通过现有文献的研究总结了生物质基的制备方法, 主要通过物理改性方法制备出生物质基三维多孔碳载体、生物质气凝胶等封装相变材料防止泄露;通过高分子聚合、静电纺丝等化学制备法实现对相变材料的封装。针对复合相变材料导热性能差提出多孔材料吸附、微胶囊化、添加导热材料等方法以提高导热性能。对比了以无机多孔材料为载体和以生物质多孔基为载体的不同复合材料的导热系数, 分析两种载体的优缺点。同时指出多元混合相变材料与生物质微胶囊化的研究方向, 且目前在生物质基的基础上添加高导热材料的研究相对较少, 对此不足之处进行探究, 在未来可以制备出性能更佳的复合材料应用于更多领域。
This paper summarized the preparation methods of biomass based materials through the research of existing literature.Biomass based three-dimensional porous carbon carriers were mainly prepared by physical modification.Encapsulation of phase change materials such as biomass aerogels to prevent leakage was also obtained.The packaging of phase change materials was realized by chemical preparation methods such as polymer polymerization and electrospinning.Aiming at the poor thermal conductivity of composite phase change materials, porous material adsorption, microencapsulation and adding thermal conductive materials were proposed to improve the thermal conductivity.The thermal conductivity of different composites with inorganic porous materials as carrier and biomass porous matrix as carrier were compared.The advantages and disadvantages of the two carriers were analyzed.At the same time, the research direction of multicomponent mixed phase change materials and biomass microencapsulation was pointed out.At present, there are relatively few studies on adding high thermal conductivity materials on the basis of biomass, and this deficiency needs to be further explored so that composites with better performance can be prepared and applied in more fields in the future.
[1] Wu Y,Wang T.Hydrated salts/expanded graphite composite with high thermal conductivity as a shape-stabilized phase change material for thermal energy storage[J].Energy Conversion & Management,2015,101:164-171.
[2] Lee S Y,Shin H K,Park M,et al.Thermal characterization of erythritol/expanded graphite composites for high thermal storage capacity[J].Carbon,2014,68:67-72.
[3] 付弯弯.新型无机水合盐定形复合相变材料的制备及性能[D].广州:华南理工大学,2019.
[4] Ipollone R,Bianchi G,Di Battista D,et al.Experimental and numerical analyses on a plate heat exchanger with phase change for waste heat recovery at off-design conditions[J].Journal of Physics Conference,2015,655:012038.
[5] Wang S,Peng Q,Fang X,et al.A novel sebacic acid/expanded graphite composite phase change material for solar thermal medium-temperature applications[J].Solar Energy,2014,99:283-290.
[6] Chen J,Ling Z,Fang X,et al.Experimental and numerical investigation of form-stable dodecane/hydrophobic fumed silica composite phase change materials for cold energy storage[J].Energy Conversion and Management,2015,105:817-825.
[7] Jin J,Liu L,Liu R,et al.Preparation and thermal performance of binary fatty acid with diatomite as form-stable composite phase change material for cooling asphalt pavements[J].Construction and Building Materials,2019,226:616-624.
[8] Xue Fei,Lu Yu,Qi Xiaodong,et al.Melamine foam-templated graphene nanoplatelet framework toward phase change materials with multiple energy conversion abilities[J].Chemical Engineering Journal,2019,365:20-29.
[9] Xiao X,Zhang P,Li M.Preparation and thermal characterization of paraffin/metal foam composite phase change material[J].Applied Energy,2013,112:1357-1366.
[10] Wang C,Liang W,Yang Y,et al.Biomass carbon aerogels based shape-stable phase change composites with high light-to-thermal efficiency for energy storage[J].Renewable Energy,2020,153,DOI10.1016/j.renene.2020.02.008.
[11] Cai J,Kimura S,Wada M,et al.Nanoporous cellulose as metal nanoparticles support[J].Biomacromolecules,2009,10(1):87-94.
[12] 张青峰,朱钰漕,张焕芝,等.生物质及其衍生材料在有机复合相变储能材料中的应用[J].现代化工,2021,41(7):6.
[13] 蒋达华,廖绍璠,张鑫林,等.十八酸-十四酸二元相变材料的热性能研究[J].化工新型材料,2020,48(9):4.
[14] 林雅雪.脂肪酸复合相变储能材料的合成及性能研究[D].南京:南京大学,2019.
[15] 苏磊静.石蜡复合定形相变储能材料的结构性能研究[D].北京:北京化工大学,2013.
[16] Nan S A,Zr A,Cza B,et al.Honeycomb carbon fibers strengthened composite phase change materials for superior thermal energy storage-ScienceDirect[J].Applied Thermal Engineering,2020,164:114493.
[17] Umair M M,Zhang Y,Tehrim A,et al.Form-stable phase-change composites supported by a biomass-derived carbon scaffold with multiple energy conversion abilities[J].Industrial & Engineering Chemistry Research,2020,59(4):1393-1401.
[18] Li Y,Samad Y A,Polychronopoulou K,et al.From biomass to high performance solar-thermal and electric-thermal energy conversion and storage materials[J].Journal of Materials Chemistry A,2014,2(21):7759-7765.
[19] Deleuze H,Palazzolo M A,Dourges M A,et al.Preparation of lignosulfonate-based carbon foams by pyrolysis and its use in the microencapsulation of a phase change material[J].ACS Sustainable Chemistry & Engineering,2017,DOI:10.1021/acssuschemeng.7b03900.
[20] 李绍伟,傅彬彬,李静.碳化柚子皮基复合相变材料的制备及性能[J].复合材料学报,2021,39(6):2885-2893.
[21] Yang H,Wang Y,Yu Q,et al.Low-cost,three-dimension,high thermal conductivity,carbonized wood-based composite phase change materials for thermal energy storage[J].Energy,2018,159:929-936.
[22] Wei Y,Li J,Sun F,et al.Leakage-proof phase change composites supported by biomass carbon aerogels from succulents[J].Green Chemistry,2018,20:1858-1865.
[23] Gao J,Xu Q,Zhang J,et al.Fabrication of a novel highly thermal conductive shape-stabilized phase-change material using cheap and easily available cabbage mustard biochar as the matrix[J].JOM,2021,73:2487-2494.
[24] Du X,Qiu J,Eng S D,et al.Alkylated nanofibrillated cellulose/carbon nanotubes aerogels supported form-stable phase change composites with improved n-alkanes loading capacity and thermal conductivity[J].ACS Applied Materials & Interfaces,2020,12(5):5695-5703.
[25] Yang Y,Kong W,Cai X.Solvent-free preparation and performance of novel xylitol based solid-solid phase change materials for thermal energy storage[J].Energy & Buildings,2018,158:37-42.
[26] Liu Z,Fu X,Jiang L,et al.Solvent-free synthesis and properties of novel solid-solid phase change materials with biodegradable castor oil for thermal energy storage[J].Solar Energy Materials and Solar Cells,2016.
[27] Zhou Xiaoming,Liu Zhenyong.Preparation and properties of solid-solid phase change materials based on polyethylene glycol and EPDM cross-linked resin containing cyclodextrin cavity[J].Energy Sources Part A Recovery Utilization & Environmental Effects,2018,40:2044-2054.
[28] Prof.Dr.Greiner Andreas,Prof.Dr.Wendorff Joachim H.Electrospinning:a fascinating method for the preparation of ultrathin fibers[J].Angewandte Chemie,2010,46(30):5670-5703.
[29] Cai Y,Gao C,Xu X,et al.Electrospun ultrafine composite fibers consisting of lauric acid and polyamide 6 as form-stable phase change materials for storage and retrieval of solar thermal energy[J].Solar Energy Materials and Solar Cells,2012,103:53-61.
[30] Abdalkarim S,Yu H,Wang C,et al.Thermo and light-responsive phase change nanofibers with high energy storage efficiency for energy storage and thermally regulated on-off drug release devices[J].Chemical Engineering Journal,2019,375:121979-.
[31] Udangawa W,Willard C F,Mancinelli C,et al.Coconut oil-cellulose beaded microfibers by coaxial electrospinning:an eco-model system to study thermoregulation of confined phase change materials[J].Cellulose,2019,26(3):1855-1868.
[32] Chen C,Zhao Y,Liu W.Electrospun polyethylene glycol/cellulose acetate phase change fibers with core-sheath structure for thermal energy storage[J].Renewable Energy,2013,60:222-225.
[33] 陈丹.生物质多孔相变材料的制备及热湿性能研究[D].西安:西安建筑科技大学,2015.
[34] 黄雪.三元低共熔脂肪酸复合相变材料的制备及热性能研究[D].广州:广东工业大学,2015.
[35] 黄立航.温度可调的无机水合盐/二氧化硅定型复合相变材料的制备及性能[D].广州:华南理工大学,2020.
[36] 张素凌,方玉堂,汪双凤.SA-AC/膨胀石墨的制备及性能研究[J].工程热物理学报,2017,38(12):6.
[37] Zhang W,Zhang X,Zhang X,et al.Lauric-stearic acid eutectic mixture/carbonized biomass waste corn cob composite phase change materials:preparation and thermal characterization[J].Thermochimica Acta,2019,674:21-27.
[38] Zou Z,Wu W,Shen W.Introduction of phase change material into sustainable carbon materials for Enhanced Shape Stability and Thermal Conductivity[J].ChemistrySelect,2020,5(28):8679-8686.
[39] Gu X,Liu P,Liu C,et al.A novel form-stable phase change material of palmitic acid-carbonized pepper straw for thermal energy storage[J].Materials Letters,2019,248:12-15.
[40] Zhang Xiaoguang,Huang Zhaohui,Yin Zhaoyu.Form stable composite phase change materials from palmitic-lauricacid eutectic mixture and carbonized abandoned rice:preparation,characterization,and thermal conductivity enhancement[J].Energy and Buildings,2017,154:46-54.
[41] Zheng X,Zhang Y,Wang H,et al.Interconnected macroporous polymers synthesized from silica particle stabilized high internal phase emulsions[J].Macromolecules,2014,47(19):6847-6855.
[42] Sipponen M,Henn A,Penttil P,et al.Lignin-fatty acid hybrid nanocapsules for scalable thermal energy storage in phase-change materials[J].Chemical Engineering Journal,2020,393:124711.
[43] Singh J,Vennapusa J R,Chattopadhyay S.Protein-polysaccharide based microencapsulated phase change material composites for thermal energy storage[J].Carbohydrate Polymers,2020,229:115531.
[44] Hawlader M,Uddin M S,Khin M M.Microencapsulated PCM thermal-energy storage system[J].Applied Energy,2003,74(1/2):195-202.
[45] Wang Y,Li X,Shen C,et al.Lignin assisted Pickering emulsion polymerization to microencapsulate 1-tetradecanol for thermal management[J].International Journal of Biological Macromolecules,2020,146:1-8.
[46] 顾庆军,费华,王林雅,等.脂肪酸相变储能材料热性能研究进展[J].化工进展,2019,38(6):10.
[47] Wei X,Xue F,Qi X D,et al.Photo- and electro-responsive phase change materials based on highly anisotropic microcrystalline cellulose/graphene nanoplatelet structure[J].Applied Energy,2019,236:70-80.
[48] Irani F,Ranjbar Z,Jannesari A,et al.Fabrication and characterization of microencapsulated n-heptadecane with graphene/starch composite shell for thermal energy storage[J].Progress in Organic Coatings (Elsevier),2019,131:203-210.
[49] 郭启霖.膨胀石墨/赤藓糖醇相变复合材料的制备与热性能研究[D].哈尔滨:哈尔滨工业大学,2015.
基金资助
国家自然科学基金(51966004);江西省自然科学基金项目(20212BAB204029);江西理工大学清江青年优秀人才项目(JXUSTQJYX2017003)