Titanium dioxide mesocrystal,as a new type of semiconductor material,is three-dimensional ordered aggregate formed by oriented self-assembly of primary nanocrystal.Because of its unique crystallization method,its properties are different from those of traditional TiO2 materials.The morphology and structure of TiO2 mesocrystal obtained by the same synthesis method are quite different,and the properties and applications of TiO2 mesocrystal with the same morphology and structure are also very different.This article outlined the formation mechanism of mesocrystal briefly and summarized the preparation methods of TiO2 mesocrystal,such as water/solvothermal method,topological transformation method,inverse microemulsion method,etc.,as well as the photocatalytic and electrocatalytic performance of prepared TiO2 mesocrystal.Finally,the application prospects and research directions of TiO2 were discussed.
[1] 张业.纳米材料的电化学制备及其应用[J].环境工程,2011,29(3):128-130.
[2] 杨忆新,马军,秦庆东.臭氧/纳米TiO2催化氧化去除水中微量硝基苯的研究[J].环境科学,2006,27(10):2028-2034.
[3] 李勇.纳米二氧化钛负极材料的制备及其电化学性能研究[D].北京:清华大学,2017.
[4] 孙健武,葛美英,尹桂林,等.介晶半导体材料的合成及应用研究进展[J].材料导报(A),2019,33:1119-1124.
[5] Hong Z,Wei M,Lan T,et al.Additive-free synthesis of unique TiO2 mesocrystals with enhanced lithium-ion intercalation properties[J].Energy Environ Sci,2012,5(1):5408-5413.
[6] Colfen H,Antonietti M.Mesocrystals:inorganic superstructures made by highly parallel crystallization and controlled alignment[J].Angew Chem Int Ed,2005,35(44):5576-5591.
[7] 陈其凤,马闻辛,许芳,等.半导体介晶综述[J].济南大学学报,2015,29(1):55-68.
[8] Zhou L,O'Brien P.Mesocrystals:a new class of solid materials[J].Small,2008,4(10):1566-1574.
[9] Song R Q,Colfen H.Mesocrystals-ordered nanoparticle superstructures[J].Adv Mater,2010,22(12):1301-1330.
[10] Bian Z,Tachikawa T,Majima T.Superstructure of TiO2 crystalline nanoparticles yields effective conduction pathways for photogenerated charges[J].J Phys Chem Lett,2012,3(11):1422-1427.
[11] 付欣欣.纳米结构二氧化钛的可控自组装及其性能研究[D].杭州:浙江大学,2016.
[12] Yang D D,Zhang W X,Wang Y,et al.Formation mechanisms and electrical properties of perovskite mesocrystals[J].Ceramics International,2021,47:1479-1512.
[13] Cao S,Du M,Li Y,et al.Nanosized carbonate-doped TiO2-x mesocrystals for visible-light-driven photocatalytic removal of water pollutants[J].ACS Applied Nano Materials,2020,3(5):4197-4208.
[14] 焦世龙.高压溶剂热体系中TiO2微尺度的调控、组装、晶体生长以及性能研究[D].济南:山东大学,2017.
[15] Zhang W,Shen D,Liu Z.Brookite TiO2 mesocrystals with enhanced lithium-ion intercalation properties[J].Chem Commun,2018,81:1-3.
[16] Guo M H,Shen D L,Wei M D,et al.TiO2 mesocrystals processed at low-temperature as the electron-transport material in perovskite solar cells[J].ChemSusChem,2020,13(19):5256-5263.
[17] Tan B Y,Zhang X H,Li Y J,et al.Anatase TiO2 mesocrystals:green synthesis,in situ conversion to porous single crystals,and self-doping Ti3+ for enhanced visible light driven photocatalytic removal of NO[J].Chemistry,2017,23(23):5478-5487.
[18] Li Y J,Ye X Z,Cao S X,et al.Oxygen-deficient dumbbell-shaped anatase TiO2-x mesocrystals with nearly 100% exposed {101} facets:synthesis,growth mechanism,and photocatalytic performance[J].Chem Eur J,2019,25(12):3032-3041.
[19] 卜凡兴,都晨杰,姜继森.介晶的制备、性能与应用研究[J].化学进展,2014,26(1):75-86.
[20] Murakami Y,Kamegawa T,Kobori Y.TiO2 superstructures with oriented nanospaces:a strategy for efficient and selective photocatalysis[J].Nanoscale,2020,17:2-8.
[21] Zhou L,Boyle D S,O'Brien P.A facile synthesis of uniform NH4TiOF3 mesocrystals and their conversion to TiO2 mesocrystals[J].J Am Chem Soc,2008,130:1309-1320.
[22] Zhou L,Boyle D S,O'Brien P.Uniform NH4TiOF3 mesocrystals prepared by an ambient temperature self-assembly process and their topotaxial conversion to anatase[J].Chem Commun (Camb),2007(2):144-146.
[23] 施利毅,华彬,张剑平.微乳液的结构及其在制备超细颗粒中的应用[J].功能材料,1998,29(2):136-139.
[24] 丁海云.可用于化学修饰电极的金属及其化合物的纳米材料合成研究进展[J].湿法冶金,2018,37(3):173-178.
[25] Tartaj P.Sub-100 nm TiO2 mesocrystalline assemblies with mesopores:preparation,characterization,enzyme immobilization and photocatalytic properties[J].Chem Commun (Camb),2011,47(1):256-258.
[26] Tartaj P,Amarilla J M.Multifunctional response of anatase nanostructures based on 25 nm mesocrystal-like porous assemblies[J].Adv Mater,2014,23(42):4904-4907.
[27] 谭必英.锐钛矿TiO2介晶的合成、改性及其可见光催化性能研究[D].武汉:华中农业大学,2017.
[28] Aoyama Y,Oaki Y Y,Ise R,et al.Mesocrystal nanosheet of rutile TiO2 and its reaction selectivity as a photocatalyst[J].CrystEngComm,2012,14(4):1405-1411.
[29] Qi H P,Wang H L,Zhao D Y,et al.Synthesis of novel magnetic superstructure TiO2 mesocrystal composites with enhanced visible-light photocatalytic activity[J].Mater Res Bull,2019,118:110516.
[30] Yao X X,Liu X H,Liu T Y,et al.One-step and large-scale synthesis of anatase TiO2 mesocrystals along [001] orientation with enhanced photocatalytic performance[J].CrystEngComm,2013,15(47):10246.
[31] Hong Z S,Xu Y X,Liu Y B,et al.Unique ordered TiO2 superstructures with tunable morphology and crystalline phase for improved lithium storage properties[J].Chemistry,2012,18(34):10753-10760.
[32] Lan T B,Tu J X,Zou Q M,et al.Synthesis of anatase TiO2 mesocrystals with highly exposed low-index facets for enhanced electrochemical performance[J].Electrochimica Acta,2019,319:101-109.
基金资助
国家自然科学基金(51508353,21676027);北京市属高校高水平教师队伍建设支持计划高水平创新团队建设计划项目(IDHT20180508)