金属有机框架化合物(MOFs)具有较多孔道,且孔道内存在大量均匀分布的不饱和金属位点,赋予了MOFs材料优异的催化性能。从Fe基MOFs、Zr基MOFs、Zn基MOFs、Cu基MOFs等不同金属簇的MOFs光催化材料角度,评述了MOFs材料在光催化还原Cr(Ⅵ)方面的研究进展,对MOFs材料在光催化还原Cr(Ⅵ)领域的研究前景进行了展望。
There are abundant channels in metal organic frameworks (MOFs) and a large number of uniformly distributed unsaturated metal sites in the channels,which give MOFs materials excellent catalytic performance.The research progress of photocatalytic reduction of Cr(Ⅵ) was reviewed from the perspective of MOFs with different metal clusters such as Fe MOFs,Zr MOFs,Zn MOFs and Cu MOFs.The research prospect of MOFs materials in the field of photocatalytic reduction of Cr(Ⅵ) was discussed.
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基金资助
辽宁省“兴辽英才”项目(XLYC1907173);辽宁省教育厅科学研究经费项目(LQ2019003、LQ2020014和LJ2020014);辽宁省科技厅博士启动基金项目(2021-BS-253);国家环境保护近岸海域生态环境重点实验室开放基金(202103);渤海大学海洋研究院开放基金(BDHYYJY2021006,BDHYYJY2020014)