中空纳米纤维具有独特的中空结构和较大的比表面积,在吸附、催化、电化学、医药等领域具有广阔的应用前景。静电纺丝技术是制备中空纳米纤维的有效手段。随着静电纺丝工艺的不断成熟,利用静电纺丝大规模制备中空纳米纤维提上了日程。首先详细介绍了基于静电纺丝技术制备中空纳米纤维的原理和方法,探讨了现阶段基于静电纺丝技术大规模制备中空纳米纤维存在的问题以及研究现状,总结了中空纳米纤维的应用进展,最后指出了中空纳米纤维的发展方向,为推动中空纳米纤维的大规模制备及应用奠定基础。
With unique hollow structures and high specific surface areas,hollow nanofibers have promising applications in the fields of adsorption,catalysis,electrochemistry,and medicine.Electrostatic spinning technology is an effective way to produce hollow nanofibers.With developments of electrostatic spinning process,the large-scale preparations of hollow nanofibers using electrostatic spinning is on the agenda.Firstly,the article introduced the principle and method of preparing hollow nanofibers based on electrostatic spinning technology in detail.Secondly,it discussed the problems and research status of large-scale preparation of hollow nanofibers based on electrostatic spinning technology at this stage.Next,it summarized the progress of application of hollow nanofibers.Finally pointed out the development direction of hollow nanofibers to lay the foundation for promoting the large-scale preparation and application of hollow nanofibers.
[1] Eatemadi A,Daraee H,Zarghami N,et al.Nanofiber:synthesis and biomedical applications[J].Artificial Cells Nanomedicine and Biotechnology,2016,44(1):111-121.
[2] Song B,Wu L,Wu C,et al.Preparation of hollow bioactive glass nanofibers by a facile electrospinning method[J].Biomedical Glasses,2015,1(1):136-139.
[3] Cui B,Wang H Z,Li Y G,et al.Synthesis and properties of hollow CaSi2O2N2∶Eu2+ luminescence fibers[J].Journal of Inorganic Materials,2014,29(10):1029-1033.
[4] Shang J,Zou W,Wang P,et al.Preparation and characterization of hollow zinc oxide nanofibers and investigation of its photocatalytic properties[J].Journal of Nanoelectronics and Optoelectronics,2021,16(1):64-71.
[5] Xie W,Khan S A,Rojas O J,et al.Control of micro- and mesopores in carbon nanofibers and hollow carbon nanofibers derived from cellulose diacetate via vapor phase infiltration of diethyl zinc[J].ACS Sustainable Chemistry & Engineering,2018,6(11):13844-13853.
[6] Di Salle A,Viscusi G,Di Cristo F,et al.Antimicrobial and antibiofilm activity of curcumin-loaded electrospun nanofibers for the prevention of the biofilm-associated infections[J].Molecules (Basel,Switzerland),2021,26(16):4866.
[7] Wang Y,Xu J,Shen Y,et al.Fabrication of energetic aluminum core/hydrophobic shell nanofibers via coaxial electrospinning[J].Chemical Engineering Journal,2022,427:132001.
[8] Ou K L,Chen C S,Lin L H,et al.Membranes of epitaxial-like packed,super aligned electrospun micron hollow poly(L-lactic acid) (PLLA) fibers[J].European Polymer Journal,2011,47(5):882-892.
[9] 周一凡,郑勰,周剑锋,等.温度响应性中空纳米纤维膜的制备和表征[J].材料研究学报,2018,32(5):327-332.
[10] 李树锋,程博闻,罗永莎,等.聚丙烯腈基活性中空碳纳米纤维制备及其性能[J].纺织学报,2019,40(10):1-6.
[11] Hu H,Yang Y,Jiang X,et al.Double-shelled hollow SiO2@N-C nanofiber boosts the lithium storage performance of [PMo12O40]3-[J].Chemistry-A European Journal,2021,27(53):13367-13375.
[12] 滕乐天,赵康,王红珍,等.静电纺丝技术制备TiO2/NiO复合中空纳米纤维及光催化性能[J].人工晶体学报,2014,43(12):3175-3179.
[13] 徐淑芝,董相廷,盖广清,等.三层同轴静电纺丝技术制备TiO2@SiO2同轴双壁亚微米管及光催化性能研究[J].化学学报,2012,70(15):1660-1666.
[14] Lee B S,Yang H S,Yu W R.Fabrication of double-tubular carbon nanofibers using quadruple coaxial electrospinning[J].Nanotechnology,2014,25(46):465602.
[15] Xu G,Chen X,Zhu Z,et al.Pulse gas-assisted multi-needle electrospinning of nanofibers[J].Advanced Composites and Hybrid Materials,2020,3(1):98-113.
[16] Campatelli G,Sapuppo L,Scippa A.Analytical-FE simulation of a multi-jet electrospinning process to predict material flow[J].Simulation Modelling Practice and Theory,2015,52:135-148.
[17] 李建军,季骥,王丽秋.圆环状辅助电极多针头静电纺丝体系电场分布研究及Al2O3/ZrO2复合纤维的制备[J].中国陶瓷,2018,54(9):40-45.
[18] Li Y,Zhu J,Cheng H,et al.Developments of advanced electrospinning techniques:a critical review[J].Advanced Materials Technologies,2021,6(11):2100410.
[19] Pokorny M,Klemes J,Kotzianova A,et al.The effects of electric field dynamics on the quality of large-area nanofibrous layers[J].Polymers,2021,13(12):1968.
[20] Ning P,Shi H,Niu P,et al.Electric field analysis of auxiliary electrode in needle-free electrostatic spinning[J].Ferroelectrics,2019,548(1):60-71.
[21] 陈柔羲.新型气泡静电纺丝技术及自清洁纳米纤维膜的制备[D].苏州:苏州大学,2016.
[22] 房飞宇,王晗,陈新,等.一种大量制备三维纳米纤维支架的离心气电纺装置:CN201510780518.6[P].2016-03-30.
[23] Xu J,Liu X,Zhang Z,et al.Controllable generation of nanofibers through a magnetic-field-assisted electrospinning design[J].Materials Letters,2019,247(15):19-24.
[24] Maximilian S,Amanda C,Maheshinie R,et al.Improved control over polymer nanofiber deposition with a programmable 3-axis electrospinning apparatus[J].Journal of Electrostatics,2020,103:103406.
[25] 江爱云.多孔中空PLA纤维的制备及其应用研究[D].苏州:苏州大学,2020.
[26] Kwon Y,Yoon J,Jeon S Y,et al.Numerical simulation of gas-assisted polymer-melt electrospinning:parametric study of a multinozzle system for mass production[J].Polymer Engineering & Science,2020,60(9):2111-2121.
[27] Yang X,Mao L,Peng W,et al.Synthesis of double-layered NiCo2O4-nanosheet-loaded PAN/lignin-based hollow carbon nanofibers for high-performance supercapacitor[J].Chemistry Select,2020,5(8):2602-2609.
[28] Hong S,Lee S,Paik U.Core-shell tubular nanostructured electrode of hollow carbon nanofiber/manganese oxide for electrochemical capacitors[J].Electrochimica Acta,2014,141:39-44.
[29] Zeng T,Feng D,Liu Q,et al.Confining nano-GeP in nitrogenous hollow carbon fibers toward flexible and high-performance lithium-ion batteries[J].ACS Applied Materials & Interfaces,2021,13(28):32978-32988.
[30] Hwang S H,Kim Y K,Hong S H,et al.Cu/CuO@ZnO hollow nanofiber gas sensor:effect of hollow nanofiber structure and P-N junction on operating temperature and sensitivity[J].Sensors (Basel),2019,19(14):3151.
[31] Yang J,Han W,Ma J,et al.Sn doping effect on NiO hollow nanofibers based gas sensors about the humidity dependence for triethylamine detection[J].Sensors and Actuators B:Chemical,2021,340:129971.
[32] Yang C,Yang Y,Zhang C,et al.High selectivity of Ag-doped Fe2O3 hollow nanofibers in H2S detection at room operating temperature[J].Sensors and Actuators B:Chemical,2021,341:129919.
[33] 姚怡媛,王超海,晏鑫,等.硼-氮共掺杂中空碳纳米纤维的制备及其活化过一硫酸盐降解双酚A的性能研究[J].环境科学学报,2021,41(7):2774-2784.
[34] 刘瑞红,周全,杨帆,等.PVDF中空纳米纤维的制备及其固定化酶的性能研究[J].太原理工大学学报,2022,53(1):36-43.
[35] Bi J,Wu Y B,Zhao H Y,et al.Preparation and photocatalytic properties of La2CoFeO6 bamboo-like hollow nanofibers[J].Journal of Inorganic Materials,2015,30(10):1031-1036.
[36] Mohammad Jafri N N,Jaafar J,Alias N H,et al.Synthesis and characterization of titanium dioxide hollow nanofiber for photocatalytic degradation of methylene blue dye[J].Membranes,2021,11(8):581.
[37] Shi H,Fu J,Jiang W,et al.Construction of g-C3N4/Bi4Ti3O12 hollow nanofibers with highly efficient visible-light-driven photocatalytic performance[J].Colloids and Surfaces A:Physicochemical and Engineering Aspects,2021,615:126063.
[38] Huang W Y,Hashimoto N,Kitai R,et al.Nanofiber-Mâché hollow ball mimicking the three-dimensional structure of a cyst[J].Polymers(Basel),2021,13(14):2273.
[39] Bhattarai D P,Tiwari A P,Maharjan B,et al.Sacrificial template-based synthetic approach of polypyrrole hollow fibers for photothermal therapy[J].Journal of Colloid and Interface Science,2019,534:447-458.
[40] Zhao T,Zheng Y,Zhang X,et al.Design of helical groove/hollow nanofibers via tri-fluid electrospinning[J].Materials & Design,2021,205:109705.
[41] 王桂平,喻伯鸣,敖日格勒.木质素基磁性多孔复合纳米碳纤维的制备及微波吸收性能[J].材料导报,2020,34(20):20159-20164.
[42] Liu Y,Ma Q,Yang M,et al.Flexible hollow nanofibers:novel one-pot electrospinning construction,structure and tunable luminescence-electricity-magnetism trifunctionality[J].Chemical Engineering Journal,2016,284:831-840.
基金资助
国家自然科学基金面上项目(51603144)