泡沫陶瓷/聚氨酯复合材料的制备及性能研究

王陈鹏1, 刘佳伟1, 马跃1, 刘颖隆1, 叶豪1, 许晓茹1, 刘英丽1, 陈智聪1, 李云飞2, 梁波1,2*

化工新型材料 ›› 2023, Vol. 51 ›› Issue (5) : 266 -269.

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化工新型材料 ›› 2023, Vol. 51 ›› Issue (5) : 266-269. DOI: 10.19817/j.cnki.issn1006-3536.2023.05.049
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泡沫陶瓷/聚氨酯复合材料的制备及性能研究

    王陈鹏1, 刘佳伟1, 马跃1, 刘颖隆1, 叶豪1, 许晓茹1, 刘英丽1, 陈智聪1, 李云飞2, 梁波1,2*
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Preparation and performance study of foam ceramic/polyurethane composites

  • Wang Chenpeng1, Liu Jiawei1, Ma Yue1, Liu Yinglong1, Ye Hao1, Xu Xiaoru1, Liu Yingli1, Chen Zhicong1, Li Yunfei2, Liang Bo1,2
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摘要

以不同孔隙密度泡沫陶瓷作为复合材料骨架,选用聚氨酯作为基底材料填充进泡沫陶瓷,制备出泡沫陶瓷-聚氨酯复合材料。通过分析复合材料的微观形貌,以及对材料的压缩和冲击性能进行测试分析,研究了不同孔隙密度泡沫陶瓷对复合材料压缩性能及冲击性能的影响。结果表明:加入泡沫陶瓷后的复合材料界面结合紧密,性能得到提高。当泡沫陶瓷的孔径密度为40ppi时,复合材料压缩强度得到了极大提高,达到了16.52MPa,相比较纯PU,压缩强度提高了84.2%,复合材料压缩强度达到最大。但复合材料的抗冲击性能与泡沫陶瓷孔隙密度成反比,泡沫陶瓷孔隙密度越低,材料抗冲击性能越好,20ppi泡沫陶瓷聚氨酯复合材料冲击能量为66.25J,与纯聚氨酯相比,冲击能量提高了367.2%,性能得到明显增长,表现出良好的力学性能,可在建材领域加以利用。

Abstract

The foam ceramics with different pore densities were used as the composite skeleton,and polyurethane was used as the substrate material to fill into the foam ceramics to prepare foam ceramic-polyurethane composite material.Through analyzing the micro morphology of the composite materials and testing their compression and impact properties,the influence of different pore density foam ceramics on the compression and impact properties of composite materials were studied.It was found that the interface bonding of the composites with the addition of foam ceramics was tight and the properties were improved.When the pore size density of ceramic foam was 40ppi,the compressive strength of the composite material was greatly improved and reached 16.52MPa,which was 84.2% higher than that of pure PU,and the compressive strength of the composite achieved the maximum.However,the impact resistance of the composites was inversely proportional to the pore density of ceramic foam.The lower the pore density of ceramic foam,the better the impact resistance of the materials.The impact energy of 20ppi foam ceramic polyurethane composite was 66.25J,which increased by 367.2% compared with pure polyurethane,proving that the performance was significantly enhanced.The composites had good mechanical properties and could be used in the field of building materials.

关键词

聚氨酯 / 泡沫陶瓷 / 压缩强度 / 冲击强度

Key words

polyurethane / foam ceramic / compressive strength / impact strength

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泡沫陶瓷/聚氨酯复合材料的制备及性能研究[J]. 化工新型材料, 2023, 51(5): 266-269 DOI:10.19817/j.cnki.issn1006-3536.2023.05.049

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参考文献

[1] 韩红青,赵浩成.室温固化聚醚型聚氨酯弹性体的制备及研究[J].化工新型材料,2013,41(9):59-62.
[2] 李雅瑜,周天扬,施冬健,等.基于多重氢键的自修复聚氨酯弹性体的制备与性能研究[J].化工新型材料,2021,49(7):89-93.
[3] 莫钦,张雅峰,熊林颖,等.聚氨酯胶粘剂热稳定性研究进展[J].化工新型材料,2021,49(3):213-217.
[4] 秦国治,王顺.硬质聚氨酯泡沫塑料及其应用[J].化工设备与防腐蚀,1998(6):46-52.
[5] 王宇,田春蓉,芦艾,等.聚氨酯固-固相变材料的合成与性能分析[J].化工新型材料,2013,41(2):82-88.
[6] 徐祥,沈照羽,崔胜凯,等.发泡剂对硬质聚氨酯泡沫性能的影响[J].热固性树脂,2021,36(2):31-39.
[7] 张俊兵.硬质聚氨酯发泡成型探讨[J].山西建筑,2019,45(1):179-180.
[8] 杨颖旎,尚丽娜,赵俊淇,等.聚氨酯相变储能微胶囊的制备及性能表征[J].化工新型材料,2019,47(12):97-100.
[9] 李捍东,张旭,王志,等.不同基材聚氨酯泡沫热稳定性研究[J].化工新型材料,2022,50(6):110-114.
[10] 王志超,刘冰,王志,等.Fe2+-ATMP阻燃改性硬质聚氨酯泡沫热稳定性研究[J].化工新型材料,2022,50(11):1-10.
[11] 罗霞,俞科静,王梦蕾,等.硅烷偶联剂对玻璃纤维/聚氨酯复合材料性能的影响研究[J].化工新型材料,2017,45(8):87-89.
[12] 秦传睿,陆伟,徐帅,等.硅烷偶联剂对矿用聚氨酯/粉煤灰加固材料压缩强度的影响[J].煤矿安全,2019,50(7):81-85.
[13] 邵迪,刁建志,王丽洁,等.聚氨酯/无机填料复合弹性体的制备及性能研究[J].化工新型材料,2016,44(10):156-158.
[14] 魏建国,马端人,柳佳,等.玻纤增强聚氨酯泡沫的研制[J].聚氨酯工业,2020,35(1):36-38.
[15] 李莉,王宏斌,姚亮,等.聚氨酯/金刚砂复合材料的制备及性能研究[J].化工新型材料,2014,42(3):83-85.
[16] Han M S,Kim Y H,Han S J,et al.Effects of a silane coupling agent on the exfoliation of organoclay layers in polyurethane/organoclay nanocomposite foams[J].Journal of Applied Polymer Science,2008,110(1):376-386.
[17] Hu J,Li F,Wang B,et al.A two-step combination strategy for significantly enhancing the interfacial adhesion of CF/PPS composites:the liquid-phase oxidation followed by grafting of silane coupling agent[J].Composites Part B,2020,191:1-12.
[18] Jiang S,Li Q,Zhao Y,et al.Effect of surface silanization of carbon fiber on mechanical properties of carbon fiber reinforced polyurethane composites[J].Composites Science and Technology,2015,110:87-94.
[19] Wen Z,Xu C,Qian X,et al.A two-step carbon fiber surface treatment and its effect on the interfacial properties of CF/EP composites:the electrochemical oxidation followed by grafting of silane coupling agent[J].Applied Surface Science,2019,486:546-554.
[20] Wu B,Zheng G,Wang R,et al.Synergistic modification of carbon fiber by electrochemical oxidation and sizing treatment and its effect on the mechanical properties of carbon fiber reinforced composites[J].Journal of Applied Polymer Science,2019,136(41):1-10.
[21] Zo H J,Joo S H,Kim T,et al.Enhanced mechanical and thermal properties of carbon fiber composites with polyamide and thermoplastic polyurethane blends[J].Fibers and Polymers,2014,15(5):1071-1077.
[22] 陈斐,孙婉婉,姜敬陆,等.可瓷化聚氨酯泡沫复合材料的制备和阻燃性能[J].武汉理工大学学报,2016,38(4):1-7.
[23] 冯胜山,刘庆丰.常温固化免烧结泡沫陶瓷复合材料的制备及性能[J].陶瓷,2009(12):17-21.
[24] 郭怀泉,李冰,律微波,等.聚氨酯互穿网络聚合物的制备与性能分析[J].化工新型材料,2016,44(9):4-6.
[25] 秦桑路,杨振国,赵斌,等.增强聚氨酯硬泡塑料的冲击性能研究[J].玻璃钢/复合材料,2004(1):18-20.

基金资助

国家自然科学基金面上项目(500200137);国家重点研发计划(500190028)

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