Corn stalk was used as carbon source (CS),pretreated by soaking in Na2CO3 solution and activated by KOH to prepare porous biomass carbon (CS-ACS).The component,structure,morphology and electrochemical performances were investigated.The researches revealed that CS-AC-3 had multi-channel structure and the specific surface area could reach 3299m2/g.In three-electrode system,its specific capacitance as single electrode was up to 272F/g and 220F/g in 6mol/L NaOH solution and 0.5mol/L Na2SO4 solution as the electrolytes at a current density of 1A/g,respectively,and its capacity retention was 89% and 80%,respectively,after 5000 cycles at a current density of 5A/g.The CS-AC-3//CS-AC-3 symmetric capacitor assembled with this material had a wide voltage window of 1.4V and good electrochemical performance in two-electrode system.As a renewable and promising carbon material,the CS-ACS had excellent prospects for practical application.
[1] Wei Q L,Chen Z M,Wang X F,et al.A two-step method for the preparation of high performance corncob-based activated carbons as supercapacitor electrodes using ammonium chloride as a pore forming additive[J].New Carbon Materials,2018,33(5):402-408.
[2] Huang J Y,Liang Y R,Hu H,et al.Ultrahigh-surface-area hierarchical porous carbon from chitosan:acetic acid mediated efficient synthesis and its application in superior supercapacitors[J].Journal of Materials Chemistry A,2017,5(47):24775-24781.
[3] Noori A,Ei-Kady M F,Rahmanifar M S,et al.Towards establishing standard performance metrics for batteries,supercapacitors and beyond[J].Chemical Society Reviews,2019,48(5):1272-1341.
[4] Deb-Nath N C,Jeon I Y,Ju M J,et al.Edge-carboxylated graphene nanoplatelets as efficient electrode materials for electrochemical supercapacitors[J].Carbon,2019,142(28):89-98.
[5] 李宁,陈涛.石墨烯基电极材料在柔性全固态超级电容器中的研究进展[J].应用化学,2018,35(3):259-271.
[6] 张晓凤,项锦欣,田井清,等.Na2CO3、K2CO3和KOH制备废弃柑橘皮渣活性炭及其性能分析[J].化学试剂,2021,43(3):274-279.
[7] 肖钰,刘慕函,廖丽霞,等.基于稻谷壳的多孔生物质碳锂离子电池负极材料的制备及性能研究[J].化工新型材料,2019,47(12):113-116.
[8] Tang W J,Zhang Y F,Zhong Y,et al.Natural biomass-derived carbons for electrochemical energy storage[J].Materials Research Bulletin,2017,88(4):234-241.
[9] Wei Q L,Chen Z M,Wang X F,et al.A two-step method for the preparation of high performance corncob-based activated carbons as supercapacitor electrodes using ammonium chloride as a pore forming additive[J].New Carbon Materials,2018,33(5):402-408.
[10] 宗飞旭,潘超,高静怡,等.海带基微孔/介孔复合多级孔纳米炭的制备及电化学性能研究[J].纳米技术,2017,7(1):11-20.
[11] 姜洋,牛云凤,王燕,等.树叶基多孔碳材料的制备及其电化学性能研究[J].燕山大学学报,2016,40(3):257-262.
[12] Yang C,Jang Y S,Jeong H K.Bamboo-based activated carbon for supercapacitor applications[J].Current Applied Physics,2014,14(12):1616-1620.
[13] 邓筠飞,杜卫民,王梦瑶,等.基于玉米秸秆合成的多孔生物质炭材料及其电化学储能[J].应用化学,2019,36(11):1323-1332.
[14] Du Y,Li N,Zhang T L,et al.Reduced graphene oxide coating with anticorrosion and electrochemical property-enhancing effects applied in hydrogen storage system[J].ACS Applied Materials & Interfaces,2017,9(34):28980-28989.
[15] Li D W,Chen D Y,Zhu X F.Reduction in time required for synthesis of high specific surface area silica from pyrolyzed rice husk by precipitation at lowpH[J].Bioresource Technology,2011,102(13):7001-7003.
[16] Gao Z,Zhang G Y,Song N,et al.Biomass-derived renewable carbon materials for electrochemical energystorage[J].Materials Research Letters,2017,5(2):69-88.
[17] Fic K,Lota G,Meller M,et al.Novel insight into neutral medium as electrolyte for high-voltage supercapacitors[J].t Energy & Environmental Science,2012,5(2):5842-5850.
基金资助
甘肃省河西走廊特色资源利用重点实验室面上项目(XY1809);国家级大学生创新创业训练计划项目(201910740008)