石墨烯量子点是一种新型碳纳米材料, 具有独特的物理、化学及生物特性。采用五步法:以石墨为原料, 利用Hummers法制备氧化石墨烯;采用化学法以水合肼还原制得石墨烯;再用浓硫酸与浓硝酸的混酸体系预氧化裁剪;进行水热二次剪裁;最后透析纯化, 即得到石墨烯量子点。采用紫外可见分光光度计、扫描电子显微镜、荧光分光光度计等对石墨烯量子点的尺寸、形貌、光学性能进行表征。实验结果表明, 所制备的石墨烯量子点具有较好的荧光性能, 在不同的激发波长下具有强吸收特征, 并呈现强度类似的荧光响应值。
Graphene quantum dots (GQDS) are a new type of carbon nanomaterial with unique physical, chemical and biological peculiarities.In here, GQDS were prepared in five steps: graphene oxide was prepared by Hummer method with graphite as raw material;graphene was prepared by the reduction of graphene oxide by hydrazine hydrate;pre-oxidation to clip graphene by the mixture of concentrated sulfuric acid and nitric acid;secondary hydrothermal treatment to further clip;and dialysis and purification to obtain the final produce GQDS.Ultraviolet-visible spectrophotometer, scanning electron microscope and fluorescence spectrophotometer were used to characterize the size, morphology and optical properties of graphene quantum dots.Ultraviolet-visible spectrophotometer, scanning electron microscope and fluorescence spectrophotometer were employed to characterize the size, morphology and optical properties of GQDS.The results indicated that the prepared GQDS had good fluorescence properties, and displayed strong absorption present with similar fluorescence response intensity at different excitation wavelengths.
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基金资助
陕西省自然科学科技计划项目(2022JM-075);西安市科技局计划(22GXFW0112);国家自然科学基金(21445004、21545014、21643014);陕西省创新能力支撑计划(2018KJXX-090);陕西省教育厅重点实验室访问学者项目(14JS095);西安文理学院博士启动基金(06005017);陕西省分析化学重点学科资助(09009001);陕西高校青年创新团队(环境污染监测与治理创新团队51#)
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