类水滑石(LDHs)和蒙脱土(MMT)都属于二维层状黏土,通过将LDHs与MMT复合可得到不同结构的LDHs/MMT复合材料,如板对板交替结构、花状结构及板层混合交替结构,已应用于吸附、催化、荧光、油水分离领域。介绍了LDHs/MMT复合材料的制备方法,对其在各领域的研究进展进行了综述,最后对其发展前景进行了展望。
Both layered double hydroxides (LDHs) and montmorillonite (MMT) belong to two-dimensional layered clays.By combining layered double hydroxides and montmorillonite,the LDHs/MMT composites with different structures can be obtained,such as alternating plate-to-plate structure,flower-like structure and mixed alternating layer structure,which have been used in the fields of adsorption,catalysis,fluorescence,and oil-water separation,etc.In this paper,the preparation methods of LDHs/MMT composite were introduced,and the research progress of LDHs/MMT composites was reviewed.Finally,the development of LDHs/MMT was prospected.
[1] Bravosuarez J J,Paezmozo E A,Oyama S T,et al.Review of the synthesis of layered double hydroxides:a thermodynamic approach[J].Química Nova,2004,27(4):601-614.
[2] Gao Y S,Zhang Y,Williams G R,et al.Layered double hydroxide-oxidized carbon nanotube hybrids as highly efficient flame retardant nanofillers for polypropylene[J].Scientific Reports,2016,6(1):1-13.
[3] Liu P F,Zhang Y P,Liu S Q,et al.Fabrication of superhydrophobic marigold shape LDHs films on stainless steel meshes via in-situ growth for enhanced anti-corrosion and high efficiency oil-water separation[J].Applied Clay Science,2019,182:105292.
[4] Daniel S,Thomas S.Layered double hydroxides:fundamentals to applications[M].Cambridge:Woodhead Publishing,2020:1-76.
[5] Saikia P,Borah A,Goswamee R L.Iso-conversional kinetics study on thermal degradation of Ni-Al layered double hydroxide synthesized by ‘soft chemical’sol-gel method[J].Materials Chemistry and Physics,2017,186:52-60.
[6] Wan H,Yan A,Xiong H,et al.Montmorillonite:a structural evolution from bulk through unilaminar nanolayers to nanotubes[J].Applied Clay Science,2020,194:105695.
[7] Bee S,Abdullah M A,Bee S T,et al.Polymer nanocomposites based on silylated-montmorillonite:a review[J].Progress in Polymer Science,2018,85:57-82.
[8] Xiao F,Yan B Q,Zou X Y,et al.Study on ionic liquid modified montmorillonite and molecular dynamics simulation[J].Colloids and Surfaces A:Physicochemical and Engineering Aspects,2020,587:124311.
[9] Jiang Y N,Yang Z H,Liu L L,et al.Zn-Al layered double hydroxide growing on the substrate of graphene and polypyrrole composite as anode material for Zn-Ni secondary battery[J].Materials Letters,2019,255:126558.
[10] Shang S,Hanif A,Sun M,et al.Novel M (Mg/Ni/Cu)-Al-CO3 layered double hydroxides synthesized by aqueous miscible organic solvent treatment (AMOST) method for CO2 capture[J].Journal of Hazardous Materials,2019,373:285-293.
[11] 刘仁杰,李三喜,王松,等.蒙脱土剥离方法的研究进展[J].材料导报,2020,34(S1):249-254.
[12] Huang S,Cen X,Peng H D,et al.Heterogeneous ultrathin films of poly(vinyl alcohol)/layered double hydroxide and montmorillonite nanosheets via layer-by-layer assembly[J].The Journal of Physical Chemistry B,2009,113(46):15225-15230.
[13] Chalasani R,Gupta A,Vasudevan S.Engineering new layered solids from exfoliated inorganics:a periodically alternating hydrotalcite-montmorillonite layered hybrid[J].Scientific Reports,2013,3(1):568-571.
[14] Scaffaro R,Sutera F,Mistretta M C,et al.Structure-properties relationships in melt reprocessed PLA/hydrotalcites nanocomposites[J].Express Polymer Letters,2017,11(7):555-564.
[15] Hu Z Y,Zhang P,Xie R S,et al.Controlled synthesis of train-structured montmorillonite/layered double hydroxide nanocomposites by regulating the hydrolysis of polylactic acid[J].Journal of Materials Science,2018,53(23):15859-15870.
[16] Wang D B,Yu X,Feng Q G,et al.In-situ growth of β-Bi2O3 nanosheets on g-C3N4 to construct direct Z-scheme heterojunction with enhanced photocatalytic activities[J].Journal of Alloys and Compounds,2021,859:157795.
[17] Zhang L,Cai P,Wei Z,et al.Synthesis of reduced graphene oxide supported nickel-cobalt-layered double hydroxide nanosheets for supercapacitors[J].Journal of Colloid and Interface Science,2021,588:637-645.
[18] Li C J,Zhang J,Lin Y Y,et al.In situ growth of layered double hydroxide on disordered platelets of montmorillonite[J].Applied Clay Science,2016,119:103-108.
[19] Li Z,Liu Z Q,Zhang J,et al.Bio-based layered double hydroxide nanocarrier toward fire-retardant epoxy resin with efficiently improved smoke suppression[J].Chemical Engineering Journal,2019,378:122046.
[20] Guo X L,Zhang J M,Xu W N,et al.Growth of NiMn LDH nanosheet arrays on KCu7S4 microwires for hybrid supercapacitors with enhanced electrochemical performance[J].Journal of Materials Chemistry A,2017,5(39):20579-20587.
[21] 何洋.碳酸根柱撑水滑石的制备及结构重构性能研究[D].哈尔滨:哈尔滨工程大学,2011.
[22] Makwana D,Polisetti V,Castaño J,et al.Mg-Fe layered double hydroxide modified montmorillonite as hydrophilic nanofiller in polysulfone-polyvinylpyrrolidone blend ultrafiltration membranes:separation of oil-water mixture[J].Applied Clay Science,2020,192:105636.
[23] Jiang D B,Jing C,Yuan Y,et al.2D-2D growth of NiFe-LDHs nanoflakes on montmorillonite for cationic and anionic dye adsorption performance[J].Journal of Colloid and Interface Science,2019,540:398-409.
[24] Mishra M,Bora J J,Goswamee R L.Improvement of the mechanical strength of alumina preforms by coating with montmorillonite/LDHs gels[J].Applied Clay Science,2011,53(1):8-14.
[25] Zhou S W,Gu C T,Qian Z Y,et al.The activity and selectivity of catalytic peroxide oxidation of chlorophenols over Cu-Al hydrotalcite/clay composite[J].Journal of Colloid and Interface Science,2011,357(2):447-452.
[26] Gan F Q,Luo Y F,Hang X S,et al.Heterocoagulated clay-derived adsorbents for phosphate decontamination from aqueous solution[J].Journal of Environmental Management,2016,166:23-30.
[27] Hsu L C,Tzou Y M,Chiang P N,et al.Adsorption mechanisms of chromate and phosphate on hydrotalcite:a combination of macroscopic and spectroscopic studies[J].Environmental Pollution,2019,247:180-187.
[28] Seddighi H,Darban A K,Khanchi A,et al.LDHS(Mg/Al:2)@montmorillonite nanocomposite as a novel anion-exchanger to adsorb uranyl ion from carbonate-containing solutions[J].Journal of Radioanalytical and Nuclear Chemistry,2017,314(1):415-427.
[29] Bakr A A,Sayed N A,Salama T M,et al.Kinetics and thermodynamics of Mn(Ⅱ) removal from aqueous solutions onto Mg-Zn-Al LDH/montmorillonite nanocomposite[J].Egyptian Journal of Petroleum,2018,27(4):1215-1220.
[30] Yan D P,Lu J,Ma J,et al.Layered host-guest materials with reversible piezochromic luminescence[J].Angewandte Chemie,2011,50(31):7037-7040.
[31] Ikeda M,Yoshii T,Matsui T,et al.Montmorillonitesupramolecular hydrogel hybrid for fluorocolorimetric sensing of polyamines[J].Journal of the American Chemical Society,2011,133(6):1670-1675.
[32] Zdeňka K,Matouek J,Pavla A,et al.A new luminescent montmorillonite/borane nanocomposite[J].Applied Clay Science,2015,118:295-300.
[33] Yan D P,Lu J,Ma J,et al.Anionic poly(p-phenylenevinylene)/layered double hydroxide ordered ultrathin films with multiple quantum well structure:a combined experimental and theoretical study[J].Langmuir,2010,26(10):7007-7014.
[34] Liu M T,Wang T L,Ma H W,et al.Assembly of luminescent ordered multilayer thin-films based on oppositely-charged MMT and magnetic NiFe-LDHs nanosheets with ultra-long lifetimes[J].Scientific Reports,2014,4(1):1-9.
[35] Wang T L,Liu M T,Ma H W,et al.Lifetime-ultra-prolonged luminescent multilayer thin films with electronic microenvironment[J].RSC Advances,2014,4(77):40748-40752.
[36] Liu M T,Wang T L,Ma H W,et al.Layer-by-layer assembly of luminescent multilayer thin films by MMT,anionic chromophores and magnetic CoAl-LDHs nanosheets[J].Materials Letters,2015,153:40-43.
[37] Zhao Y F,Jia X D,Geoffrey I N W,et al.Layered double hydroxide nanostructured photocatalysts for renewable energy production[J].Advanced Energy Materials,2016,6(6):1501974.
[38] 李海金,韩秋彤,贾虎,等.LDHs材料的制备及光催化应用研究进展[J].中国材料进展,2019,38(2):91-97.
[39] Mersly L E L,Moujahid E M,Forano C,et al.ZnCr-LDHs with dual adsorption and photocatalysis capability for the removal of acid orange 7 dye in aqueous solution[J].Journal of Science:Advanced Materials and Devices,2021,6(1):118-126.
[40] Bg A,Rt A,Mav A,et al.Photocatalytic degradation of trimethoprim on doped Ti-pillared montmorillonite[J].Applied Clay Science,2019,167:43-49.
[41] Chuaicham C,Xiong Y,Sekar K,et al.A promising Zn-Ti layered double hydroxide/Fe-bearing montmorillonite composite as an efficient photocatalyst for Cr(Ⅵ) reduction:Insight into the role of Fe impurity in montmorillonite[J].Applied Surface Science,2021,546:148835.
[42] 李桂水,王庆港,陈皓,等.用于油水分离过程中的膜材料及其制备与改性的综述[J].天津科技大学学报,2021,36(4):1-7.
[43] Zhang L H,Gong Z Q,Jiang B,et al.Ni-Al layered double hydroxides (LDHs) coated superhydrophobic mesh with flower-like hierarchical structure for oil/water separation[J].Applied Surface Science,2019,490:145-156.
[44] Sanyal S,Bhui U K,Balaga D,et al.Interaction study of montmorillonite-crude oil-brine:molecular-level implications on enhanced oil recovery during low saline water flooding from hydrocarbon reservoirs[J].Fuel,2019,254:115725.
基金资助
国家自然科学基金项目资助——国家自然科学基金重点项目[21838007];陕西省教育厅服务地方专项项目[20JC006];陕西省重点研发项目[2020GY-258];陕西省创新能力支撑计划(项目号:2021TD-16)