随着人们对于能源需求量的增加,染料敏化太阳能电池作为一种清洁的能量收集装置得到广泛研究。染料敏化太阳能电池是通过染料来获得光电子,利用自身的氧化还原产生电流,但由于光阳极材料的比表面积和电子传输速率提升困难等因素,在实际应用中受到限制。总结了染料敏化太阳能电池的结构和工作原理和研究进展,对它们的优缺点进行分析,提出染料敏化太阳能电池发展中存在的问题和挑战,并对染料敏化太阳能电池光阳极的趋势进行了展望。
With the increase of people's demand for energy,dye-sensitized solar cells,as clean energy collection devices,have been widely studied.Dye-sensitized solar cells obtain photoelectrons through dyes and generate electric current by their own redox processes.However,due to difficulties in improving the specific surface area and the electron transfer rate of photoanode materials,they are limited in practical applications.In this paper,the structure,working principle and research progress of dye-sensitized solar cells were summarized,their advantages and disadvantages were analyzed,the existing problems and challenges in the development of dye-sensitized solar cells were put forward,and the research trend of dye-sensitized solar cells photoanode was prospected.
[1] Birel Ö,Nadeem S,Duman H.Porphyrin-based dye-sensitized solar cells (DSSCs):a review[J].Journal of Fluorescence,2017,27(3):1075-1085.
[2] Wang H M,Wang G Q,Qi J C,et al.Scarcity-weighted fossil fuel footprint of China at the provincial level[J].Applied Energy,2020,258:114081.
[3] Höök M,Tang X.Depletion of fossil fuels and anthropogenic climate change—a review[J].Energy Policy,2013,52:797-809.
[4] Valentine S V.Emerging symbiosis:renewable energy and energy security[J].Renewable and Sustainable Energy Reviews,2011,15(9):4572-4578.
[5] Kumavat P P,Sonar P,Dalal D S.An overview on basics of organic and dye sensitized solar cells,their mechanism and recent improvements[J].Renewable and Sustainable Energy Reviews,2017,78:1262-1287.
[6] 刘家森,陈秀华,李绍元,等.石墨烯/硅肖特基结太阳能电池的研究进展[J].材料导报,2021,35(9):9115-9122.
[7] Wu J H,Lan Z,Lin J M,et al.Electrolytes in dye-sensitized solar cells[J].Chemical Reviews,2015,115(5):2136-2173.
[8] Sharma K,Sharma V,Sharma S S.Dye-sensitized solar cells:fundamentals and current status[J].Nanoscale Research Letters,2018,13(1):1-46.
[9] Yahya M,Bouziani A,Ocak C,et al.Organic/metal-organic photosensitizers for dye-sensitized solar cells (DSSC):recent developments,new trends,and future perceptions[J].Dyes and Pigments,2021,192:109227.
[10] Al-Alwani M A M,Mohamad A B,Ludin N A,et al.Dye-sensitised solar cells:development,structure,operation principles,electron kinetics,characterisation,synthesis materials and natural photosensitisers[J].Renewable and Sustainable Energy Reviews,2016,65:183-213.
[11] Devadiga D,Selvakumar M,Shetty P,et al.The integration of flexible dye-sensitized solar cells and storage devices towards wearable self-charging power systems:a review[J].Renewable and Sustainable Energy Reviews,2022,159:112252.
[12] Dwivedi G,Munjal G,Bhaskarwar A N,et al.Dye-sensitized solar cells with polyaniline:a review[J].Inorganic Chemistry Communications,2022,135:109087.
[13] Hagfeldt A,Boschloo G,Sun L,et al.Dye-sensitized solar cells[J].Chemical reviews,2010,110(11):6595-6663.
[14] Sugathan V,John E,Sudhakar K.Recent improvements in dye sensitized solar cells:a review[J].Renewable and Sustainable Energy Reviews,2015,52:54-64.
[15] Mariotti N,Bonomo M,Fagiolari L,et al.Recent advances in eco-friendly and cost-effective materials towards sustainable dye-sensitized solar cells[J].Green Chemistry,2020,22(21):7168-7218.
[16] Khan M Z H,Al-Mamun M R,Halder P K,et al.Performance improvement of modified dye-sensitized solar cells[J].Renewable and Sustainable Energy Reviews,2017,71:602-617.
[17] Tomar N,Agrawal A,Dhaka V S,et al.Ruthenium complexes based dye sensitized solar cells:fundamentals and research trends[J].Solar Energy,2020,207:59-76.
[18] Ahmad T,Guria C,Mandal A.Synthesis,characterization and performance studies of mixed-matrix poly(vinyl chloride)-bentonite ultrafiltration membrane for the treatment of saline oily wastewater[J].Process Safety and Environmental Protection,2018,116:703-717.
[19] 庞亚帅.染料敏化太阳能电池新型光阳极的制备及其光电性能研究[D].郑州:河南大学,2019.
[20] Najafabadi H A,Fattahi A R,Asemi M,et al.Performance enhancement of dye-sensitized solar cells by plasma treatment of BaSnO3 photoanode[J].Journal of Alloys and Compounds,2020,818:152856.
[21] O'regan B,Grätzel M.A low-cost,high-efficiency solar cell based on dye-sensitized colloidal TiO2 films[J].Nature,1991,353(6346):737-740.
[22] Ikpesu J E,Iyuke S E,Daramola M,et al.Synthesis of improved dye-sensitized solar cell for renewable energy power generation[J].Solar Energy,2020,206:918-934.
[23] Sharma D,Jha R,Kumar S.Quantum dot sensitized solar cell:recent advances and future perspectives in photoanode[J].Solar Energy Materials and Solar Cells,2016,155:294-322.
[24] Parisi M L,Maranghi S,Basosi R.The evolution of the dye sensitized solar cells from Grätzel prototype to up-scaled solar applications:a life cycle assessment approach[J].Renewable and Sustainable Energy Reviews,2014,39:124-138.
[25] De Marco L,Calestani D,Qualtieri A,et al.Single crystal mesoporous ZnO platelets as efficient photoanodes for sensitized solar cells[J].Solar Energy Materials and Solar Cells,2017,168:227-233.
[26] 冯诗乐,黄梦玲,施玮,等.Zn掺杂TiO2光阳极对染料敏化太阳电池性能影响[J].陶瓷学报,2019,40(1):18-23.
[27] Tributsch H.Dye sensitization solar cells:a critical assessment of the learning curve[J].Coordination Chemistry Reviews,2004,248(13-14):1511-1530.
[28] Raj C C,Prasanth R.A critical review of recent developments in nanomaterials for photoelectrodes in dye sensitized solar cells[J].Journal of Power Sources,2016,317:120-132.
[29] Hu Q,Wu C,Cao L,et al.A novel TiO2 nanowires/nanoparticles composite photoanode with SrO shell coating for high performance dye-sensitized solar cell[J].Journal of Power Sources,2013,226:8-15.
[30] Dissanayake M,Kumari J,Senadeera G K R,et al.Low cost,platinum free counter electrode with reduced graphene oxide and polyaniline embedded SnO2 for efficient dye sensitized solar cells[J].Solar Energy,2021,230:151-165.
[31] Ou J Z,Rani R A,Ham M H,et al.Elevated temperature anodized Nb2O5:a photoanode material with exceptionally large photoconversion efficiencies[J].ACS Nano,2012,6(5):4045-4053.
[32] Liu W,Hong C,Wang H,et al.Enhanced photovoltaic performance of fully flexible dye-sensitized solar cells based on the Nb2O5 coated hierarchical TiO2 nanowire-nanosheet arrays[J].Applied Surface Science,2016,364:676-685.
[33] Nath N C D,Choi S Y,Jeong H W,et al.Stand-alone photoconversion of carbon dioxide on copper oxide wire arrays powered by tungsten trioxide/dye-sensitized solar cell dual absorbers[J].Nano Energy,2016,25:51-59.
[34] Nikhil S K,Das A,Bhagavathiachari M,et al.Effect of aspect ratio of c-axis oriented ZnO nanorods on photoelectrochemical performance and photoconversion efficiency[J].Optical Materials,2021,121:111551.
[35] Fukuda K,Yu K,Someya T.The future of flexible organic solar cells[J].Advanced Energy Materials,2020,10(25):2000765.
[36] Zhang Y,Cao X,Cui Y,et al.Enhanced light harvest in dye-sensitized solar cells by nanocrystals-on-microcrystals TiO2 photoanode[J].Materials Research Express,2019,6(12):125523.
[37] Gupta A,Sahu K,Dhonde M,et al.Novel synergistic combination of Cu/S co-doped TiO2 nanoparticles incorporated as photoanode in dye sensitized solar cell[J].Solar Energy,2020,203:296-303.
[38] Boro B,Gogoi B,Rajbongshi B M,et al.Nano-structured TiO2/ZnO nanocomposite for dye-sensitized solar cells application:a review[J].Renewable and Sustainable Energy Reviews,2018,81:2264-2270.
[39] Ye M,Wen X,Wang M,et al.Recent advances in dye-sensitized solar cells:from photoanodes,sensitizers and electrolytes to counter electrodes[J].Materials Today,2015,18(3):155-162.
[40] Ning F,Shao M,Xu S,et al.TiO2/graphene/NiFe-layered double hydroxide nanorod array photoanodes for efficient photoelectrochemical water splitting[J].Energy & Environmental Science,2016,9(8):2633-2643.
[41] Kathirvel S,Pedaballi S,Su C,et al.Morphological control of TiO2 nanocrystals by solvothermal synthesis for dye-sensitized solar cell applications[J].Applied Surface Science,2020,519:146082.
[42] Ramakrishang V M,Pitchaiya S,Muthukumarasamy N,et al.Performance of TiO2 nanoparticles synthesized by microwave and solvothermal methods as photoanode in dye-sensitized solar cells (DSSC)[J].International Journal of Hydrogen Energy,2020,45(51):27036-27046.
[43] Murakami T,Abe T.Novel and promising preparation of an efficient hematite photoanode for oxygen evolution reaction[J].International Journal of Electrochemical Science,2020,15:7381-7389.
[44] Bhatt M D,Lee J S.Recent theoretical progress in the development of photoanode materials for solar water splitting photoelectrochemical cells[J].Journal of Materials Chemistry A,2015,3(20):10632-10659.
[45] Bahramian A.High conversion efficiency of dye-sensitized solar cells based on coral-like TiO2 nanostructured films:synthesis and physical characterization[J].Industrial & Engineering Chemistry Research,2013,52(42):14837-14846.
[46] Ahmad M S,Pandey A K,Abd Rahim N.Advancements in the development of TiO2 photoanodes and its fabrication methods for dye sensitized solar cell (DSSC) applications.a review[J].Renewable and Sustainable Energy Reviews,2017,77:89-108.
[47] Babar F,Mehmood U,Asghar H,et al.Nanostructured photoanode materials and their deposition methods for efficient and economical third generation dye-sensitized solar cells:a comprehensive review[J].Renewable and Sustainable Energy Reviews,2020,129:109919.
[48] Yang M,Kim D,Jha H,et al.Nb doping of TiO2 nanotubes for an enhanced efficiency of dye-sensitized solar cells[J].Chemical Communications,2011,47(7):2032-2034.
[49] Duan Y D,Fu N Q,Zhang Q,et al.Influence of Sn source on the performance of dye-sensitized solar cells based on Sn-doped TiO2 photoanodes:a strategy for choosing an appropriate doping source[J].Electrochimica Acta,2013,107:473-480.
[50] Xue D,Luo J,Li Z,et al.Enhanced photoelectrochemical properties from Mo-doped TiO2 nanotube Arrays film[J].Coatings,2020,10(1):75.
[51] Dong Z,Ding D,Li T,et al.Ni-doped TiO2 nanotubes photoanode for enhanced photoelectrochemical water splitting[J].Applied Surface Science,2018,443:321-328.
[52] Dhonde M,Sahu K,Murty V V S,et al.Surface plasmon resonance effect of Cu nanoparticles in a dye sensitized solar cell[J].Electrochimica Acta,2017,249:89-95.
[53] Naderi H R,Sobhani-Nasab A,Rahimi-Nasrabadi M,et al.Decoration of nitrogen-doped reduced graphene oxide with cobalt tungstate nanoparticles for use in high-performance supercapacitors[J].Applied Surface Science,2017,423:1025-1034.
[54] Mahmoud M S,Akhtar M S,Mohamed I M A,et al.Demonstrated photons to electron activity of S-doped TiO2 nanofibers as photoanode in the DSSC[J].Materials Letters,2018,225:77-81.
[55] Wang C T,Lin H S,Wang W P.Hydrothermal synthesis of Fe and Nb-doped titania nanobelts and their tunable electronic structure toward photovoltaic application[J].Materials Science in Semiconductor Processing,2019,99:85-91.
[56] Kundu S,Sarojinijeeva P,Karthick R,et al.Enhancing the efficiency of DSSCs by the modification of TiO2 photoanodes using N,F and S,co-doped graphene quantum dots[J].Electrochimica Acta,2017,242:337-343.
[57] Park J Y,Kim C S,Okuyama K,et al.Copper and nitrogen doping on TiO2 photoelectrodes and their functions in dye-sensitized solar cells[J].Journal of Power Sources,2016,306:764-771.
[58] Miao F,Sun B,Tao B,et al.MoS2/Ag/TiO2 for photoanode of dye sensitized solar cells[J].Journal of Materials Research and Technology,2022,20:781-790.
[59] Taş R.Effect of polyaniline polymers with boric acid and multi-walled carbon nanotube on dye sensitive solar cells performance[J].Acta Physica Polonica A,2021,139(6):687-691.
[60] Li W,Jin G,Hu H,et al.Phosphotungstic acid and WO3 incorporated TiO2 thin films as novel photoanodes in dye-sensitized solar cells[J].Electrochimica Acta,2015,153:499-507.
[61] Shin S G,Kim K H,Bark C W,et al.Preparation of a phosphor/TiO2 nanoparticle composite layer for applications in dye-sensitized solar cells[J].Journal of the Korean Physical Society,2014,65(3):387-391.
[62] Yang L,Leung W W F.Application of a bilayer TiO2 nanofiber photoanode for optimization of dye-sensitized solar cells[J].Advanced Materials,2011,23(39):4559-4562.
[63] Ni S,Wang D,Guo F,et al.Efficiency improvement of TiO2 nanowire arrays based dye-sensitized solar cells through further enhancing the specific surface area[J].Journal of Crystal Growth,2019,505:62-68.
[64] Liu W W,Lu H,Zhang M,et al.Controllable preparation of TiO2 nanowire arrays on titanium mesh for flexible dye-sensitized solar cells[J].Applied Surface Science,2015,347:214-223.
[65] Lee B,Kim J I,Lee S,et al.Oriented hierarchical porous TiO2 nanowires on Ti substrate:evolution of nanostructures for dye-sensitized solar cells[J].Electrochimica ACTA,2014,145:231-236.
[66] 杨小洁,董兵海,陈凤翔,等.一维二氧化钛光阳极的制备及在染料敏化太阳能电池中的应用综述[J].材料导报,2017,31(17):138-145.
[67] Ding Y,Mo L,Tao L,et al.TiO2 sub-microspheres as a bi-functional scattering layer for high-performance dye-sensitized solar cells[J].Nano,2014,9(5):1440007.
基金资助
安徽理工大学环境友好材料与职业健康研究院(芜湖)研发专项(ALW2020YF02);2021年国家级大学生创新创业训练计划项目(202110361071);安徽理工大学2021年研究生创新基金项目(2021CX2084);2022年光电材料与技术国家重点实验室开放课题(OEMT-2022-KF-04)
PDF
