采用基于波导法的电磁参数测试系统测试了纳米碳纤维(CNFs)掺量为水泥质量0、0.05%、0.10%、0.15%、0.20%的CNFs增强水泥基材料在1.7~2.6GHz频率范围内的介电常数,通过分析介电常数实部(ε′)、介电常数虚部(ε″)和介电损耗角正切(tanδe),研究了CNFs对水泥基材料介电损耗性能的影响。结果表明:随着CNFs掺量的增加,水泥基材料的ε′、ε″和tanδe不断增大,极化能力和介电损耗能力不断增强,介电损耗性能不断提高。CNFs的掺增加了杂水泥基材料中的纤维相,且纤维相的介电常数更大,故水泥基材料的介电常数增大。
The dielectric constants of carbon nanofiber (CNFs) reinforced cement-based materials with CNFs content of 0,0.05%,0.10%,0.15% and 0.20% were measured in the frequency range of 1.7~2.6GHz by electromagnetic parameter testing system based on waveguide method.The effects of CNFs on the dielectric loss performance of cement-based materials were studied by analyzing the real part of dielectric constant (ε′),the imaginary part of dielectric constant (ε″) and the dielectric loss tangent (tanδe).The results showed that the ε′,ε″ and tanδe of cement-based materials increased with the increase of CNFs content,and the polarization ability and dielectric loss ability of cement-based materials increased continuously.The addition of CNFs increased the fiber phase in cement-based materials,and the dielectric constant of fiber phase was larger,so the dielectric constant of cement-based materials increased.
[1] 田义宗.电磁辐射污染对环境和人体健康的影响建模研究[J].环境科学与管理,2021,46(11):137-140;166.
[2] 杨凌峰.电磁功能化碳纳米纤维的制备及其复合材料吸波性能研究[D].武汉:武汉理工大学,2018.
[3] 张晓笑.纳米碳纤维表面改性及其吸波性能研究[D].武汉:武汉理工大学,2020.
[4] 王志航,许金余,吴云泉,等.纳米碳纤维增强混凝土的介电特性[J].土木与环境工程学报(中英文),2022,44(1):134-141.
[5] Xia Wei,Xu Jinyu,Nie Liangxue.Research on the mechanical performance of carbon nanofiber reinforced concrete under impact load based on fractal theory[J].Crystals,2021,11(4):387.
[6] 高迪,彭立敏.纳米碳纤维混凝土力学性能的试验研究[J].铁道科学与工程学报,2011,8(3):18-24.
[7] Wang Tengjiao,Xu Jinyu,Meng Boxu,et al.Experimental study on the effect of carbon nanofiber content on the durability of concrete[J].Construction and Building Materials,2020,250:118891.
[8] 孟博旭,许金余,彭光.纳米碳纤维增强混凝土抗冻性能试验[J].复合材料学报,2019,36(10):2458-2468.
[9] 高迪,彭立敏,莫诒隆.纳米碳纤维自密实混凝土的电阻特性[J].四川大学学报(工程科学版),2011,43(5):52-58.
[10] 汪晖.环境条件对纳米碳纤维水泥基材料压阻性能的影响[D].哈尔滨:哈尔滨工业大学,2017.
[11] Gao Di,Mariel Sturm,Mo Y L.Electrical resistance of carbon-nanofiber concrete[J].Smart Materials and Structures,2011,20(4):049501.
[12] Wang Zhihang,Xu Jinyu,Bai Erlei,et al.Dielectric model of carbon nanofiber reinforced concrete[J].Materials,2020,13(21):4869.
[13] 孟美丽,王复明,高海彬.水泥混凝土介电模型研究[J].硅酸盐通报,2015,34(10):2797-2802.
[14] Brown W F.Dielectrics in encyclopedia of physics[M].Berlin:Springer,1956:15-16.
[15] 孟美丽,孟雄号.温度和频率对水泥混凝土介电模型的影响[J].硅酸盐通报,2018,37(5):1758-1764.
[16] Anatolij Shutko M,Reutov E M.Mixture formulas applied in estimation of dielectric and radiative characteristics of soils and grounds at microwave frequencies[J].IEEE Transactions on Geoscience and Remote Sensing,1982,20(1):11-13.
基金资助
国家自然科学基金(52278287,51908548);国家人民防空办公室立项课题(RF20SC01J-S0);陕西省高校科协青年人才托举计划项目(20200415)