邻苯二甲腈树脂是一类新型的耐高温热固性树脂体系,为了改善其工艺性并满足严苛的环境性能需求,国内外针对邻苯二甲腈树脂体系开展了大量改性研究工作。着重从分子主链结构设计、固化方式及机理、树脂改性和复合材料改性等方面,介绍了改性邻苯二甲腈体系的研究进展,表明其具有优异的工艺性、耐候性和力学特性,展示出良好的应用前景。
Phthalonitrile resin is a novel kind of thermosetting resin system with high temperature resistance.In order to promote the manufacturability and meet the demand of severe environmental performance,plenty of modification works for phthalonitrile systems have been carried out.In this paper,the relevant research progress was mainly introduced from the aspects of molecular structure design,curing mode and mechanism,resin modification and composite material modification,etc.It was shown that the modified phthalonitrile systems had excellent manufacturability,weatherability and mechanical properties,and exhibited promising application prospect.
[1] Gutowski T G.Advanced composites manufacturing[M].New York:John Wiley & Sons Inc,1997:6-8.
[2] 林玩君,易爱华,赵侠.碳纤维改性环氧树脂复合材料研究进展[J].化工新型材料,2012,40(5):4-6,10.
[3] 邢丽英,包建文,礼嵩明,等.先进树脂基复合材料发展现状和面临的挑战[J].复合材料学报,2016,33(7):1327-1338.
[4] Liu X,Long S,Luo D,et al.Preparation and properties of polyarylene ether nitrites/multi-walled carbon nanotubes composites[J].Materials Letters,2008,62(1):19-22.
[5] 王兴刚,于洋,李树茂,等.先进热塑性树脂基复合材料在航天航空上的应用[J].纤维复合材料,2011(2):44-47.
[6] 陈平,于祺,孙明等.高性能热塑性树脂基复合材料的研究进展[J],纤维复合材料,2005(2):52-57.
[7] 钟凤.耐高温环氧树脂的合成与性能研究[D].上海:东华大学,2014.
[8] 许孔力,夏雨,李丽英,等.树脂基烧蚀材料研究进展[J].复合材料科学与工程,2021(2):123-128.
[9] 黄孝华.新型功能性聚酰亚胺的合成与性能研究[D].上海:上海交通大学,2011.
[10] 周健,黄祖洪.新型双马来酰亚胺树脂的研究及在环氧树脂中的应用[J].绝缘材料,2002,35(3):10-13.
[11] Keller T M,Price T R.Amine-cured bisphenol-linked phthalonitrile resins[J].Journal of Macromolecular Science Chemistry,1982,18(6):931-937.
[12] Terekhov V E,Bogolyubov A A,Morozov O S,et al.High-temperature phthalonitrile matrix containing silane fragments[J].Mendeleev Communications,2020,30(6):796-798.
[13] Bai S N,Sun X Y,Chen X G,et al.Synthesis and properties of a thioether bonded phthalonitrile resin[J].Materials Today Communications,2020,24:101352-101358.
[14] Bai S N,Sun X Y,Zhang Z J,et al.Synthesis and properties of a low melting point phthalonitrile resin containing high density nitrile groups[J].Chemistry Select,2020,5(1):265-269.
[15] Liao S J,Wu H,He X,et al.Promoting effect of methyne/methylene moiety of bisphenol E/F on phthalonitrile resin curing:expanding the structural design route of phthalonitrile resin[J].Polymer,2020,210:123001-123012.
[16] Wu M J,Xu J J,Bai S N,et al.A high-performance functional phthalonitrile resin with a low melting point and a low dielectric constant[J].Soft Matter,2020,16(7):1888-1896.
[17] Yang K,Chen X,Zhang Z,et al.Introducing rigid pyrimidine ring to improve the mechanical properties and thermal-oxidative stabilities of phthalonitrile resin[J].Polymers for Advanced Technologies,2020,31(2):328-337.
[18] Keller T M.Synthesis and polymerization of multiple aromatic ether phthalonitriles[J].Chemistry of materials,1994,6(3):302-305.
[19] 李正,张宗波,林先凯,等.邻苯二甲腈树脂的固化机理与改性研究进展[J].材料导报,2013,27(15):82-87.
[20] Gao C,Gu H,Du A,et al.Polyaniline facilitated curing of phthalonitrile resin with enhanced processibility and mechanical property[J].Polymer,2021,219:123533-123539.
[21] 翁志焕,宗立率,刘程,等.邻苯二甲腈树脂分子结构及性能调控工作进展[J].高分子材料科学与工程,2021,37(1):189-199.
[22] 罗廷福,李罕,黄梦瑶,等.查尔酮型双邻苯二甲腈树脂的合成与性能[J].塑料工业,2019,47(4):15-20.
[23] Zhang H,Wang B,Hu J,et al.Curing behavior studies of phenol-containing phthalonitrile monomer for advanced composite materials[J].Thermochimica Acta,2021,696:178837-178843.
[24] Xu M Z,Liu M D,Dong S H,et al.Design of low temperature self-cured phthalonitrile-based polymers for advanced glass fiber composite laminates[J].Journal of Materials Science,2013,48(23):8108-8116.
[25] 雷雅杰,左芳,赵睿.聚芳醚腈/双邻苯二甲腈树脂共混改性与性能研究[J].材料工程,2009(S2):169-172.
[26] 王蒙娜,王志强,苏韬,等.聚酰亚胺改性耐高温透波邻苯二甲腈复合材料制备[J].工程塑料应用,2020,48(6):40-45.
[27] 马京京.双邻苯二甲腈树脂的增韧及其复合材料导电性能的研究[D].长春:吉林大学,2018.
[28] 陈智然.二元酚改性双邻苯二甲腈树脂[D].成都:电子科技大学,2014.
[29] 李晓丹.POSS改性双邻苯二甲腈耐热树脂体系设计制备与改性机理[D].哈尔滨:哈尔滨工业大学,2018.
[30] 曾科,杨刚.聚邻苯二甲腈树脂研究进展[J].热固性树脂,2012,27(1):58-63.
[31] 夏学莲,史向阳,赵海鹏,等.热塑性高分子材料增韧机理研究进展[J].化工新型材料,2019,47(4):34-37.
[32] 张然,解惠贞,李瑞珍.树脂基复合材料增韧研究进展[J].化工新型材料,2021,49(3):39-42.
[33] 赵泽华,孙劲松,郭颖,等.聚酰亚胺颗粒层间增韧碳纤维/邻苯二甲腈树脂复合材料[J].复合材料学报,2021,38(3):732-740.
[34] Sun J,Han Y,Zhao Z,et al.Improved toughness of phthalonitrile composites through synergistic toughening methods[J].Composites Communications,2021,26:100779-100784.
[35] 单书燕.聚苯腈/氧化铝复合材料制备与性能研究[D].天津:河北工业大学,2016.
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