光-生物可降解LDPE/纳米TiO2/TPS复合膜材料的制备及性能研究

李凤红, 李鹏珍, 笪伟, 王哲, 师岩

化工新型材料 ›› 2023, Vol. 51 ›› Issue (1) : 290 -295.

PDF
化工新型材料 ›› 2023, Vol. 51 ›› Issue (1) : 290-295. DOI: 10.19817/j.cnki.issn1006-3536.2023.01.056
开发与应用

光-生物可降解LDPE/纳米TiO2/TPS复合膜材料的制备及性能研究

    李凤红, 李鹏珍, 笪伟, 王哲, 师岩
作者信息 +

Preparation and properties of photo-biodegradable LDPE/nano-TiO2/TPS composite film materials

  • Li Fenghong, Li Pengzhen, Da Wei, Wang Zhe, Shi Yan
Author information +
文章历史 +
PDF

摘要

以低密度聚乙烯(LDPE)为基体,采用改性纳米二氧化钛(纳米TiO2)光降解剂和糊化处理后的淀粉(TPS)生物降解剂,通过密炼机和平板硫化机制备了光-生物可降解LDPE/纳米TiO2/TPS复合膜材料,并对其进行了热性能、力学性能、光降解性能和生物降解性能研究。实验结果表明,添加光-生物降解剂后,光-生物可降解膜的降解能力明显高于纯LDPE膜,并且随着TPS生物降解剂的增多,膜材料的结晶度和力学性能增加,降解能力更加明显。当TPS的质量为LDPE基体的20%时,复合膜材料的结晶度最大,为29.3%。

Abstract

In this paper,using Low-density polyethylene (LDPE) as the matrix material,modified nano-titanium dioxide (nano-TiO2) as photodegradation agent and gelatinized starch (TPS) as biodegradation agent,the photo-biodegradable LDPE/nano-TiO2/TPS composite membrane materials were prepared by an internal mixer and a flat vulcanizer.The thermal properties,mechanical properties,photodegradation and biodegradability of the composite film materials were further studied.The results showed that the degradation ability of the photo-biodegradable film,after adding photo-biodegradable agent,was obviously higher than that of the pure LDPE film.Furthermore,the crystallinity and mechanical properties of the film materials increased with the increase of TPS biodegradable agent,and the degradation ability of the photo-biodegradable LDPE/nano-TiO2/TPS composite film became more obvious.When the mass of TPS was 20% of LDPE matrix,the maximum crystallinity of the composite film material was 29.3%.

关键词

光-生物可降解 / 纳米二氧化钛 / 淀粉 / 低密度聚乙烯

Key words

photo-biodegradable / nano-titanium dioxide / starch / low-density polyethylene

引用本文

引用格式 ▾
光-生物可降解LDPE/纳米TiO2/TPS复合膜材料的制备及性能研究[J]. 化工新型材料, 2023, 51(1): 290-295 DOI:10.19817/j.cnki.issn1006-3536.2023.01.056

登录浏览全文

4963

注册一个新账户 忘记密码

参考文献

[1] Hakimeh E,Parvaneh S,Farzaneh S,et al.CuO/LDPE nanocomposite for active food packaging application:a comparative study of its antibacterial activities with ZnO/LDPE nanocomposite[J].Polymer Bulletin,2021,78(3):1671-1682.
[2] Zhai X D,Wang X Y,Zhang J J,et al.Extruded low density polyethylene-curcumin film:a hydrophobic ammonia sensor for intelligent food packaging[J].Food Packaging and Shelf Life,2020,26:1-8.
[3] Xu J Z,Wang X,Yuan X M,et al.Polyaniline modified mesoporous titanium dioxide that enhances oxo-biodegradation of polyethylene films for agricultural plastic mulch application[J].Polymer International,2019,68(7):1332-1340.
[4] 龚健花,王庭慰.PA6/LDPE医用复合薄膜加速老化和寿命评价[J].塑料工业,2016,44(03):103-106,110.
[5] 周城,刘鹏,张海松,等.阻燃改性氢氧化镁/低密度聚乙烯的性能研究[J].绝缘材料,2021,54(3):29-35.
[6] 徐汝珍,师岩,安萍,等.纳米抗菌聚乙烯复合膜的制备技术研究进展[J].塑料科技,2018,46(7):127-130.
[7] 宋美丽,谷宇,田广华,等.聚乙烯薄膜的性能及应用综述[J].合成材料老化与应用,2018,47(3):115-118,124.
[8] Sridharan R,Vetriselvan M,Krishnaswamy V G,et al.Integrated approach in LDPE degradation-an application using Winogradsky column,computational modeling,and pathway prediction[J].Journal of Hazardous Materials,2021,412:125336-125336.
[9] 李菲,江贵长,陈明芬.浅析可降解塑料包装材料[J].上海包装,2018(4):47-50.
[10] 崔文娟.可降解塑料的种类及应用现状[J].杨凌职业技术学院学报,2021,20(2):20-22.
[11] 陕洁,牟芬,王新芳,等.可生物降解塑料的合成及其改性[J].聚酯工业,2021,34(3):23-26.
[12] Nooshin N,Wangyujue H,Babak G,et al.Study of cellulose nanocrystal doped starch-polyvinyl alcohol bio-nanocomposite films[J].International Journal of Biological Macromolecules,2018,107,2065-2074.
[13] Abdul K H,Baneriee A,Aparajita B,et al.Biodegradable films for fruits and vegetables packaging application:preparation and properties[J].Food Engineering Reviews,2018,10(3):139-153.
[14] Kumar P,Tanwar R,Gupta V,et al.Pineapple peel extract incorporated poly(vinyl alcohol)-corn starch film for active food packaging:preparation,characterization and antioxidant activity[J].International Journal of Biological Macromolecules,2021,187:223-231.
[15] Mahendrasinh R,Ravikumar S,Sagar J,et al.Studies on blends of modified starch-LDPE[J].Polymer Science,Series A,2018,60(6):805-815.
[16] Kuljit K,Rajeev J,Mithu M,et al.Studies on the properties and biodegradability of PVA/Trapa natans starch (N-st) composite films and PVA/N-st-g-poly (EMA) composite films[J].International Journal of Biological Macromolecules,2019,123:826-836.
[17] Paula G S,Carolina M J,Lucia F,et al.Biodegradable and non-retrogradable eco-films based on starch-glycerol with citric acid as crosslinkingagent[J].Carbohydrate Polymers,2016,138:66-74.
[18] Mahdiyar S,Mahsa M,Asgar F.Physical modification of starch by high-pressure homogenization for improving functional properties of κ-carrageenan/starch blend film[J].Food Hydrocolloids,2018,85:204-214.
[19] 寇志敏.小分子增塑剂对淀粉热塑化改性及性能的影响研究进展[J].包装工程,2021,42(15):148-155.
[20] 应纪飞.膜级淀粉基全生物降解材料的制备与性能研究[D].镇江:江苏科技大学,2017.
[21] 张策,周立轩,王怡,等.淀粉/LDPE复合材料制备及性能研究[J].辽宁化工,2016,45(3):245-246,249.
[22] 张月航.热塑性淀粉基生物材料共混体系加工性能研究[D].武汉:湖北工业大学,2017.
[23] Seyeda O,Younes Z,Babak G,et al.Modification of physicochemical and thermal properties of starch films by incorporation of TiO2 nanoparticles[J].International Journal of Biological Macromolecules,2016,89:256-264.
[24] 陈章健,韩硕,郑湃,等.锐钛矿型纳米二氧化钛经口暴露90天对Sprague-Dawley大鼠血常规指标的影响[J].北京大学学报(医学版),2021,53(6):1205-1208.
[25] Zhou G Z,Cao Y Y,Jin Y Q,et al.Novel selective adsorption and photodegradation of BPA by molecularly imprinted sulfur doped nano-titanium dioxide[J].Journal of Cleaner Production,2020,274:122929.
[26] 高瑞,侯万国.AgI负载纳米介孔TiO2的制备及其光降解性能[J].青岛科技大学学报(自然科学版),2020,41(02):29-34.
[27] 封海浪,韦子彬,夏彩芬,等.TiO2/壳聚糖复合膜的制备与应用[J].湖北工程学院学报,2019,39(6):21-26.
[28] Yu X Q,Lin D M,Li P,et al.Recent advances in the synthesis and energy applications of TiO2-graphene nanohybrids[J].Solar Energy Materials and Solar Cells,2017,172:252-269.
[29] Kordjazi Z,Ajji A.Development of TiO2 catalyzed HTPB based oxygen scavenging films for food packaging applications[J].Food Control,2021,121:107639-107644.
[30] 李莎.直链淀粉/nano-TiO2抗菌保鲜膜的制备及其性能研究[D].武汉:华中农业大学,2013.
[31] Hwang J S,Yu J,Kim H M,et al.Food additive titanium dioxide and its fate in commercial foods[J].Nanomaterials (Basel,Switzerland),2019,9(8):1175-1175.
[32] Tang Z P,Chen C W,Xie J.Development of antimicrobial active films based on poly(vinyl alcohol) containing nano-TiO2 and its application in macrobrachium rosenbergii packaging[J].Journal of Food Processing and Preservation,2018,42(8):13702-13702.
[33] 隋思瑶,马佳佳,陆皓茜,等.纳米二氧化钛抗菌防雾膜的制备表征及对草莓的保鲜效果(英文)[J].农业工程学报,2019,35(5):302-310.
[34] 杨平,霍瑞亭.偶联剂改性对纳米二氧化钛光催化活性的影响[J].天津工业大学纺织学院,2013,41(3):13-17.
[35] 郭璐瑶.纳米二氧化钛分散及其表面改性研究[D].上海:东华大学,2015.
[36] 李菲,屈贞财,肖根生.偶联剂改性纳米二氧化钛的分散性研究[J].郑州牧业工程高等专科学校学报,2014,34(03):8-10,33.
[37] 余响林,王哲,刘佳俊,等.光/生物双降解纳米TiO2/CMC基高吸水树脂的合成及性能研究[J].化工新型材料,2019,47(4):129-133.
[38] 徐敬欣,常婧瑶,殷永超,等.淀粉预糊化温度对肉粉肠品质特性的影响和机制研究[J].食品工业科技,2021,42(21):57-64.
[39] 郭斌,查东东,薛灿,等.聚乳酸纤维对热塑性淀粉塑料性能的影响[J].功能高分子学报,2018,31(3):261-266.
[40] 吴宗帅,张淑芬,吴磊,等.预糊化改性淀粉对米发糕品质的影响[J].中国食品添加剂,2021,32(3):33-39.
[41] 宋霜霜,邝淑明,杨薇,等.改性TiO2光催化降解LDPE薄膜的研究[J].塑料工业,2014,42(2):34-38.
[42] 杨薇,杨玉鹰,蔡亦金,等.光氧化TiO2/PEO/LDPE复合薄膜的生物降解性能[J].功能材料,2016,47(4):4105-4109.
[43] 叶轻飏.纳米粒子改性LDPE薄膜的研制和保鲜性能研究[D].杭州:浙江大学,2014.
[44] Maryams,Rouhollah B,Mahmood M.Effect of nanoclay on the properties of low-density polyethylene/linear low-density polyethylene/thermoplastic starch blend films[J].Carbohydrate Polymers,2016,141:75-81.
[45] 叶丽华,李乃祥,潘小虎.二氧化钛含量对PET非等温结晶性能的影响[J].合成技术及应用,2016,31(2):35-38.
[46] Nguyen D M,Do T V V,Grillet A C,et al.Biodegradability of polymer film based on low density polyethylene and cassava starch[J].International Biodeterioration & Biodegradation,2016,115:257-265.
[47] Liu H S,Yu L,Xie F W,et al.Gelatinization of cornstarch with different amylose/amylopectin content[J].Carbohydrate Polymers,2006,65(3),357-363.
[48] 黄亚琼.表面修饰TiO2催化降解LDPE薄膜的制备与性能[J].塑料工业,2016,44(6):8-11,16.
[49] Shankar S,Bang Y J,Rhim J W.Antibacterial LDPE/GSE/Mel/ZnONP composite film-coated wrapping paper for convenience food packaging application[J].Food Packaging and Shelf Life,2019,22:100421.
[50] 冯姝姝,林红军,李建喜,等.TiO2-(线性低密度聚乙烯-g-马来酸酐)/低密度聚乙烯薄膜的制备及其光催化降解性能[J].复合材料学报,2017,34(12):2695-2701.
[51] 宋霜霜,罗凯源,梁文耀,等.TiO2-g-PAA/LDPE复合薄膜的光氧化-生物降解性能[J].高分子材料科学与工程,2014,30(4):59-63.
[52] Wang H D,Wang L,Ye S Y,et al.Construction of Bi2WO6-TiO2/starch nanocomposite films for visible-light catalytic degradation of ethylene[J].Food Hydrocolloids,2019,88:92-100.
[53] 王雪.淀粉/乳酸接枝共聚物及其淀粉基薄膜的制备与性能研究[D].北京:中国地质大学(北京),2018.
[54] 贾雪.玉米淀粉基薄膜材料的制备及性质研究[D].无锡:江南大学,2018.
AI Summary AI Mindmap
PDF

499

访问

0

被引

导航
相关文章

AI思维导图

/