金属有机骨架(MOFs)材料因比表面积大、孔隙率高、结构可调及生物相容性好等诸多优势而具有广阔的应用前景。银纳米粒子(Ag NPs)具有优异的抗菌、催化及光电性能,但在合成过程中易发生团聚而导致性能降低。MOFs丰富的孔隙结构能够起到分散和固定Ag NPs的作用,MOFs材料可与Ag NPs协同作用,从而提高和拓宽银负载金属有机骨架(Ag@MOFs)复合材料的性能和应用领域。归纳了不同种类及形貌的Ag@MOFs复合材料,综述了Ag@MOFs复合材料的合成方法以及在抗菌、催化及传感检测领域中的研究进展,指出了该复合材料面临的挑战并展望了其未来发展前景。
Metal-organic frameworks (MOFs) have broad application prospects due to their large surface area,high porosity,adjustable structure and good biocompatibility.Silver nanoparticles (Ag NPs) have excellent antibacterial,catalytic and photoelectric properties,but they are prone to agglomeration in the synthesis process,resulting in degradation of performance.The rich pore structure of MOFs can play a role in dispersing and fixing Ag NPs.MOFs materials can form a synergistic effect with Ag NPs,thereby improving and broadening the performance and application fields of Ag@MOFs composites.Ag@MOFs composites with different types and morphologies were summarized,and the synthesis methods of Ag@MOFs composites were further reviewed.The latest research progress and prospects of Ag@MOFs composites in the fields of antibacterial,catalytic and sensing detection were discussed.
[1] Kaur N,Tiwari P,Kapoor K S,et al.Metal-organic framework based antibiotic release and antimicrobial response:an overview[J].Cryst Eng Comm,2020,22(44):7513-7527.
[2] 蔡华敏,贾冬梅,张大鹏,等.MOFs及其复合材料去除水中重金属研究进展[J].化工新型材料,2022,50(1):82-88.
[3] Lv M,Zhou W,Tavakoli H,et al.Aptamer-functionalized metal-organic frameworks (MOFs) for biosensing[J].Biosensors & Bioelectronics,2020,176:112947.
[4] Meng C Q,Cao Y,Luo Y L,et al.A Ni-MOF nanosheet array for efficient oxygen evolution electrocatalysis in alkaline media[J].Inorganic Chemistry Frontiers,2021,8(12):3007-3011.
[5] Wei Q,Wu Y H,Liu F F,et al.Advances in antitumor nanomedicine based on functional metal-organic frameworks beyond drug carriers[J].Journal of Materials Chemistry B,2022,10(5):676-699.
[6] Xu G W,Wu Y P,Dong W W,et al.A multifunctional Tb-MOF for highly discriminative sensing of Eu3+/Dy3+ and as a catalyst support of Ag nanoparticles[J].Small,2017,13:1602996.
[7] Bin Q,Wang M,Wang L.Ag nanoparticles decorated into metal-organic framework (Ag NPs/ZIF-8) for electrochemical sensing of chloride ion[J].Nanotechnology,2020,31:125601.
[8] Samadi-Maybodi A,Ghasemi S,Ghaffari-Rad H.A novel sensor based on Ag-loaded zeolitic imidazolate framework-8 nanocrystals for efficient electrocatalytic oxidation and trace level detection of hydrazine[J].Sensors and Actuators B:Chemical,2015,220:627-633.
[9] Meng X,Duan C,Zhang Y L,et al.Corncob-supported Ag NPs@ZIF-8 nanohybrids as multifunction biosorbents for wastewater remediation:robust adsorption,catalysis and antibacterial activity[J].Composites Science and Technology,2020,200:108384.
[10] Jiang P Y,Yu K F,Yuan H B,et al.Encapsulating Ag nano-particles into ZIF-8 as an efficient strategy to boost uranium photoreduction without sacrificial agents[J].Journal of Materials Chemistry A,2021,9(15):9809-9814.
[11] Hu Y C,Yang H,Wang R H,et al.Fabricating Ag@MOF-5 nanoplates by the template of MOF-5 and evaluating its antibacterial activity[J].Colloids and Surfaces A:Physicochemical and Engineering Aspects,2021,626:127093.
[12] Qi Y,Ye J W,Ren S S,et al.In-situ synthesis of metal nano-particles@metal-organic frameworks:highly effective catalytic performance and synergistic antimicrobial activity[J].Journal of Hazardous Materials,2020,387:121687.
[13] Yadav D K,Ganesan V,Marken F,et al.Metal@MOF materials in electroanalysis:silver-enhanced oxidation reactivity towards nitrophenols adsorbed into a zinc metal organic framework—Ag@MOF-5(Zn)[J].Electrochimica Acta,2016,219:482-491.
[14] Li Y Q,Gao Q,Zhou Y S,et al.Significant enhancement in hydrolytic degradation of sulfur mustard promoted by silver nanoparticles in the Ag NPs@HKUST-1 composites[J].Journal of Hazardous Materials,2018,358:113-121.
[15] Duan C,Meng J R,Wang X Q,et al.Synthesis of novel cellulose-based antibacterial composites of Ag nanoparticles@metal-organic frameworks@carboxymethylated fibers[J].Carbohydrate Polymers,2018,193:82-88.
[16] Peng Z W,Jiang Z W,Huang X,et al.A novel electrochemical sensor of tryptophan based on silver nanoparticles/metal-organic framework composite modified glassy carbon electrode[J].RSC Advances,2016,6(17):13742-13748.
[17] Jiang Z W,Gao P F,Yang L,et al.Facile in situ synthesis of silver nanoparticles on the surface of meta-organic framework for ultrasensitive surface-enhanced raman scattering detection of dopamine[J].Analytical Chemistry,2015,87(24):12177-12182.
[18] Duan C,Liu C R,Meng X,et al.Facile synthesis of Ag NPs@MIL-100(Fe)/guar gum hybrid hydrogel as a versatile photocatalyst for wastewater remediation:photocatalytic degradation,water/oil separation and bacterial inactivation[J].Carbohydrate Polymers,2020,230:115642.
[19] Zhang Y,Sun P P,Zhang L,et al.Silver-infused porphyrinic metal-organic framework:surface-adaptive,on-demand nanoplatform for synergistic bacteria killing and wound disinfection[J].Advanced Functional Materials,2019,29(11):1808594.
[20] Liu J,Strachan D M,Thallapally P K.Enhanced noble gas adsorption in Ag@MOF-74Ni[J].Chemical Communications,2014,50(4):466-468.
[21] Mao K L,Zhu Y,Rong J,et al.Rugby-ball like Ag modified zirconium porphyrin metal-organic frameworks nanohybrid for antimicrobial activity:synergistic effect for significantly enhancing photoactivation capacity[J].Colloids and Surfaces A:Physicochemical and Engineering Aspects,2021,611:125888.
[22] Shi J L,Zhang L N,Sun N N,et al.Facile and rapid preparation of Ag@ZIF-8 for carboxylation of terminal alkynes with CO2 in mild conditions[J].ACS Applied Materials & Interfaces,2019,11(32):28858-28867.
[23] Ren X H,Jin M,Feng X X,et al.Self-assembled zeolitic imidazolate framework-8/Ag nanoparticles composite with well-controlled flower-like architectures for ultrasensitive surface-enhanced Raman scattering detection[J].Applied Surface Science,2021,537:147853.
[24] Li Q Q,Gong S S,Zhang H,et al.Tailored necklace-like Ag@ZIF-8 core/shell heterostructure nanowires for high-perfor-mance plasmonic SERS detection[J].Chemical Engineering Journal,2019,371:26-33.
[25] Liu X,He L C,Zheng J Z,et al.Solar-light-driven renewable butanol separation by core-shell Ag@ZIF-8 nanowire[J].Advanced Material,2015,27(21):3273-3277.
[26] Li D,Cao X K,Zhang Q M,et al.Facile in situ synthesis of core-shell MOF@Ag nanoparticle composites on screen-printed electrodes for ultrasensitive SERS detection of polycyclic aromatic hydrocarbons[J].Journal of Materials Chemistry A,2019,7(23):14108-14117.
[27] Aijaz A,Karkamkar A,Choi Y J,et al.Immobilizing highly catalytically active Pt nanoparticles inside the pores of metal-organic framework:a double solvents approach[J].Journal of the American Chemical Society,2012,134(34):13926-13929.
[28] Chen W J,Cheng B H,Sun Q T,et al.Preparation of MOF confined Ag nanoparticles for the highly active,size selective hydrogenation of olefins[J].ChemCatChem,2018,10(17):3659-3665.
[29] Zhao M T,Yuan K,Wang Y,et al.Metal-organic frameworks as selectivity regulators for hydrogenation reactions[J].Nature,2016,539(7627):76-80.
[30] Abd El Salam H M,Nassar H N,Khidr A S A,et al.Antimicrobial activities of green synthesized Ag nanoparticles Ni-MOF nanosheets[J].Journal of Inorganic and Organometallic Polymers and Materials,2018,28(6):2791-2798.
[31] Sohrabnezhad S,Pourahmad A,Salahshoor M.Matrices based on meso antibacterial framework[J].Journal of the Chinese Chemical Society,2020,67(9):1579-1590.
[32] Guo Y F,Fang W J,Fu J R,et al.Facile synthesis of Ag@ZIF-8 core-shell heterostructure nanowires for improved antibacterial activities[J].Applied Surface Science,2018,435:149-155.
[33] Li Y J,Gao Z G,Zhang Y,et al.MOF-shielded and glucose-responsive ultrasmall silver nano-factory for highly-efficient anticancer and antibacterial therapy[J].Chemical Engineering Journal,2021,416:127610.
[34] Shakya S,He Y P,Ren X H,et al.Ultrafine silver nanoparticles embedded in cyclodextrin metal-organic frameworks with GRGDS functionalization to promote antibacterial and wound healing application[J].Small,2019,15(27):1901065.
[35] Guo X M,Guo B,Wang Y L,et al.Preparation of spherical metal-organic frameworks encapsulating Ag nanoparticles and study on its antibacterial activity[J].Materials Science and Engineering:C,2017,80:698-707.
[36] Deng X,Yang L L,Huang H L,et al.Shape-defined hollow structural Co-MOF-74 and metal nanoparticles@Co-MOF-74 composite through a transformation strategy for enhanced photocatalysis performance[J].Small,2019,15(35):1902287.
[37] Qiu J L,Su J,Muhammad N,et al.Facile encapsulating Ag nanoparticles into a tetrathiafulvalene-based Zr-MOF for enhanced photocatalysis[J].Chemical Engineering Journal,2022,427:131970.
[38] Zhang W Z,Jiang T,Sun X X,et al.Determination of peracetic acid by an Ag nanoparticle decorated Cu-organic framework modified electrode[J].Microchemical Journal,2021,171:106856.
[39] Ma L W,Wu H,Huang Y,et al.High-performance real-time SERS detection with recyclable Ag nanorods@HfO2 substrates[J].ACS Applied Materials & Interfaces,2016,8(40):27162-27168.
[40] 万超,康雪婷,金腾,等.双金属沸石咪唑酸酯骨架基混合基质膜的制备及CO2/N2分离性能研究[J].化工新型材料,2022,50(3):89-93.
[41] Zhuang P F,Zhang P,Li K,et al.Silver nanoclusters encapsulated into metal-organic frameworks for rapid removal of heavy metal ions from water[J].Molecules,2019,24:2442.
基金资助
江苏省重点研发计划-社会发展(BE2020709)