒异质结的制备及光催化活性[J].功能材料,2020,51(1):1189-1195.
[38] Luo C,Zhao J,Li Y,et al.Photocatalytic CO2 reduction over SrTiO3:correlation between surface structure and activity[J].Applied Surface Science,2018,447:627-635.
[39] Xia Y,He Z,Su J,et al.Fabrication of novel n-SrTiO3/p-BiOI heterojunction for degradation of crystal violet under simulated solar light irradiation[J].Nano,2018,13(06):1850070.
[40] He C,Bu X,Yang S,et al.Core-shell SrTiO3/graphene structure by chemical vapor deposition for enhanced photocatalytic performance[J].Applied Surface Science,2018,436:373-381.
[41] Lin Y C,Wang D K,Liu J Y,et al.Low band-gap energy photocatalytic membrane based on SrTiO3-Cr and PVDF substrate:BSA protein degradation and separation application[J].Journal of Membrane Science,2019,586:326-337.
[42] Chen P Y,Lam C H,Edmondson B,et al.Epitaxial BaSnO3 and SrSnO3 perovskite growth on SrTiO3(001) via atomic layer deposition[J].Journal of Vacuum Science & Technology A:Vacuum,Surfaces,and Films,2019,37(5):050902.
[43] Bai Z,Zhu Z,Wang G,et al.Fast response and high sensitive photoelectrochemical ultraviolet detectors based on electrospinning SrTiO3 nanowires[J].Applied Physics A,2022,128(5):414.
[44] Yue X,Zhang J,Yan F,et al.A situ hydrothermal synthesis of SrTiO3/TiO2 heterostructure nanosheets with exposed (0 0 1) facets for enhancing photocatalytic degradation activity[J].Applied Surface Science,2014,319:68-74.
[45] Zhou M,Chen J,Jiang M,et al.Efficient anchoring of SrTiO3 on the cracked surface of carbonized bacterial cellulose for enhanced photocatalytic activities[J].Cellulose,2020,27:7023-7036.
[46] Wen X J,Niu C G,Zhang L,et al.An in depth mechanism insight of the degradation of multiple refractory pollutants via a novel SrTiO3/BiOI heterojunction photocatalysts[J].Journal of Catalysis,2017,356:283-299.
[47] Kumar A,Sharma S K,Kumar A,et al.High interfacial charge carrier separation in Fe3O4 modified SrTiO3/Bi4O5I2 robust magnetic nano-heterojunction for rapid photodegradation of diclofenac under simulated solar-light[J].Journal of Cleaner Production,2021,315:128137.
[48] Bantawal H,Shenoy U S,Bhat D K.Vanadium-doped SrTiO3 nanocubes:insight into role of vanadium in improving the photocatalytic activity[J].Applied Surface Science,2020,513:145858.
[49] Luo Y,Deng B,Pu Y,et al.Interfacial coupling effects in g-C3N4/SrTiO3 nanocomposites with enhanced H2 evolution under visible light irradiation[J].Applied Catalysis B:Environmental,2019,247:1-9.
[50] Hsieh P L,Naresh G,Huang Y S,et al.Shape-tunable SrTiO3 crystals revealing facet-dependent optical and photocatalytic properties[J].The Journal of Physical Chemistry C,2019,123(22):13664-13671.
[51] Yahya M S,Ismail M.Catalytic effect of SrTiO3 on the hydrogen storage behaviour of MgH2[J].Journal of Energy Chemistry,2019,28:46-53.
[52] Zhao Y,Guo Y,Li J,et al.Efficient hydrogen evolution with ZnO/SrTiO3 S-scheme heterojunction photocatalyst sensitized by Eosin Y[J].International Journal of Hydrogen Energy,2021,46(36):18922-18935.
[53] Han J,Dai F,Liu Y,et al.Synthesis of CdSe/SrTiO3 nanocomposites with enhanced photocatalytic hydrogen production activity[J].Applied Surface Science,2019,467:1033-1039.
[54] Jin S,Dong G,Luo J,et al.Improved photocatalytic NO removal activity of SrTiO3 by using SrCO3 as a new co-catalyst[J].Applied Catalysis B:Environmental,2018,227:24-34.
[55] Liu Y,Xu X,Zheng S,et al.Ni single atoms anchored on nitrogen-doped graphene as H2-evolution cocatalyst of SrTiO3 (Al)/CoOx for photocatalytic overall water splitting[J].Carbon,2021,183:763-773.
[56] Lin H,Cian L T.Microwave-assisted hydrothermal synthesis of SrTiO3∶Rh for photocatalytic Z-scheme overall water splitting[J].Applied Sciences,2018,9(1):55.
[57] Song S,Xu L,He Z,et al.Photocatalytic degradation of CI Direct Red 23 in aqueous solutions under UV irradiation using SrTiO3/CeO2 composite as the catalyst[J].Journal of Hazardous Materials,2008,152(3):1301-1308.
[58] 张其娣,何洁丽,保明娥,严亚.Bi掺杂的SrTiO3的制备及其可见光催化活性研究[J].大理大学学报,2017,2(12):59-62.
[59] Abdi M,Mahdikhah V,Sheibani S.Visible light photocatalytic performance of La-Fe co-doped SrTiO3 perovskite powder[J].Optical Materials,2020,102:109803.
[60] Ahmadi M,Dorraji M S S,Rasoulifard M H,et al.The effective role of reduced-graphene oxide in visible light photocatalytic activity of wide band gap SrTiO3 semiconductor[J].Separation and Purification Technology,2019,228:115771.
[61] Xia Y,He Z,Su J,et al.Fabrication and photocatalytic property of novel SrTiO3/Bi5O7I nanocomposites[J].Nanoscale Research Letters,2018,13(1):1-9.
[62] Han K,Li W,Ren C,et al.Dye-sensitized SrTiO3-based photocatalysts for highly efficient photocatalytic hydrogen evolution under visible light[J].Journal of the Taiwan Institute of Chemical Engineers,2020,112:4-14.

基金资助

石家庄市科学技术研究与发展计划项目(211240043A,191240263A)

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