A composite coating with super-hydrophobicity and low infrared emissivity was prepared by glass rod scraping method using flake Al powders,nano-SiO2 and polydimethylsiloxane (PDMS) modified epoxy resin (HYSZ) as functional pigments,micro-nano structural modifier and adhesive,respectively.The effects of the mass ratio of PDMS to HYSZ,the total filler addition and the mass ratio of flake Al powder to nano-SiO2 on the coating properties were systematically investigated.The results showed that the mass ratio of PDMS to HYSZ had an important influence on the adhesion strength and hydrophobic properties of the coating.When the mass ratio was 1∶9,the coating had good hydrophobic properties and its adhesion strength could reach grade 1.The total filler addition had an obvious impact on the coating performance.With the increase of the total filler addition,the emissivity and the glossiness of the coating could be significantly reduced.When the total filler addition was 50%,the coating surface produced obvious papillary micro-nano rough structure,which could significantly improve the hydrophobic performance of the coating.The mass ratio of flake Al powder to nano-SiO2 could obviously affect the emissivity and hydrophobic properties of the coating.When the mass ratio was 5∶5,the coating had good overall performance.At this time,the emissivity of the coating was as low as 0.652;the glossiness and adhesion strength were 2.7 and grade 1,respectively;the water contact angle and sliding angle were 152° and 8°,respectively.By appropriately reducing the surface energy of the coating and building a micro-nano rough structure on the surface of the coating,the super-hydrophobicity,low emissivity and high adhesion strength compatibility of the coating could be achieved.
[1] Fang S J,Wang W,Yu X L,et al.Preparation of ZnO∶(Al,La)/polyacrylonitrile (PAN) nonwovens with low infrared emissivity via electrospinning[J].Materials Letter,2015,143:120-123.
[2] Solovyev A A,Rabotkin S V,Kovsharov N F.Polymer films with multilayer low-E coatings[J].Materials Science in Semiconductor Processing,2015,38:373-380.
[3] Wang L,Xu G Y,Liu C Y,et al.Surface-modified CeO2 coating with excellent thermal shock resistance performance and low infrared emissivity at high-temperature[J].Surface and Coatings Technology,2019,357:559-566.
[4] Mao Z P,Yu X L,Zhang L P,et al.Novel infrared stealth property of cotton fabrics coated with nano ZnO∶(Al,La) particles[J].Vacuum,2014,104:111-115.
[5] Liu Z H,Ban G D,Ye S T,et al.Infrared emissivity properties of infrared stealth coatings prepared by water-based technologies[J].Optical Materials Express,2016,6:3716-3724.
[6] Guo T C,Xu G Y,Tan S J,et al.Controllable synthesis of ZnO with different morphologies and their morphology-dependent infrared emissivity in high temperature conditions[J].Journal of Alloys and Compounds,2019,804:503-510.
[7] Zhang W G,Lv D D.Preparation and characterization of Ge/TiO2 one-dimensional photonic crystal with low infrared emissivity in the 8-14μm band[J].Materials Research Bulletin,2020,124:110747.
[8] Qi L,Weng X L,Yuan L,et al.Improved thermal expansion performance of Aluminum/polysiloxane/glass coatings with low infrared emissivity by zinc powder[J].Infrared Physics & Technology,2020,110:103458.
[9] Hu C,Xu G Y,Shen X M,et al.The epoxy-siloxane/Al composite coatings with low infrared emissivity for high temperature applications[J].Applied Surface Science,2010,256:3459-3463.
[10] Yan X X,Xu G Y.Corrosion and mechanical properties of epoxy-polyurethane/bronze composite coatings with low infrared emissivity[J].Surface & Coatings Technology,2010,205:2307-2312.
[11] He L H,Zhao Y,Xing L Y,et al.Low infrared emissivity coating based on graphene surface-modified flaky aluminum[J].Materials,2018,11:1502.
[12] Liu Z H,Ban G D,Ye S T,et al.Infrared emissivity properties of infrared stealth coatings prepared by water-based technologies[J].Optical Materials Express,2016,6(12):3716-3724.
[13] Wang K Z,Wang C X,Yin Y J,et al.Modification of Al pigment with graphene for infrared/visual stealth compatible fabric coating[J].Journal of Alloys and Compounds,2017,690:741-748.
[14] Wu G W,Yu D M.Preparation and characterization of a new low infrared-emissivity coating based on modified aluminum[J].Progress in Organic Coatings,2013,76:107-112.
[15] Fantucci S,Serra V.Investigating the performance of reflective insulation and low emissivity paints for the energy retrofit of roof attics[J].Energy and Buildings,2019,182:300-310.
[16] Chen Y P,Xu G Y,Guo T C,et al.Infrared emissivity and microwave absorbing property of epoxy-polyurethane/annealed carbonyl iron composites coatings[J].Science China Technological Science,2012,55(3):623-628.
[17] Pawar P G,Xing R M,Kambale R C,et al.Polystyrene assisted superhydrophobic silica coatings with surface protection and self-cleaning approach[J].Progress in Organic Coatings,2017,105:235-244.
[18] Satapathy M,Varshney P,Nanda D,et al.Fabrication of durable porous and non-porous superhydrophobic LLDPE/SiO2 nanoparticles coatings with excellent self-cleaning property[J].Surface & Coatings Technology,2018,341:31-39.
[19] Li C L,Sun Y C,Cheng M,et al.Fabrication and characterization of a TiO2/polysiloxane resin composite coating with full-thickness super-hydrophobicity[J].Chemical Engineering Journal,2018,333:361-369.
[20] Liu Y,LI S,Zhang J,et al.Fabrication of biomimetic superhydrophobic surface with controlled adhesion by electrodeposition[J].Chemical Engineering Journal,2014,248:440-447.
[21] Wang Z,Shen X P,Yan Y T,et al.Facile fabrication of a PDMS@stearic acid-Al(OH)3 coating on lignocellulose composite with superhydrophobicity and flame retardancy[J].Applied Surface Science,2018,450:387-395.
[22] 郭永刚,耿铁,吴海宏,等.聚合物/疏水性SiO2超疏水复合涂层的制备及表征[J].材料研究学报,2013,27(4):439-443.
[23] 侯俊文,蔡东宝,叶向东.一种具有自粘附性能的超疏水自清洁涂层制备方法[J].表面技术,2019,48(2):69-75.
[24] Zhong M Z,Zhang Y,Li X Q,et al.Facile fabrication of durable superhydrophobic silica/epoxy resin coatings with compatible transparency and stability[J].Surface & Coating Technology,2018,347:191-198.
[25] Zhang W G,Xu G Y,Ding R Y,et al.Nacre biomimetic design--a possible approach to prepare low infrared emissivity composite coatings[J].Materials Science and Engineering C,2013,33:99-102.
基金资助
国家自然科学基金(61705029);安徽省高校优秀青年人才支持计划重点项目(gxyqZD2020044);安徽省自然科学基金项目(1808085MF187);安徽省科技重大专项(202103a05020018);滁州学院大学生创新训练计划项目(2021CXXL087)