季铵化卤胺改性氧化石墨烯纳米复合材料的制备及抗菌性能研究

肖凌寒, 颜振, 冀晨曦, 卜聃琳

化工新型材料 ›› 2023, Vol. 51 ›› Issue (8) : 245 -249.

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化工新型材料 ›› 2023, Vol. 51 ›› Issue (8) : 245-249. DOI: 10.19817/j.cnki.issn1006-3536.2023.08.046
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季铵化卤胺改性氧化石墨烯纳米复合材料的制备及抗菌性能研究

    肖凌寒, 颜振, 冀晨曦, 卜聃琳
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Preparation and antibacterial properties of quaternary ammonium halide modified graphene oxide nanocomposites

  • Xiao Linghan, Yan Zhen, Ji Chenxi, Pu Danlin
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摘要

近年来, 细菌和病毒的爆发频频导致大型传染病事件, 严重阻碍了人类社会的进步和发展。抗菌纳米复合材料由于其优异的抗菌性能成为研究的热点。然而, 单一抗菌材料有诸多缺点, 如单一杀菌机制杀菌效率低, 以及材料循环性差等一系列原因。因此, 多种抗菌材料协同杀菌增强杀菌效果的研究愈发重要。制备了一种多接枝的氧化石墨烯纳米抗菌复合材料-季铵化卤胺改性氧化石墨烯(GO-VPBHD)。由于多种杀菌作用协同, 该材料与未接枝前的GO和单一接枝的4-乙烯基吡啶改性氧化石墨烯(GO-VP)有着更好的杀菌效果。对金黄色葡萄球菌和大肠杆菌10min杀灭效率在99%以上。同时, 该材料在多次循环和长时间储存后, 依旧表现出优异的杀菌性能。

Abstract

In recent years, outbreaks of bacteria and viruses have frequently led to major infectious disease events, seriously hindering the progress and development of human society.Antibacterial nanocomposites have become a hot topic of research due to their excellent antibacterial properties.However, single antimicrobial materials have many disadvantages, such as low bactericidal efficiency of a single bactericidal mechanism and poor material recyclability for a range of reasons.Therefore, it is increasingly important to investigate the synergistic bactericidal effect of multiple antimicrobial materials to enhance the bactericidal effect.In this paper, a multi-grafted graphene oxide nanocomposite, quaternised graphene oxide modified with haloamine (GO-VPBHD), was prepared.Due to the synergistic effect of multiple grafting, this material had better bactericidal effect than the ungrafted GO and the single grafted 4-vinylpyridine-modified graphene oxide (GO-VP).The killing efficiency for Staphylococcus aureus and Escherichia coli was over 99% in 10 min.The material also exhibited excellent bactericidal performance after multiple cycles and long storage periods.

关键词

氧化石墨烯 / 卤胺化合物 / 协同抗菌

Key words

graphene oxide / haloamine compound / synergistic antibacterial

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季铵化卤胺改性氧化石墨烯纳米复合材料的制备及抗菌性能研究[J]. 化工新型材料, 2023, 51(8): 245-249 DOI:10.19817/j.cnki.issn1006-3536.2023.08.046

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基金资助

吉林省科学技术厅科技项目(20210506039ZP);吉林省教育厅科技项目(JJKH20210758KJ)

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