石墨烯基气凝胶(GAs)不仅具有超高的比表面积和孔隙率、高导电性、高比热容、低密度,而且还有优异的力学性能、稳定的化学性质,在超级电容器、催化剂载体、吸波材料等方面有广阔的应用。针对石墨烯基气凝胶的制备方法(如模板法、自组装法、3D打印法、溶胶-凝胶法等),以及在环境净化、能源及催化等领域的应用和GAs的发展前景进行了综述。
Graphene-based aerogels (GAs) not only have ultra-high specific surface area and porosity,high electrical conductivity,high specific heat capacity and low density,but also have excellent mechanical properties and stable chemical properties,which exhibit broad applications in supercapacitors,catalyst carriers and absorbing materials.In this paper,the preparation methods of graphene-based aerogels,such as template method,self-assembly method,3D printing method and sol-gel method,as well as the applications in the fields of environmental purification,energy and catalysis,and the development prospect of GAs were reviewed.
[1] Korkmaz S,Kariper A.Graphene and graphene oxide based aerogels:synthesis,characteristics and supercapacitor applications[J].Journal of Energy Storage,2020,27:101038.
[2] Olabi A G,Abdelkareem M A,Sayed E T,et al.Application of graphene in energy storage device—a review[J].Renewable and Sustainable Energy Reviews,2021,135:110026.
[3] Li X,Li B H,Kang F Y,et al.A review of graphynes:properties,applications and synthesis[J].New Carbon Materials,2020,35(6):619-629.
[4] 杨文栋,刘元军.石墨烯基复合吸波材料的最新研究进展[J].丝绸.2021,58(7):51-61.
[5] 姜凯,白臻祖,黄珊,等.气凝胶的研究进展[J].云南化工,2020,47(6):1-5.
[6] 李天,支丹丹,孟凡彬,等.石墨烯基气凝胶微球的研究进展[J].材料工程,2021,49(11):14-29.
[7] Quan L,Wang C,Ruoff R S,et al.Electromagnetic properties of graphene aerogels made by freeze-casting[J].Chemical Engineering Journal,2022,428:131337.
[8] Trinh T T P N X,Nguyet D M,Hieu N H,et al.Preparing three-dimensional graphene aerogels by chemical reducing method:investigation of synthesis condition and optimization of adsorption capacity of organic dye[J].Surfaces and Interfaces,2021,23:101023.
[9] Liu D,Chen C,Hu L,et al.3D-printed,high-porosity,high-strength graphite aerogel[J].Small Methods,2021,5(7):2001188.
[10] Wang S,Niu Y,Li A,et al.Modified hollow glass microspheres/reduced graphene oxide composite aerogels with low thermal conductivity for highly efficient solar steam generation[J].ACS Applied Materials & Interfaces,2021,13(36):42803-42812.
[11] Pottathara Y B,Tiyyagura H R,Sadasivuni K K,et al.Graphene based aerogels:fundamentals and applications as supercapacitors[J].Journal of Energy Storage,2020,30:101549.
[12] Tang S,Xia D,Peng Y,et al.Dye adsorption by self-recoverable,adjustable amphiphilic graphene aerogel[J].Journal of Colloid and Interface Science,2019,554:682-691.
[13] Xu H S,Huang G Q,Xue M Y,et al.Study on characterization of Ni/N-rGO catalyst and its hydrogenation performance of phenol[J].Journal of Fuel Chemistry and Technology,2021,49(7):1042-1048.
[14] 刘徐越,梁兵,龙佳朋.石墨烯气凝胶在催化领域的研究进展[J].化工新型材料,2021,49(5):60-64.
[15] Ge J,Zhu H W,Yu S H,et al.A general and programmable synthesis of graphene-based composite aerogels by a melamine-sponge-templated hydrothermal process[J].CCS Chemistry,2020,2(2):1-12.
[16] Zhang W,Cheng R R,He X J,et al.A review of porous carbons produced by template methods for supercapacitor applications[J].New Carbon Materials,2021,36(1):69-81.
[17] Zhang X,Su J,Yuan C,et al.Synthesis of graphene aerogels using cyclohexane and n-butanol as soft templates[J].RSC Advances,2020,10(24):14283-14290.
[18] Zhang X,Zhang T,Zhang J,et al.Ultralight,superelastic,and fatigue-resistant graphene aerogel templated by graphene oxide liquid crystal stabilized air bubbles[J].ACS Applied Materials & Interfaces,2019,11(1):1303-1310.
[19] Ping Y,Gong Y,Pan C,et al.Preparation of three-dimensional graphene foam for high performance supercapacitors[J].Progress in Natural Science:Materials International,2017,27(2):177-181.
[20] Liu S,Yao F,Fu G,et al.Green synthesis of oriented xanthan gum-graphene oxide hybrid aerogels for water purification[J].Carbohydrate Polymers,2017,174:392-399.
[21] Lai K C,Hiew B Y Z,Khiew P S,et al.Ice-templated graphene oxide/chitosan aerogel as an effective adsorbent for sequestration of metanil yellow dye[J].Bioresource Technology,2019,274:134-144.
[22] Bo Y,Yu A,Zhang C,et al.Preparation of elastic graphene aerogel and its adsorption of oil[J].Journal of Porous Materials,2020,28(1):39-56.
[23] 刘明禹.氧化石墨烯基气凝胶颗粒的高效制备与应用研究[D].天津:天津工业大学,2019,
[24] Hu X,Wang Y,Liu Z,et al.Preparation of graphene/graphene nanoribbons hybrid aerogel and its application for the removal of uranium from aqueous solutions[J].Journal of Radioanalytical and Nuclear Chemistry,2020,325(1):207-215.
[25] 周玉清,方派,夏明桂,等.新型石墨烯基复合气凝胶用于废水中钆离子的吸附[J].武汉纺织大学学报,2021,34(3):37-41.
[26] Wang X,Lu Y,Wang W,et al.CoFe2O4/N-doped reduced graphene oxide aerogels for high-performance microwave absorption[J].Chemical Engineering Journal,2020,388:124317.
[27] Zhu Z Q,Dai J F,Li A,et al.Facile preparation of porous graphene oxide-based nanocomposite xerogel for selective absorption[J].Chemistry Select,2017,2(27):8493-8499.
[28] Li Y,Sheng K,Shi G,et al.A high-performance flexible fibre-shaped electrochemical capacitor based on electrochemically reduced graphene oxide[J].Chem Commun (Camb),2013,49(3):291-293.
[29] Kim D W,Jung S M,Jung H Y.A super-thermostable,flexible supercapacitor for ultralight and high performance devices[J].Journal of Materials Chemistry A,2020,8(2):532-542.
[30] Guo B,Liang G,Bai J,et al.3D printing of reduced graphene oxide aerogels for energy storage devices:a paradigm from materials and technologies to applications[J].Energy Storage Materials,2021,39:146-165.
[31] Tran T S,Dutta N K,Choudhury N R.Poly(ionic liquid)-stabilized graphene nanoinks for scalable 3D printing of graphene aerogels[J].ACS Applied Nano Materials,2020,3(11):11608-11619.
[32] Masud A,Zhou C,Aich N.Emerging investigator series:3D printed graphene-biopolymer aerogels for water contaminant removal:a proof of concept[J].Environmental Science:Nano,2021,8(2):399-414.
[33] 张恩爽,雷朝帅,张昊,等.超轻质磁性石墨烯-炭气凝胶的制备及电磁干扰性能[J].新型碳材料,2020,35(6):707-715.
[34] Zhou Y,Hu X,Liu X,et al.Multi-functional graphene/carbon nanotube aerogels for its applications in supercapacitor and direct methanol fuel cell[J].Electrochimica Acta,2018,264:12-19.
[35] Ma Z,Zhao X,Zhang Z,et al.Preparation of a graphene-based composite aerogel and the effects of carbon nanotubes on preserving the porous structure of the aerogel and improving its capacitor performance[J].Journal of Materials Chemistry A,2015,3(25):13445-13452.
[36] Garcia-Bordeje E,Victor-Roman S,Maser W K,et al.Control of the microstructure and surface chemistry of graphene aerogels via pH and time manipulation by a hydrothermal method[J].Nanoscale,2018,10(7):3526-3539.
[37] Kang W,Cui Y,Liu X,et al.A novel robust adsorbent for efficient oil/water separation:magnetic carbon nanospheres/graphene composite aerogel[J].Journal of Hazardous Materials,2020,392,122499.
[38] Bessa A,Henriques B,Marques P A A P,et al.Graphene oxide/polyethyleneimine aerogel for high-performance mercury sorption from natural waters[J].Chemical Engineering Journal,2020,398:125587.
[39] Joshi P,Sharma O P,Khatri O P,et al.Fruit waste-derived cellulose and graphene-based aerogels:plausible adsorption pathways for fast and efficient removal of organic dyes[J].Journal of Colloid and Interface Science,2022,680:2870-2883.
[40] Nundy S,Ghosh A,Nath R,et al.Reduced graphene oxide (rGO) aerogel:efficient adsorbent for the elimination of antimony (Ⅲ) and (Ⅴ) from wastewater[J].Journal of Hazardous Materials,2021,420,126554.
[41] Li K,Lei Y,Zhang Y,et al.A facile synthesis of graphene oxide/locust bean gum hybrid aerogel for water purification[J].Carbohydrate Polymers,2021,254:117318.
[42] Zhang W,Huang T,Tu Q,et al.Preparation of chitosan crosslinked with metal-organic framework (MOF-199)@aminated graphene oxide aerogel for the adsorption of formaldehyde gas and methyl orange[J].International Journal of Biological Macromolecules,2021,193:2243-2251.
[43] Zhi D,Li T,Meng F,et al.A review of three-dimensional graphene-based aerogels:synthesis,structure and application for microwave absorption[J].Composites Part B:Engineering,2021,211:108642.
[44] Shu R,Wan Z,Shi J,et al.Synergistically assembled nitrogen-doped reduced graphene oxide/multi-walled carbon nanotubes composite aerogels with superior electromagnetic wave absorption performance[J].Composites Science and Technology,2021,210:108818.
[45] Shu R,Zhang J,Li X,et al.Synthesis of nitrogen-doped reduced graphene oxide/cobalt-zinc ferrite composite aerogels with superior compression recovery and electromagnetic wave absorption performance[J].Nanoscale,2021,13(8):4485-4495.
[46] Li N,Shu R,Wu Y,et al.Synthesis of ultralight three-dimensional nitrogen-doped reduced graphene oxide/multi-walled carbon nanotubes/zinc ferrite composite aerogel for highly efficient electromagnetic wave absorption[J].Journal of Colloid and Interface Science,2021,596:364-375.
[47] Shaikh J S,Shaikh N S,Lokhande C D,et al.The implementation of graphene-based aerogel in the field of supercapacitor[J].Nanotechnology,2021,32(36):362001.
[48] Chen Y,Jiang Y,Zhuo K,et al.Hierarchical porous N-doped graphene aerogel with good wettability for high-performance ionic liquid-based supercapacitors[J].Electrochimica Acta,2021,366:137414.
[49] Zhang J J,Wu Y H,Guan X X,et al.Synergetic adsorption and photocatalytic degradation of pollutants over 3D TiO2-graphene aerogel composites synthesized via a facile one-pot route[J].Photochemical & Photobiological Sciences,2016,15(8):1012-1019.
[50] Liu M,Liu X,Zhang X,et al.N-doped three-dimensional graphene aerogel with a high loading of Ag particles as an efficient catalyst and antibacterial agent[J].Colloids and Surfaces A:Physicochemical and Engineering Aspects,2021,626:126886.
[51] Yang X,Chen Z,Chen M,et al.Freestanding 3D MoS2 nanosheets/graphene aerogel heterostructure as a recyclable photocatalyst for efficiently degrading antibiotic residues[J].Materials Letters,2019,252:5-7.
基金资助
国家自然科学基金(21473126);湖北省教育厅基金项目(B2014094);湖北省教育厅指导性项目(B2017010)
PDF
