具有多重优异性能的石墨烯已经成为推动新经济、新业态下的革命性新材料,石墨烯柔性膜材料作为石墨烯基材料的一种重要表现形式,在光伏发电、能源储备、电磁屏蔽、抗菌消毒等领域有着广泛的应用前景,也成为研究的重点。针对目前石墨烯基柔性膜材料的制备方法、应用机理和应用范畴进行综述,并分析当下所面临的主要问题及其发展前景。
Graphene with multiple excellent properties has become a revolutionary new material to promote new economy and new industry.As an important manifestation of graphene-based materials,graphene flexible membrane material has a wide application prospect in photovoltaic power generation,energy storage,electromagnetic shielding,anti-bacterial and other fields,which has also become a research focus.This article reviewed the preparation methods,application mechanism and application scope,and analyzed the main problems faced at present and development prospects.
[1] Aunkor M T H,Mahbubul I M,Saidur R,et al.The green reduction of graphene oxide[J].RSC Advances,2016,6(33):27807-27828.
[2] Torres Alonso E,Rodrigues D P,Khetani M,et al.Graphene electronic fibres with touch-sensing and light-emitting functionalities for smart textiles[J].NPJ Flexible Electronics,2018,2(1):25.
[3] Yu J,Wang M,Xu P,et al.Ultrahigh-rate wire-shaped supercapacitor based on graphene fiber[J].Carbon,2017,119:332-338.
[4] 郑贤宏,胡侨乐,聂文琪,等.纤维状柔性超级电容器的研究进展[J].精细化工,2021,38(12):2393-2403.
[5] Han G,Ma Z,Zhou B,et al.Cellulose-based Ni-decorated graphene magnetic film for electromagnetic interference shielding[J].Journal of Colloid and Interface Science,2021,583:571-578.
[6] Meng F,Lu W,Li Q,et al.Graphene-based fibers:a review[J].Advanced Materials,2015,27(35):5113-5131.
[7] Castro Neto A H,Guinea F,Peres N M R,et al.The electronic properties of graphene[J].Reviews of Modern Physics,2009,81(1):109-162.
[8] Lerf A,He H,Forster M,et al.Structure of graphite oxide revisited[J].Journal of Physical Chemistry B,1998,102:4477-4482.
[9] 吴思达.石墨烯基薄膜的气液界面自组装制备及应用研究[D].天津:天津大学,2014.
[10] Immanuel S,Sivasubramanian R.Electrochemical reduction of NAD+ on graphene oxide and chemically reduced graphene oxide nanosheets[J].Materials Science and Engineering:B,2020,262:114705.
[11] Park S,Dikin D A,Nguyen S T,et al.Graphene oxide sheets chemically cross-linked by polyallylamine[J].The Journal of Physical Chemistry C,2009,113(36):15801-15804.
[12] Zheng Y,Yin X,Zhang S.Activity enhancement in photocatalytic reduction of CO2 over nano-ZnO anchored on graphene[J].Water,Air,& Soil Pollution,2018,229(8):262.
[13] De Silva K K H,Huang H H,Joshi R K,et al.Chemical reduction of graphene oxide using green reductants[J].Carbon,2017,119:190-199.
[14] Fang X,Fan Z,Gu Y,et al.A solution processable flexible transparent conductive graphene/PEDOT∶ PSS film fabricated by spin and blade coating[J].Journal of Shanghai Jiaotong University (Science),2018,23(1):106-111.
[15] Kobayashi T,Bando M,Kimura N,et al.Production of a 100-m-long high-quality graphene transparent conductive film by roll-to-roll chemical vapor deposition and transfer process[J].Applied Physics Letters,2013,102(2):023112.
[16] Wågberg L,Erlandsson J.The use of layer-by-layer self-assembly and nanocellulose to prepare advanced functional materials[J].Advanced Materials,2021,33(28):2001474.
[17] Velasco-Hernández A,Esparza-Muñoz R A,de Moure-Flores F J,et al.Synthesis and characterization of graphene oxide-TiO2 thin films by sol-gel for photocatalytic applications[J].Materials Science in Semiconductor Processing,2020,114:105082.
[18] Khosravi M,Seyfi J,Saeidi A,et al.Spin-coated polyvinylidene fluoride/graphene nanocomposite thin films with improved β-phase content and electrical conductivity[J].Journal of Materials Science,2020,55(15):6696-6707.
[19] Chamoli P,Das M K,Kar K K.Urea-assisted low temperature green synthesis of graphene nanosheets for transparent conducting film[J].Journal of Physics and Chemistry of Solids,2018,113:17-25.
[20] Lee H J,Song Y S,An T K,et al.Ultrasmooth transparent conductive hybrid films of reduced graphene oxide and single-walled carbon nanotube by ultrasonic spraying[J].Synthetic Metals,2016,221:340-344.
[21] Li X,Cai W,An J,et al.Large-area synthesis of high-quality and uniform graphene films on copper foils[J].Science,2009,324(5932):1312-1314.
[22] Xin S,Yang N,Gao F,et al.Free-standing and flexible polypyrrole nanotube/reduced graphene oxide hybrid film with promising thermoelectric performance[J].Materials Chemistry and Physics,2018,212:440-445.
[23] Luo H,Xu C,Wang B,et al.Highly conductive graphene-modified TiO2 hierarchical film electrode for flexible Li-ion battery anode[J].Electrochimica Acta,2019,313:10-19.
[24] Li X,Zhang G,Bai X,et al.Highly conducting graphene sheets and Langmuir-Blodgett films[J].Nature Nanotechnology,2008,3(9):538-542.
[25] Yang T,Yang J,Shi L,et al.Highly flexible transparent conductive graphene/single-walled carbon nanotube nanocomposite films produced by Langmuir-Blodgett assembly[J].RSC Advances,2015,5(30):23650-23657.
[26] Bae S,Kim H,Lee Y,et al.Roll-to-roll production of 30-inch graphene films for transparent electrodes[J].Nature Nanotechnology,2010,5(8):574-578.
[27] Zhu J,Cao Y,He J.Facile fabrication of transparent,broadband photoresponse,self-cleaning multifunctional graphene-TiO2 hybrid films[J].Journal of Colloid and Interface Science,2014,420:119-126.
[28] Wu B,He W,Lu M,et al.Fabrication and electrochemical properties of flexible transparent supercapacitor electrode materials based on cellulose nanofibrils and reduced graphene oxide[J].Polymer Composites,2020,41(3):1135-1144.
[29] Bae S Y,Jeon I Y,Yang J,et al.Large-area graphene films by simple solution casting of edge-selectively functionalized graphite[J].ACS Nano,2011,5(6):4974-4980.
[30] Dong B,Zhang L,Wu Y.Highly conductive natural rubber-graphene hybrid films prepared by solution casting and in situ reduction for solvent-sensing application[J].Journal of Materials Science,2016,51(23):10561-10573.
[31] Hemasiri B W N H,Kim J K,Lee J M.Fabrication of highly conductive graphene/ITO transparent bi-film through CVD and organic additives-free sol-gel techniques[J].Scientific Reports,2017,7(1):17868.
[32] Yu J,Wang M,Xu P,et al.Ultrahigh-rate wire-shaped supercapacitor based on graphene fiber[J].Carbon,2017,119:332-338.
[33] Zhu Y,Ye X,Tang Z,et al.Free-standing graphene films prepared via foam film method for great capacitive flexible supercapacitors[J].Applied Surface Science,2017,422:975-984.
[34] Sevilla M,Ferrero G A,Fuertes A B.Graphene-cellulose tissue composites for high power supercapacitors[J].Energy Storage Materials,2016,5:33-42.
[35] Wan X,Lu H,Kang J,et al.Preparation of graphene-glass fiber-resin composites and its electromagnetic shielding performance[J].Composite Interfaces,2018,25(10):883-900.
[36] Han G,Ma Z,Zhou B,et al.Cellulose-based Ni-decorated graphene magnetic film for electromagnetic interference shielding[J].Journal of Colloid and Interface Science,2021,583:571-578.
[37] Xu L,Lu H,Zhou Y,et al.Ultrathin,ultralight,and anisotropic ordered reduced graphene oxide fiber electromagnetic interference shielding membrane[J].Advanced Materials Technologies,2021:2100531.
[38] Pan N,Wei Y,Zuo M,et al.Antibacterial poly (ε-caprolactone) fibrous membranes filled with reduced graphene oxide-silver[J].Colloids and Surfaces A:Physicochemical and Engineering Aspects,2020,603:125186.
[39] Dasari M,Hautzinger M P,Fan-Hagenstein H,et al.Large area ultra-thin graphene films for functional photovoltaic devices[J].Journal of Materials Research,2018,33(16):2306-2317.
[40] Tugba Camic B,Oytun F,Hasan Aslan M,et al.Fabrication of a transparent conducting electrode based on graphene/silver nanowires via layer-by-layer method for organic photovoltaic devices[J].Journal of Colloid and Interface Science,2017,505:79-86.
[41] Torres Alonso E,Rodrigues D P,Khetani M,et al.Graphene electronic fibres with touch-sensing and light-emitting functionalities for smart textiles[J].NPJ Flexible Electronics,2018,2(1):25.
[42] Ren H,Zheng L,Wang G,et al.Transfer-medium-free nanofiber-reinforced graphene film and applications in wearable transparent pressure sensors[J].ACS Nano,2019,13(5):5541-5548.
基金资助
浙江省自然科学基金青年基金项目(LQ18E030006);上海工程技术大学产学研项目((19)FZ-015)
PDF
