TiO2基异质结光催化剂应用于有机污染物降解的研究进展

杨鹤云1,2, 李晓良1,2, 郑兴1,2*

化工新型材料 ›› 2023, Vol. 51 ›› Issue (6) : 64 -69.

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化工新型材料 ›› 2023, Vol. 51 ›› Issue (6) : 64-69. DOI: 10.19817/j.cnki.issn1006-3536.2023.06.012
综述与专论

TiO2基异质结光催化剂应用于有机污染物降解的研究进展

    杨鹤云1,2, 李晓良1,2, 郑兴1,2*
作者信息 +

Research progress of TiO2-based heterojunction photocatalyst for degradation of organic pollutants

  • Yang Heyun1,2, Li Xiaoliang1,2, Zheng Xing1,2
Author information +
文章历史 +
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摘要

光催化技术具有绿色、清洁、环境友好等优点,被广泛应用于降解水体中的有机污染物。其中,TiO2光催化剂由于其独特的优势,被认为是一种十分具有前景的光催化剂。然而,其本身存在着带隙能较宽可见光响应不足与载流子复合几率高等缺点导致光催化活性受限。为解决以上问题,TiO2与异质结的结合引起了研究者的兴趣。并且采用一定的改性手段制备的非常规TiO2基异质结,具有很高的光催化降解能力。但这些新型光催化剂在实际应用中仍具有极大的挑战,例如成本较高、稳定性较差以及副产物毒性风险高等等。基于此,对现有TiO2基异质结的相关研究进行了系统全面的综述,以期为后续研究提供一定的理论支持。

Abstract

Photocatalytic technology has the advantages of being green,clean and environment-friendly,and is widely used to degrade organic pollutants in water.Among them,TiO2 material is considered to be a promising photocatalyst because of its unique advantages.However,it has some drawbacks,such as wide band gap energy,insufficient visible light response and high recombination probability of carriers,which lead to the limitation of photocatalytic activity.To solve the above problems,the combination of TiO2 and heterojunction has aroused the interest of researchers.In addition,the unconventional TiO2-based heterojunction prepared by certain modification means has high photocatalytic degradation ability.However,these new photocatalysts still have great challenges in practical application,such as high cost,poor stability and high toxicity risk of by-products.Based on this,this paper made a systematic and comprehensive review of the existing research on TiO2-based heterojunctions in order to provide a certain theoretical support for the future research.

关键词

二氧化钛材料 / 异质结 / 改性二氧化钛基异质结 / 有机污染物降解 / 面临的挑战

Key words

TiO2 materials / heterojunction / modified TiO2-based heterojunction / organic pollutants degradation / challenges faced

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TiO2基异质结光催化剂应用于有机污染物降解的研究进展[J]. 化工新型材料, 2023, 51(6): 64-69 DOI:10.19817/j.cnki.issn1006-3536.2023.06.012

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基金资助

国家自然科学基金(52100104和52170053)

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