超疏水低发射率PDMS改性环氧树脂/Al复合涂层的制备及性能表征

张伟钢, 薛瑞, 吕丹丹

化工新型材料 ›› 2023, Vol. 51 ›› Issue (4) : 202 -207.

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化工新型材料 ›› 2023, Vol. 51 ›› Issue (4) : 202-207. DOI: 10.19817/j.cnki.issn1006-3536.2023.04.036
科学研究

超疏水低发射率PDMS改性环氧树脂/Al复合涂层的制备及性能表征

    张伟钢, 薛瑞, 吕丹丹
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Preparation and characterization of PDMS modified epoxy resin/Al composite coating with super-hydrophobicity and low emissivity

  • Zhang Weigang, Xue Rui, Lv Dandan
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摘要

以片状Al粉为功能颜料,纳米SiO2为微纳结构改性剂,聚二甲基硅氧烷(PDMS)改性环氧树脂(HYSZ)为黏合剂,采用简单的玻璃棒刮涂法制备了一种同时具有超疏水和低红外发射率性能的复合涂层。探讨了PDMS和HYSZ质量比、总填料添加量及片状Al粉和纳米SiO2质量比对涂层性能的影响规律。结果表明:PDMS和HYSZ质量比对涂层附着力和疏水性能具有重要影响,当质量比为1∶9时,涂层具备良好的疏水性能,其附着力可达1级。总填料添加量对涂层性能影响明显,随着总填料添加量的增加,涂层发射率和光泽度可明显降低。当总填料添加量为50%时,涂层表面可产生明显的乳突状微纳粗糙结构,从而可明显提升涂层的疏水性能。片状Al粉和纳米SiO2质量比会明显影响涂层的发射率和疏水性能,当质量比为5∶5时,涂层可具备良好的综合性能。此时涂层发射率可低至0.652,光泽度和附着力分别为2.7和1级,水接触角和滚动角分别为152°和8°。通过适当降低涂层表面能及在涂层表面构筑微纳粗糙结构可实现涂层超疏水、低发射率和高附着力的兼容。

Abstract

A composite coating with super-hydrophobicity and low infrared emissivity was prepared by glass rod scraping method using flake Al powders,nano-SiO2 and polydimethylsiloxane (PDMS) modified epoxy resin (HYSZ) as functional pigments,micro-nano structural modifier and adhesive,respectively.The effects of the mass ratio of PDMS to HYSZ,the total filler addition and the mass ratio of flake Al powder to nano-SiO2 on the coating properties were systematically investigated.The results showed that the mass ratio of PDMS to HYSZ had an important influence on the adhesion strength and hydrophobic properties of the coating.When the mass ratio was 1∶9,the coating had good hydrophobic properties and its adhesion strength could reach grade 1.The total filler addition had an obvious impact on the coating performance.With the increase of the total filler addition,the emissivity and the glossiness of the coating could be significantly reduced.When the total filler addition was 50%,the coating surface produced obvious papillary micro-nano rough structure,which could significantly improve the hydrophobic performance of the coating.The mass ratio of flake Al powder to nano-SiO2 could obviously affect the emissivity and hydrophobic properties of the coating.When the mass ratio was 5∶5,the coating had good overall performance.At this time,the emissivity of the coating was as low as 0.652;the glossiness and adhesion strength were 2.7 and grade 1,respectively;the water contact angle and sliding angle were 152° and 8°,respectively.By appropriately reducing the surface energy of the coating and building a micro-nano rough structure on the surface of the coating,the super-hydrophobicity,low emissivity and high adhesion strength compatibility of the coating could be achieved.

关键词

复合涂层 / 低红外发射率 / 超疏水 / 附着力 / 光泽度

Key words

composite coating / low infrared emissivity / super-hydrophobic / adhesion strength / glossiness

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超疏水低发射率PDMS改性环氧树脂/Al复合涂层的制备及性能表征[J]. 化工新型材料, 2023, 51(4): 202-207 DOI:10.19817/j.cnki.issn1006-3536.2023.04.036

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基金资助

国家自然科学基金(61705029);安徽省高校优秀青年人才支持计划重点项目(gxyqZD2020044);安徽省自然科学基金项目(1808085MF187);安徽省科技重大专项(202103a05020018);滁州学院大学生创新训练计划项目(2021CXXL087)

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