由于间歇性可再生能源供应的不断增加,电池储能系统在能源消费方面有巨大需求,钒氧化还原电池系统因其可扩展性和稳定性备受关注。膜材料是该类电池系统的关键组件,对电池系统的性能和运行成本有较大影响。基于Nafion基质子交换膜的钒离子选择性低和材料成本高等问题,研究者进行了大量探索。通过材料改性或使用替代材料可以提高膜性能、降低膜成本,进而促进该类电池系统的工业化应用。综述了不同类型膜材料的研发进展,分析了决定膜性能的重要因素,指出了未来可能提高电池系统性能、降低电池成本的新型膜材料的发展方向。
Due to the increasing supply of intermittent renewable energy,there is a huge demand for battery storage systems in terms of energy consumption.Vanadium redox battery system has attracted much attention for its scalability and stability.Membrane material is the key component of this battery system,which has great influence on the performance and operating cost of the battery system.Based on the problems of low vanadium ion selectivity and high material cost of Nafion proton exchange membranes,researchers have made a lot of exploration.The performance of membrane can be improved and the cost of membrane can be reduced by material modification or the use of substitution,which will promote the industrial application of this kind of battery system.This paper reviewed the research and development progress of different membrane materials,analyzed the important factors that determined the membrane performance,and pointed out the development direction of new membrane materials that might improve the performance of battery system and reduced the cost of battery.
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基金资助
抚顺市“抚顺英才计划”项目(FSYC202107010);辽宁省教育厅上面的项目(LJK0411);国家自然科学基金面上项目(21676282)
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