脂肪酸复合相变材料的微观结构及其热稳定性研究进展

潘昱丞, 费华*, 贺倩, 杜文清, 周嘉宏, 梁西妹

化工新型材料 ›› 2023, Vol. 51 ›› Issue (6) : 18 -23.

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化工新型材料 ›› 2023, Vol. 51 ›› Issue (6) : 18-23. DOI: 10.19817/j.cnki.issn1006-3536.2023.06.004
综述与专论

脂肪酸复合相变材料的微观结构及其热稳定性研究进展

    潘昱丞, 费华*, 贺倩, 杜文清, 周嘉宏, 梁西妹
作者信息 +

Research progress on microstructure and thermal stability of fatty acid composite phase change materials

  • Pan Yuchen, Fei Hua, He Qian, Du Wenqing, Zhou Jiahong, Liang Ximei
Author information +
文章历史 +
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摘要

脂肪酸相变材料是目前重要的储热功能材料之一,因其稳定的化学性质和优异的物理性能被广泛关注,但是也存在相变温度不理想、易泄漏和热性能不稳定等问题。通过现有文献,总结了对脂肪酸相变材料相变温度不适宜和热导率低的改良方法;针对易泄露的问题讨论了多孔介质吸附和微胶囊化两种有效的解决方法;对比了两种制备方法得到的脂肪酸复合相变材料微观结构的差异,并分析了两种制备方法的优缺点;综述了脂肪酸复合相变材料热稳定性能的影响因素。最后就脂肪酸复合相变材料发展现状提出了今后的研究方向,为建筑节能材料的发展提供理论基础。

Abstract

Fatty acid phase change material is one of the important heat storage functional materials at present,and has attracted much attention due to their stable chemical properties and excellent physical performances.However,there are some disadvantages such as unsatisfactory phase transition temperature,easy leakage and unstable thermal performance.Based on the existing literatures,the improvement methods for inappropriate phase change temperature and poor thermal conductivity of fatty acid phase change materials were summarized.Aiming at the problem of easy leakage,two effective solutions,porous media adsorption and microencapsulation,were discussed.The microstructure differences of fatty acid composite phase change materials obtained by the two preparation processes were compared,and the advantages and disadvantages of the two preparation processes were analyzed.The factors affecting thermal stability of fatty acid phase change composite materials were reviewed.Finally,the future development direction of fatty acid composite phase change materials was put forward,which provided a theoretical basis for the development of building energy-saving materials.

关键词

脂肪酸 / 微观结构 / 热稳定性 / 热循环

Key words

fatty acids / microstructure / thermal stability / thermal cycle

引用本文

引用格式 ▾
脂肪酸复合相变材料的微观结构及其热稳定性研究进展[J]. 化工新型材料, 2023, 51(6): 18-23 DOI:10.19817/j.cnki.issn1006-3536.2023.06.004

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参考文献

[1] 顾庆军,费华,王林雅,等.脂肪酸相变储能材料热性能研究进展[J].化工进展,2019,38(6):2825-2834.
[2] 贺倩,费华,杜文清,等.膨胀石墨基相变材料孔隙结构及导热性能的研究进展[J].化工新型材料,2021,49(4):11-20.
[3] 李贝,刘道平,杨亮.复合相变蓄热材料研究进展[J].制冷学报,2017,38(4):36-43.
[4] 王毅,夏天东,冯辉霞.有机相变储热材料的研究进展[J].材料导报,2011,25(3):66-74.
[5] 石文华,朱兴元,朱教群,等.癸酸-棕榈酸/硅藻土储能石膏复合材料的制备与性能[J].储能科学与技术,2017,6(6):1306-1312.
[6] 陈文朴,章学来,丁锦宏,等.癸酸-正辛酸低温相变材料的制备和循环性能[J].制冷学报,2016,37(3):12-16.
[7] 孟多,王立久.脂肪酸/无机纳米颗粒基定形相变材料的制备与热性能[J].建筑材料学报,2013,16(1):91-96.
[8] Eanest J B,Valan A A.Characterisation and stability analysis of eutectic fatty acid as a low cost cold energy storage phase change material[J].Journal of Energy Storage,2020,31:101708.
[9] 李忠,井波,于少明.CA-SA/蒙脱土复合相变贮能材料的制备、结构与性能[J].化工新型材料,2007,35(3):42-44.
[10] 刘凤利,胡国峰,刘俊华,等.癸酸-硬脂酸有机膨胀蛭石相变蓄热砂浆的制备与性能研究[J].功能材料,2020,51(5):5007-5012.
[11] 黄雪,崔英德,尹国强,等.癸酸-棕榈酸-硬脂酸/膨胀石墨蓄能复合相变材料的制备与热性能研究[J].材料导报,2017,31(14):52-56.
[12] 孟新,张焕芝,赵梓名,等.三元脂肪酸/膨胀石墨复合相变材料的制备、包覆定形及热性能[J].高等学校化学学报,2012,33(3):526-530.
[13] 王立久,孟多.LA-MA/聚甲基丙烯酸甲酯复合相变蓄热材料的制备与性能[J].功能材料,2010,41(4):709-712.
[14] 蔡伟,孙志高,马鸿凯,等.月桂酸-十四醇二元复合相变材料的相变特性[J].太阳能学报,2017,38(9):2493-2497.
[15] 王委委,宋肖飞,蔡以兵,等.三元脂肪酸共晶物/二氧化硅定形相变复合材料的制备及其热性能[J].材料科学与工程学报,2020,38(1):68-73.
[16] 孙晓璐,苏婧,宋肖飞,等.月桂酸-棕榈酸/Al2O3复合定形相变材料的制备与热性能研究[J].化工新型材料,2019,47(6):171-175.
[17] 周孙希,章学来,刘升,等.癸醇-棕榈酸/膨胀石墨低温复合相变材料的制备与性能[J].化工学报,2019,70(1):290-297.
[18] 王大程,谭淑娟,徐国跃,等.硬脂酸/碳纳米管/聚甲基丙烯酸甲酯复合相变胶囊的制备与热性能研究[J].太阳能学报,2019,40(1):24-29.
[19] 张东,康韡,李凯莉.复合相变材料研究进展[J].功能材料,2007,38(12):1936-1940.
[20] 张焕芝,崔韦唯,夏永鹏,等.复合相变材料的制备及热性能研究进展[J].化工新型材料,2019,47(6):35-38,43.
[21] 付路军,董发勤,杨玉山,等.二元脂肪酸SiO2复合相变储能材料的制备与表征[J].功能材料,2013,44(4):548-551.
[22] Alva G,Huang X,Liu L K,et al.Synthesis and characterization of microencapsulated myristic acid-palmitic acid eutectic mixture as phase change material for thermal energy storage[J].Applied Energy,2017,203:677-685.
[23] 尉菁华,刘欢,连慧琴,等.棕榈酸二氧化硅相变微胶囊的制备及性能研究[J].中国塑料,2020,34(2):1-8.
[24] Yang X,Liu Y,Lv Z,et al.Synthesis of high latent heat lauric acid/silica microcapsules by interfacial polymerization method for thermal energy storage[J].Journal of Energy Storage,2021,33:102059.
[25] Xing J,Zhou Y,Yang K,et al.Microencapsulation of fatty acid eutectic with polyvinyl chloride shell used for thermal energy storage[J].Journal of Energy Storage,2021,34:101998.
[26] 王信刚,陈忠发,徐伟,等.癸酸相变微胶囊的制备及热性能[J].精细化工,2019,36(11):2207-2212.
[27] Dao T D,Jeong H M.Novel stearic acid/graphene core-shell composite microcapsule as a phase change material exhibiting high shape stability and performance[J].Solar Energy Materials & Solar Cells,2015,137:227-234.
[28] Fei H,Du W Q,He Q,et al.Study of phase-transition characteristics of new composite phase change materials of capric acid-palmitic acid/expanded graphite[J].ACS Omega,2020,5:27522-27529.
[29] 李云涛,晏华,汪宏涛,等.月桂酸复合相变材料的制备与性能研究[J].化工新型材料,2016,44(11):64-66.
[30] 吴韶飞,闫霆,蒯子函,等.高导热膨胀石墨/棕榈酸定形复合相变材料的制备及储热性能研究[J].化工学报,2019,70(9):3553-3564,3207.
[31] Li C C,Zhang B,Xie B S,et al.Stearic acid/expanded graphite as a composite phase change thermal energy storage material for tankless solar water heater[J].Sustainable Cities and Society,2019,44:458-464.
[32] 张庆,王宏丽,米欣.月桂酸-肉豆蔻酸-癸酸/膨胀石墨定形相变材料的制备与性能研究[J].化工新型材料,2015,43(4):46-48.
[33] Wei T,Zheng B C,Liu J,et al.Structures and thermal properties of fatty acid/expanded perlite composites as form-stable phase change materials[J].Energy and Buildings,2014,68:587-592.
[34] 赵思勰,晏华,汪宏涛,等.月桂酸/膨胀珍珠岩复合相变材料的制备与热性能研究[J].材料导报,2017,31(10):107-111.
[35] 孟多,王东旭,王立久,等.改性硅藻土脂肪酸定形相变材料的制备及性能[J].功能材料,2017,48(10):10149-10153.
[36] Jin J,Liu L,Liu R,et al.Preparation and thermal performance of binary fatty acid with diatomite as form-stable composite phase change material for cooling asphalt pavements[J].Construction and Building Materials,2019,226:616-624.
[37] 田胜力,张东,肖德炎,等.脂肪酸相变储能材料热循环行为的试验研究[J].材料开发与应用,2006(1):9-12.
[38] 谢雯倩,王温馨,丁益民.LA-PA/焦粉复合相变储能材料的制备与性能研究[J].化工新型材料,2021,49(10):138-141,145.
[39] Saeed R M,Schlegel J P,Castano C,et al.Preparation and thermal performance of methyl palmitate and lauric acid eutectic mixture as phase change material(PCM)[J].Journal of Energy Storage,2017,13:418-424.
[40] Zhou S X,Zhang X L,Liu S,et al.Performance study on expand graphite/organic composite phase change material for cold thermal energy storage[J].Energy Procedia,2019,158:5305-5310.
[41] Yang X J,Yuan Y P,Zhang N,et al.Preparation and properties of myristic-palmitic-stearic acid/expanded graphite composites as phase change materials for energy storage[J].Solar Energy,2014,99:259-266.
[42] Jiang L,Liu Z M,Yuan Y,et al.Fabrication and characterization of fatty acid/wood-flflour composites as novel form-stable phase change materials for thermal energy storage[J].Energy & Buildings,2018,171:88-99.
[43] Gökhan H,Memduh N,Mohammed O,et al.Silica fume/capric acid-stearic acid PCM included-cementitious composite for thermal controlling of buildings:thermal energy storage and mechanical properties[J].Energy,2021,219:119588.
[44] Fei H,Du W Q,Gu Q J,et al.The phase change characteristics of capric acid-based binary low eutectic mixtures adsorbed in expanded graphite[J].Energy Fuels,2020,34:14893-14901.

基金资助

国家自然科学基金(51966004);江西省自然科学基金项目(20212BAB204029);江西理工大学清江青年优秀人才项目(JXUSTQJYX2017003)

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